A Highly Enantioselective Catalytic Intramolecular Stetter Reaction
Publication type: Journal Article
Publication date: 2002-08-10
scimago Q1
wos Q1
SJR: 5.554
CiteScore: 22.5
Impact factor: 15.6
ISSN: 00027863, 15205126
PubMed ID:
12197730
General Chemistry
Catalysis
Biochemistry
Colloid and Surface Chemistry
Abstract
A family of chiral triazolium salts has been developed for inducing the asymmetric intramolecular Stetter reaction. The use of an aminoindanol-derived catalyst affords optimal results, with the product keto esters formed in 82-97% ee and very good chemical yield. Aromatic and aliphatic aldehydes are equally competent substrates for this reaction. The reaction conditions are reasonably mild and allow the isolation of the newly formed stereocenter without epimerization, although the presumed carbenic intermediates are strong bases.
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459
Total citations:
459
Citations from 2025:
10
(2.18%)
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GOST
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Kerr M. S., Read De Alaniz J., Rovis T. A Highly Enantioselective Catalytic Intramolecular Stetter Reaction // Journal of the American Chemical Society. 2002. Vol. 124. No. 35. pp. 10298-10299.
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Kerr M. S., Read De Alaniz J., Rovis T. A Highly Enantioselective Catalytic Intramolecular Stetter Reaction // Journal of the American Chemical Society. 2002. Vol. 124. No. 35. pp. 10298-10299.
Cite this
RIS
Copy
TY - JOUR
DO - 10.1021/ja027411v
UR - https://doi.org/10.1021/ja027411v
TI - A Highly Enantioselective Catalytic Intramolecular Stetter Reaction
T2 - Journal of the American Chemical Society
AU - Kerr, Mark S
AU - Read De Alaniz, J
AU - Rovis, Tomislav
PY - 2002
DA - 2002/08/10
PB - American Chemical Society (ACS)
SP - 10298-10299
IS - 35
VL - 124
PMID - 12197730
SN - 0002-7863
SN - 1520-5126
ER -
Cite this
BibTex (up to 50 authors)
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@article{2002_Kerr,
author = {Mark S Kerr and J Read De Alaniz and Tomislav Rovis},
title = {A Highly Enantioselective Catalytic Intramolecular Stetter Reaction},
journal = {Journal of the American Chemical Society},
year = {2002},
volume = {124},
publisher = {American Chemical Society (ACS)},
month = {aug},
url = {https://doi.org/10.1021/ja027411v},
number = {35},
pages = {10298--10299},
doi = {10.1021/ja027411v}
}
Cite this
MLA
Copy
Kerr, Mark S., et al. “A Highly Enantioselective Catalytic Intramolecular Stetter Reaction.” Journal of the American Chemical Society, vol. 124, no. 35, Aug. 2002, pp. 10298-10299. https://doi.org/10.1021/ja027411v.