The First Silastannene >SiSn<: A New Doubly-Bonded System of Heavier Group 14 Elements
Тип публикации: Journal Article
Дата публикации: 2002-11-20
scimago Q1
wos Q1
БС1
SJR: 5.489
CiteScore: 24.4
Impact factor: 15.6
ISSN: 00027863, 15205126
PubMed ID:
12475304
General Chemistry
Catalysis
Biochemistry
Colloid and Surface Chemistry
Краткое описание
The reaction of bis[di-tert-butyl(methyl)silyl]dilithiosilane 1 with dichlorobis(2,4,6-triisopropylphenyl)stannane in THF at room temperature yielded highly air- and moisture-sensitive deep violet crystals of 1,1-bis[di-tert-butyl(methyl)silyl]-2,2-bis(2,4,6-triisopropylphenyl)-1-sila-2-stannaethene 2 with a Si=Sn double bond. The molecular structure of 2 was established by X-ray crystallography, which showed a trans-bent structure (bending angles of 26.2 degrees for the sp2 Si atom and 9.6 degrees for the sp2 Sn atom) with a >Si=Sn< bond length of 2.4188(14) A and a twisting angle of 34.6 degrees . The geometry and regioselectivity of the addition reaction of PhEH (E = O and S) corresponds to the polarity of the double bond Sidelta-=Sndelta+, which is also supported by theoretical calculations on the model silastannene (H3Si)2Si=SnPh2.
Найдено
Ничего не найдено, попробуйте изменить настройки фильтра.
Для доступа к списку цитирований публикации необходимо авторизоваться.
Топ-30
Журналы
|
2
4
6
8
10
|
|
|
Organometallics
10 публикаций, 16.95%
|
|
|
Journal of the American Chemical Society
7 публикаций, 11.86%
|
|
|
Angewandte Chemie
4 публикации, 6.78%
|
|
|
Angewandte Chemie - International Edition
4 публикации, 6.78%
|
|
|
Chemistry Letters
3 публикации, 5.08%
|
|
|
Dalton Transactions
3 публикации, 5.08%
|
|
|
Coordination Chemistry Reviews
2 публикации, 3.39%
|
|
|
Chemistry - A European Journal
2 публикации, 3.39%
|
|
|
Bulletin of the Chemical Society of Japan
1 публикация, 1.69%
|
|
|
Yuki Gosei Kagaku Kyokaishi/Journal of Synthetic Organic Chemistry
1 публикация, 1.69%
|
|
|
Silicon Chemistry
1 публикация, 1.69%
|
|
|
Computational and Theoretical Chemistry
1 публикация, 1.69%
|
|
|
Mendeleev Communications
1 публикация, 1.69%
|
|
|
Nachrichten aus der Chemie
1 публикация, 1.69%
|
|
|
Chemistry - An Asian Journal
1 публикация, 1.69%
|
|
|
European Journal of Inorganic Chemistry
1 публикация, 1.69%
|
|
|
Chemical Reviews
1 публикация, 1.69%
|
|
|
Inorganic Chemistry
1 публикация, 1.69%
|
|
|
Chemical Communications
1 публикация, 1.69%
|
|
|
Phosphorus, Sulfur and Silicon and the Related Elements
1 публикация, 1.69%
|
|
|
Structure Types. Part 10: Space Groups (140) I4/mcm – (136) P42/mnm
1 публикация, 1.69%
|
|
|
2
4
6
8
10
|
Издатели
|
2
4
6
8
10
12
14
16
18
20
|
|
|
American Chemical Society (ACS)
19 публикаций, 32.2%
|
|
|
Wiley
14 публикаций, 23.73%
|
|
|
Elsevier
9 публикаций, 15.25%
|
|
|
Oxford University Press
4 публикации, 6.78%
|
|
|
Royal Society of Chemistry (RSC)
4 публикации, 6.78%
|
|
|
Springer Nature
2 публикации, 3.39%
|
|
|
The Society of Synthetic Organic Chemistry, Japan
1 публикация, 1.69%
|
|
|
OOO Zhurnal "Mendeleevskie Soobshcheniya"
1 публикация, 1.69%
|
|
|
Taylor & Francis
1 публикация, 1.69%
|
|
|
2
4
6
8
10
12
14
16
18
20
|
- Мы не учитываем публикации, у которых нет DOI.
- Статистика публикаций обновляется еженедельно.
Вы ученый?
Создайте профиль, чтобы получать персональные рекомендации коллег, конференций и новых статей.
Метрики
59
Всего цитирований:
59
Цитирований c 2025:
1
(1.69%)
Цитировать
ГОСТ |
RIS |
BibTex |
MLA
Цитировать
ГОСТ
Скопировать
Sekiguchi A. et al. The First Silastannene >SiSn<: A New Doubly-Bonded System of Heavier Group 14 Elements // Journal of the American Chemical Society. 2002. Vol. 124. No. 50. pp. 14822-14823.
ГОСТ со всеми авторами (до 50)
Скопировать
Sekiguchi A., Izumi R., Lee V. Y., Ichinohe M. The First Silastannene >SiSn<: A New Doubly-Bonded System of Heavier Group 14 Elements // Journal of the American Chemical Society. 2002. Vol. 124. No. 50. pp. 14822-14823.
Цитировать
RIS
Скопировать
TY - JOUR
DO - 10.1021/ja021077l
UR - https://doi.org/10.1021/ja021077l
TI - The First Silastannene >SiSn<: A New Doubly-Bonded System of Heavier Group 14 Elements
T2 - Journal of the American Chemical Society
AU - Sekiguchi, Akira
AU - Izumi, Rika
AU - Lee, Vladimir Ya.
AU - Ichinohe, Masaaki
PY - 2002
DA - 2002/11/20
PB - American Chemical Society (ACS)
SP - 14822-14823
IS - 50
VL - 124
PMID - 12475304
SN - 0002-7863
SN - 1520-5126
ER -
Цитировать
BibTex (до 50 авторов)
Скопировать
@article{2002_Sekiguchi,
author = {Akira Sekiguchi and Rika Izumi and Vladimir Ya. Lee and Masaaki Ichinohe},
title = {The First Silastannene >SiSn<: A New Doubly-Bonded System of Heavier Group 14 Elements},
journal = {Journal of the American Chemical Society},
year = {2002},
volume = {124},
publisher = {American Chemical Society (ACS)},
month = {nov},
url = {https://doi.org/10.1021/ja021077l},
number = {50},
pages = {14822--14823},
doi = {10.1021/ja021077l}
}
Цитировать
MLA
Скопировать
Sekiguchi, Akira, et al. “The First Silastannene >SiSn<: A New Doubly-Bonded System of Heavier Group 14 Elements.” Journal of the American Chemical Society, vol. 124, no. 50, Nov. 2002, pp. 14822-14823. https://doi.org/10.1021/ja021077l.