Journal of the American Chemical Society, volume 124, issue 48, pages 14284-14285
High-Activity, Single-Site Catalysts for the Alternating Copolymerization of CO2 and Propylene Oxide
Publication type: Journal Article
Publication date: 2002-11-08
Q1
Q1
SJR: 5.489
CiteScore: 24.4
Impact factor: 14.4
ISSN: 00027863, 15205126
General Chemistry
Catalysis
Biochemistry
Colloid and Surface Chemistry
Abstract
Despite recent advances regarding catalysts for CO2/epoxide copolymerization, the development of high-activity catalysts for alternating polymerization of CO2 and commodity epoxides, such as propylene oxide, remains a challenge. A new class of unsymmetrically substituted beta-diiminate zinc complexes is reported that exhibits unprecedented activity for CO2/propylene oxide copolymerization. The polymers formed are of high molecular weight (Mn approximately 35 kg/mol) and have narrow polydispersities (PDI approximately 1.1), consistent with a living polymerization.
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Allen S. D. et al. High-Activity, Single-Site Catalysts for the Alternating Copolymerization of CO2 and Propylene Oxide // Journal of the American Chemical Society. 2002. Vol. 124. No. 48. pp. 14284-14285.
GOST all authors (up to 50)
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Allen S. D., Moore D. R., Lobkovsky E. B., Coates G. W. High-Activity, Single-Site Catalysts for the Alternating Copolymerization of CO2 and Propylene Oxide // Journal of the American Chemical Society. 2002. Vol. 124. No. 48. pp. 14284-14285.
Cite this
RIS
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TY - JOUR
DO - 10.1021/ja028071g
UR - https://doi.org/10.1021/ja028071g
TI - High-Activity, Single-Site Catalysts for the Alternating Copolymerization of CO2 and Propylene Oxide
T2 - Journal of the American Chemical Society
AU - Allen, Scott D
AU - Moore, David R.
AU - Lobkovsky, Emil B.
AU - Coates, Geoffrey W.
PY - 2002
DA - 2002/11/08
PB - American Chemical Society (ACS)
SP - 14284-14285
IS - 48
VL - 124
SN - 0002-7863
SN - 1520-5126
ER -
Cite this
BibTex (up to 50 authors)
Copy
@article{2002_Allen,
author = {Scott D Allen and David R. Moore and Emil B. Lobkovsky and Geoffrey W. Coates},
title = {High-Activity, Single-Site Catalysts for the Alternating Copolymerization of CO2 and Propylene Oxide},
journal = {Journal of the American Chemical Society},
year = {2002},
volume = {124},
publisher = {American Chemical Society (ACS)},
month = {nov},
url = {https://doi.org/10.1021/ja028071g},
number = {48},
pages = {14284--14285},
doi = {10.1021/ja028071g}
}
Cite this
MLA
Copy
Allen, Scott D., et al. “High-Activity, Single-Site Catalysts for the Alternating Copolymerization of CO2 and Propylene Oxide.” Journal of the American Chemical Society, vol. 124, no. 48, Nov. 2002, pp. 14284-14285. https://doi.org/10.1021/ja028071g.