A New Two-Step Four-Component Synthesis of Highly Functionalized Cyclohexenols by Sequential Nickel-Catalyzed Couplings
Publication type: Journal Article
Publication date: 2002-02-13
scimago Q1
wos Q1
SJR: 5.554
CiteScore: 22.5
Impact factor: 15.6
ISSN: 00027863, 15205126
PubMed ID:
11878951
General Chemistry
Catalysis
Biochemistry
Colloid and Surface Chemistry
Abstract
A new two-step procedure for the synthesis of cyclohexenols has been developed. A nickel-catalyzed three-component addition of an enal, alkyne, and acetylenic tin affords substituted hept-4-en-6-ynals. The products of this first step then undergo a second nickel-catalyzed reaction with organozincs or organoboranes to afford densely functionalized cyclohexenols. Variation in each of the four components is tolerated to provide access to a wide range of versatile building blocks.
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41
Total citations:
41
Citations from 2024:
3
(7%)
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MLA
Cite this
GOST
Copy
Lozanov M., Montgomery J. A New Two-Step Four-Component Synthesis of Highly Functionalized Cyclohexenols by Sequential Nickel-Catalyzed Couplings // Journal of the American Chemical Society. 2002. Vol. 124. No. 10. pp. 2106-2107.
GOST all authors (up to 50)
Copy
Lozanov M., Montgomery J. A New Two-Step Four-Component Synthesis of Highly Functionalized Cyclohexenols by Sequential Nickel-Catalyzed Couplings // Journal of the American Chemical Society. 2002. Vol. 124. No. 10. pp. 2106-2107.
Cite this
RIS
Copy
TY - JOUR
DO - 10.1021/ja0175845
UR - https://doi.org/10.1021/ja0175845
TI - A New Two-Step Four-Component Synthesis of Highly Functionalized Cyclohexenols by Sequential Nickel-Catalyzed Couplings
T2 - Journal of the American Chemical Society
AU - Lozanov, Mario
AU - Montgomery, John
PY - 2002
DA - 2002/02/13
PB - American Chemical Society (ACS)
SP - 2106-2107
IS - 10
VL - 124
PMID - 11878951
SN - 0002-7863
SN - 1520-5126
ER -
Cite this
BibTex (up to 50 authors)
Copy
@article{2002_Lozanov,
author = {Mario Lozanov and John Montgomery},
title = {A New Two-Step Four-Component Synthesis of Highly Functionalized Cyclohexenols by Sequential Nickel-Catalyzed Couplings},
journal = {Journal of the American Chemical Society},
year = {2002},
volume = {124},
publisher = {American Chemical Society (ACS)},
month = {feb},
url = {https://doi.org/10.1021/ja0175845},
number = {10},
pages = {2106--2107},
doi = {10.1021/ja0175845}
}
Cite this
MLA
Copy
Lozanov, Mario, and John Montgomery. “A New Two-Step Four-Component Synthesis of Highly Functionalized Cyclohexenols by Sequential Nickel-Catalyzed Couplings.” Journal of the American Chemical Society, vol. 124, no. 10, Feb. 2002, pp. 2106-2107. https://doi.org/10.1021/ja0175845.