Anion−Aromatic Bonding: A Case for Anion Recognition by π-Acidic Rings
Тип публикации: Journal Article
Дата публикации: 2002-05-11
scimago Q1
wos Q1
БС1
SJR: 5.489
CiteScore: 24.4
Impact factor: 15.6
ISSN: 00027863, 15205126
PubMed ID:
12033854
General Chemistry
Catalysis
Biochemistry
Colloid and Surface Chemistry
Краткое описание
The basis for unprecedented noncovalent bonding between anions and the aryl centroid of electron-deficient aromatic rings has been demonstrated by an ab initio study of the interaction between 1,3,5-triazine and the fluoride, chloride, and azide ion at the MP2 level of theory. Minima are also located corresponding to C[bond]H...X(-) hydrogen bonding, reactive complexes for nucleophilic attack on the triazine ring, and pi-stacking interactions (with azide). Trifluoro-1,3,5-triazine also participates in aryl centroid complexation and forms nucleophilic reactive complexes with anions. This novel mode of bonding suggests the development of new cyclophane-type receptors for the recognition of anions.
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ГОСТ
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Mascal M., Armstrong A. S., Bartberger M. D. Anion−Aromatic Bonding: A Case for Anion Recognition by π-Acidic Rings // Journal of the American Chemical Society. 2002. Vol. 124. No. 22. pp. 6274-6276.
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Mascal M., Armstrong A. S., Bartberger M. D. Anion−Aromatic Bonding: A Case for Anion Recognition by π-Acidic Rings // Journal of the American Chemical Society. 2002. Vol. 124. No. 22. pp. 6274-6276.
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TY - JOUR
DO - 10.1021/ja017449s
UR - https://doi.org/10.1021/ja017449s
TI - Anion−Aromatic Bonding: A Case for Anion Recognition by π-Acidic Rings
T2 - Journal of the American Chemical Society
AU - Mascal, Mark
AU - Armstrong, Alan S.
AU - Bartberger, Michael D.
PY - 2002
DA - 2002/05/11
PB - American Chemical Society (ACS)
SP - 6274-6276
IS - 22
VL - 124
PMID - 12033854
SN - 0002-7863
SN - 1520-5126
ER -
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@article{2002_Mascal,
author = {Mark Mascal and Alan S. Armstrong and Michael D. Bartberger},
title = {Anion−Aromatic Bonding: A Case for Anion Recognition by π-Acidic Rings},
journal = {Journal of the American Chemical Society},
year = {2002},
volume = {124},
publisher = {American Chemical Society (ACS)},
month = {may},
url = {https://doi.org/10.1021/ja017449s},
number = {22},
pages = {6274--6276},
doi = {10.1021/ja017449s}
}
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MLA
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Mascal, Mark, et al. “Anion−Aromatic Bonding: A Case for Anion Recognition by π-Acidic Rings.” Journal of the American Chemical Society, vol. 124, no. 22, May. 2002, pp. 6274-6276. https://doi.org/10.1021/ja017449s.