EXAFS Investigations of the Mechanism of Facilitated Ion Transfer into a Room-Temperature Ionic Liquid
Тип публикации: Journal Article
Дата публикации: 2002-08-16
scimago Q1
wos Q1
БС1
SJR: 5.489
CiteScore: 24.4
Impact factor: 15.6
ISSN: 00027863, 15205126
PubMed ID:
12207515
General Chemistry
Catalysis
Biochemistry
Colloid and Surface Chemistry
Краткое описание
The Sr(II)-crown ether complexes formed in a room-temperature ionic liquid (RTIL), 1-methyl-3-pentylimidazolium bis[(trifluoromethyl)sulfonyl]amide, have been studied by X-ray absorption fine structure measurements at the Sr K-edge. When a Sr(NO(3))(2)-crown ether complex is directly dissolved in a water-saturated RTIL, both nitrate ligands and the crown ether coordinate the Sr, as observed in a conventional two-phase water-octanol system. When the cationic Sr-crown ether complex is created in a two-phase water-RTIL system, however, only cationic Sr-crown ether complexes are observed in the RTIL phase. This difference in the coordination complexes arises from differences in the mechanism of cation extraction between the RTIL and conventional molecular organic solvents, a finding with important implications for synthesis, catalysis, and ion separations using two-phase water-RTIL systems.
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ГОСТ
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Jensen M. P. et al. EXAFS Investigations of the Mechanism of Facilitated Ion Transfer into a Room-Temperature Ionic Liquid // Journal of the American Chemical Society. 2002. Vol. 124. No. 36. pp. 10664-10665.
ГОСТ со всеми авторами (до 50)
Скопировать
Jensen M. P., Dzielawa J. A., Rickert P., Dietz M. L. EXAFS Investigations of the Mechanism of Facilitated Ion Transfer into a Room-Temperature Ionic Liquid // Journal of the American Chemical Society. 2002. Vol. 124. No. 36. pp. 10664-10665.
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RIS
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TY - JOUR
DO - 10.1021/ja027476y
UR - https://doi.org/10.1021/ja027476y
TI - EXAFS Investigations of the Mechanism of Facilitated Ion Transfer into a Room-Temperature Ionic Liquid
T2 - Journal of the American Chemical Society
AU - Jensen, Mark P
AU - Dzielawa, Julie A.
AU - Rickert, Paul
AU - Dietz, Mark L.
PY - 2002
DA - 2002/08/16
PB - American Chemical Society (ACS)
SP - 10664-10665
IS - 36
VL - 124
PMID - 12207515
SN - 0002-7863
SN - 1520-5126
ER -
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BibTex (до 50 авторов)
Скопировать
@article{2002_Jensen,
author = {Mark P Jensen and Julie A. Dzielawa and Paul Rickert and Mark L. Dietz},
title = {EXAFS Investigations of the Mechanism of Facilitated Ion Transfer into a Room-Temperature Ionic Liquid},
journal = {Journal of the American Chemical Society},
year = {2002},
volume = {124},
publisher = {American Chemical Society (ACS)},
month = {aug},
url = {https://doi.org/10.1021/ja027476y},
number = {36},
pages = {10664--10665},
doi = {10.1021/ja027476y}
}
Цитировать
MLA
Скопировать
Jensen, Mark P., et al. “EXAFS Investigations of the Mechanism of Facilitated Ion Transfer into a Room-Temperature Ionic Liquid.” Journal of the American Chemical Society, vol. 124, no. 36, Aug. 2002, pp. 10664-10665. https://doi.org/10.1021/ja027476y.