Reactions of Oximate α-Nucleophiles with Esters: Evidence from Solvation Effects for Substantial Decoupling of Desolvation and Bond Formation
Тип публикации: Journal Article
Дата публикации: 2002-07-01
scimago Q1
wos Q1
БС1
SJR: 5.489
CiteScore: 24.4
Impact factor: 15.6
ISSN: 00027863, 15205126
PubMed ID:
12137508
General Chemistry
Catalysis
Biochemistry
Colloid and Surface Chemistry
Краткое описание
This communication is concerned with deviations from linearity in Brønsted-type nucleophilicity plots as indicators of changes in transition-state structures, in particular as related to solvational effects. Increasing dimethyl sulfoxide (DMSO) content of DMSO-water mixtures removes the leveling off observed in Brønsted type plots of the reaction of p-nitrophenylacetate (PNPA) with oximate alpha-nucleophiles. This is interpreted as due to virtually complete decoupling between desolvation of the oxyanion nucleophile and bond formation in the rate-determining transition state (solvational imbalance).
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ГОСТ
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Buncel E. et al. Reactions of Oximate α-Nucleophiles with Esters: Evidence from Solvation Effects for Substantial Decoupling of Desolvation and Bond Formation // Journal of the American Chemical Society. 2002. Vol. 124. No. 30. pp. 8766-8767.
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Buncel E., Cannes C., Chatrousse A., Terrier F. Reactions of Oximate α-Nucleophiles with Esters: Evidence from Solvation Effects for Substantial Decoupling of Desolvation and Bond Formation // Journal of the American Chemical Society. 2002. Vol. 124. No. 30. pp. 8766-8767.
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TY - JOUR
DO - 10.1021/ja020379k
UR - https://doi.org/10.1021/ja020379k
TI - Reactions of Oximate α-Nucleophiles with Esters: Evidence from Solvation Effects for Substantial Decoupling of Desolvation and Bond Formation
T2 - Journal of the American Chemical Society
AU - Buncel, Erwin
AU - Cannes, Céline
AU - Chatrousse, Alain-Pierre
AU - Terrier, François
PY - 2002
DA - 2002/07/01
PB - American Chemical Society (ACS)
SP - 8766-8767
IS - 30
VL - 124
PMID - 12137508
SN - 0002-7863
SN - 1520-5126
ER -
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BibTex (до 50 авторов)
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@article{2002_Buncel,
author = {Erwin Buncel and Céline Cannes and Alain-Pierre Chatrousse and François Terrier},
title = {Reactions of Oximate α-Nucleophiles with Esters: Evidence from Solvation Effects for Substantial Decoupling of Desolvation and Bond Formation},
journal = {Journal of the American Chemical Society},
year = {2002},
volume = {124},
publisher = {American Chemical Society (ACS)},
month = {jul},
url = {https://doi.org/10.1021/ja020379k},
number = {30},
pages = {8766--8767},
doi = {10.1021/ja020379k}
}
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MLA
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Buncel, Erwin, et al. “Reactions of Oximate α-Nucleophiles with Esters: Evidence from Solvation Effects for Substantial Decoupling of Desolvation and Bond Formation.” Journal of the American Chemical Society, vol. 124, no. 30, Jul. 2002, pp. 8766-8767. https://doi.org/10.1021/ja020379k.