Lanthanide Double-Decker Complexes Functioning as Magnets at the Single-Molecular Level
Тип публикации: Journal Article
Дата публикации: 2003-06-25
SCImago Q1
Tоп 10% SCImago
WOS Q1
БС1
SJR: 5.491
CiteScore: 22
Impact factor: 16.6
ISSN: 00027863, 15205126
PubMed ID:
12862442
General Chemistry
Catalysis
Biochemistry
Colloid and Surface Chemistry
Краткое описание
Double-decker phthalocyanine complexes with Tb3+ or Dy3+ showed slow magnetization relaxation as a single-molecular property. The temperature ranges in which the behavior was observed were far higher than that of the transition-metal-cluster single-molecule magnets (SMMs). The significant temperature rise results from a mechanism in the relaxation process different from that in the transition-metal-cluster SMMs. The effective energy barrier for reversal of the magnetic moment is determined by the ligand field around a lanthanide ion, which gives the lowest degenerate substate a large |Jz| value and large energy separations from the rest of the substates in the ground-state multiplets.
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ISHIKAWA N. et al. Lanthanide Double-Decker Complexes Functioning as Magnets at the Single-Molecular Level // Journal of the American Chemical Society. 2003. Vol. 125. No. 29. pp. 8694-8695.
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ISHIKAWA N., Sugita M., Ishikawa T., Koshihara S., KAIZU Y. Lanthanide Double-Decker Complexes Functioning as Magnets at the Single-Molecular Level // Journal of the American Chemical Society. 2003. Vol. 125. No. 29. pp. 8694-8695.
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TY - JOUR
DO - 10.1021/ja029629n
UR - https://doi.org/10.1021/ja029629n
TI - Lanthanide Double-Decker Complexes Functioning as Magnets at the Single-Molecular Level
T2 - Journal of the American Chemical Society
AU - ISHIKAWA, Naoto
AU - Sugita, Miki
AU - Ishikawa, Tadahiko
AU - Koshihara, Shin-ya
AU - KAIZU, YOUKOH
PY - 2003
DA - 2003/06/25
PB - American Chemical Society (ACS)
SP - 8694-8695
IS - 29
VL - 125
PMID - 12862442
SN - 0002-7863
SN - 1520-5126
ER -
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@article{2003_ISHIKAWA,
author = {Naoto ISHIKAWA and Miki Sugita and Tadahiko Ishikawa and Shin-ya Koshihara and YOUKOH KAIZU},
title = {Lanthanide Double-Decker Complexes Functioning as Magnets at the Single-Molecular Level},
journal = {Journal of the American Chemical Society},
year = {2003},
volume = {125},
publisher = {American Chemical Society (ACS)},
month = {jun},
url = {https://doi.org/10.1021/ja029629n},
number = {29},
pages = {8694--8695},
doi = {10.1021/ja029629n}
}
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MLA
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ISHIKAWA, Naoto, et al. “Lanthanide Double-Decker Complexes Functioning as Magnets at the Single-Molecular Level.” Journal of the American Chemical Society, vol. 125, no. 29, Jun. 2003, pp. 8694-8695. https://doi.org/10.1021/ja029629n.
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