Activation of Nitrous Oxide and Selective Epoxidation of Alkenes Catalyzed by the Manganese-Substituted Polyoxometalate, [MnIII2ZnW(Zn2W9O34)2]10-
Тип публикации: Journal Article
Дата публикации: 2002-07-01
scimago Q1
wos Q1
БС1
SJR: 5.489
CiteScore: 24.4
Impact factor: 15.6
ISSN: 00027863, 15205126
PubMed ID:
12137519
General Chemistry
Catalysis
Biochemistry
Colloid and Surface Chemistry
Краткое описание
A manganese(III)-substituted polyoxometalate of the "sandwich" structure, [MnIII2ZnW(ZnW9O34)2]10-, catalyzed the highly selective (>99.9%) epoxidation of alkenes, such as 1-octene, 2-octene, and cyclohexene with nitrous oxide. Reactions occurred in homogeneous media at 150 degrees C under 1 atm N2O. The epoxidation had a linear reaction profile; turnover frequencies of 0.5-1.4 h-1 were measured. The reactions were also stereoselective; for example, cis-stilbene gave cis-stilbene oxide. From ESR spectroscopy, it was shown that a Mn(II) octahedral species is reversibly formed by reaction between the original Mn(III) polyoxometalate and N2O. Therefore, it would appear that a Mn(V)-oxo active species is not formed; it is possible that the activation of nitrous oxide was by its oxidation by the Mn(III) polyoxometalate.
Найдено
Ничего не найдено, попробуйте изменить настройки фильтра.
Для доступа к списку цитирований публикации необходимо авторизоваться.
Для доступа к списку профилей, цитирующих публикацию, необходимо авторизоваться.
Топ-30
Журналы
|
1
2
3
4
5
6
7
8
|
|
|
Dalton Transactions
8 публикаций, 8.33%
|
|
|
Inorganic Chemistry
6 публикаций, 6.25%
|
|
|
Journal of the American Chemical Society
5 публикаций, 5.21%
|
|
|
Organometallics
5 публикаций, 5.21%
|
|
|
Angewandte Chemie - International Edition
4 публикации, 4.17%
|
|
|
Biological Trace Element Research
3 публикации, 3.13%
|
|
|
Applied Catalysis B: Environmental
3 публикации, 3.13%
|
|
|
Inorganica Chimica Acta
3 публикации, 3.13%
|
|
|
Chemistry - A European Journal
3 публикации, 3.13%
|
|
|
Angewandte Chemie
3 публикации, 3.13%
|
|
|
Coordination Chemistry Reviews
2 публикации, 2.08%
|
|
|
Journal of Electroanalytical Chemistry
2 публикации, 2.08%
|
|
|
Tetrahedron
2 публикации, 2.08%
|
|
|
Inorganic Chemistry Communication
2 публикации, 2.08%
|
|
|
European Journal of Inorganic Chemistry
2 публикации, 2.08%
|
|
|
Journal of Materials Chemistry A
2 публикации, 2.08%
|
|
|
Phosphorus, Sulfur and Silicon and the Related Elements
1 публикация, 1.04%
|
|
|
Mendeleev Communications
1 публикация, 1.04%
|
|
|
Bulletin of the Chemical Society of Japan
1 публикация, 1.04%
|
|
|
Catalysis Communications
1 публикация, 1.04%
|
|
|
Journal of Colloid and Interface Science
1 публикация, 1.04%
|
|
|
Inorganics
1 публикация, 1.04%
|
|
|
Research on Chemical Intermediates
1 публикация, 1.04%
|
|
|
Kinetics and Catalysis
1 публикация, 1.04%
|
|
|
Russian Chemical Bulletin
1 публикация, 1.04%
|
|
|
Colloid and Polymer Science
1 публикация, 1.04%
|
|
|
Transition Metal Chemistry
1 публикация, 1.04%
|
|
|
Chinese Chemical Letters
1 публикация, 1.04%
|
|
|
Journal of Molecular Graphics and Modelling
1 публикация, 1.04%
|
|
|
1
2
3
4
5
6
7
8
|
Издатели
|
5
10
15
20
25
30
|
|
|
Elsevier
27 публикаций, 28.13%
|
|
|
American Chemical Society (ACS)
21 публикация, 21.88%
|
|
|
Wiley
16 публикаций, 16.67%
|
|
|
Royal Society of Chemistry (RSC)
14 публикаций, 14.58%
|
|
|
Springer Nature
7 публикаций, 7.29%
|
|
|
Taylor & Francis
3 публикации, 3.13%
|
|
|
OOO Zhurnal "Mendeleevskie Soobshcheniya"
1 публикация, 1.04%
|
|
|
Oxford University Press
1 публикация, 1.04%
|
|
|
MDPI
1 публикация, 1.04%
|
|
|
Pleiades Publishing
1 публикация, 1.04%
|
|
|
5
10
15
20
25
30
|
- Мы не учитываем публикации, у которых нет DOI.
- Статистика публикаций обновляется еженедельно.
Вы ученый?
Создайте профиль, чтобы получать персональные рекомендации коллег, конференций и новых статей.
Метрики
96
Всего цитирований:
96
Цитирований c 2025:
2
(2.08%)
Цитировать
ГОСТ |
RIS |
BibTex |
MLA
Цитировать
ГОСТ
Скопировать
Ben Daniel R., Weiner L., Neumann R. Activation of Nitrous Oxide and Selective Epoxidation of Alkenes Catalyzed by the Manganese-Substituted Polyoxometalate, [MnIII2ZnW(Zn2W9O34)2]10- // Journal of the American Chemical Society. 2002. Vol. 124. No. 30. pp. 8788-8789.
ГОСТ со всеми авторами (до 50)
Скопировать
Ben Daniel R., Weiner L., Neumann R. Activation of Nitrous Oxide and Selective Epoxidation of Alkenes Catalyzed by the Manganese-Substituted Polyoxometalate, [MnIII2ZnW(Zn2W9O34)2]10- // Journal of the American Chemical Society. 2002. Vol. 124. No. 30. pp. 8788-8789.
Цитировать
RIS
Скопировать
TY - JOUR
DO - 10.1021/ja0259077
UR - https://doi.org/10.1021/ja0259077
TI - Activation of Nitrous Oxide and Selective Epoxidation of Alkenes Catalyzed by the Manganese-Substituted Polyoxometalate, [MnIII2ZnW(Zn2W9O34)2]10-
T2 - Journal of the American Chemical Society
AU - Ben Daniel, Revital
AU - Weiner, Lev
AU - Neumann, Ronny
PY - 2002
DA - 2002/07/01
PB - American Chemical Society (ACS)
SP - 8788-8789
IS - 30
VL - 124
PMID - 12137519
SN - 0002-7863
SN - 1520-5126
ER -
Цитировать
BibTex (до 50 авторов)
Скопировать
@article{2002_Ben Daniel,
author = {Revital Ben Daniel and Lev Weiner and Ronny Neumann},
title = {Activation of Nitrous Oxide and Selective Epoxidation of Alkenes Catalyzed by the Manganese-Substituted Polyoxometalate, [MnIII2ZnW(Zn2W9O34)2]10-},
journal = {Journal of the American Chemical Society},
year = {2002},
volume = {124},
publisher = {American Chemical Society (ACS)},
month = {jul},
url = {https://doi.org/10.1021/ja0259077},
number = {30},
pages = {8788--8789},
doi = {10.1021/ja0259077}
}
Цитировать
MLA
Скопировать
Ben Daniel, Revital, et al. “Activation of Nitrous Oxide and Selective Epoxidation of Alkenes Catalyzed by the Manganese-Substituted Polyoxometalate, [MnIII2ZnW(Zn2W9O34)2]10-.” Journal of the American Chemical Society, vol. 124, no. 30, Jul. 2002, pp. 8788-8789. https://doi.org/10.1021/ja0259077.