Hexagonal Columnar Porphyrin Assembly by Unique Trimeric Complexation of a Porphyrin Dimer with π−π Stacking: Remarkable Thermal Behavior in a Solid
Тип публикации: Journal Article
Дата публикации: 2003-09-13
scimago Q1
wos Q1
БС1
SJR: 5.489
CiteScore: 24.4
Impact factor: 15.6
ISSN: 00027863, 15205126
PubMed ID:
14518980
General Chemistry
Catalysis
Biochemistry
Colloid and Surface Chemistry
Краткое описание
On heating, syn-diporphyrin zinc complexes fused with bis(ethano)dimethoxyanthracene, the crystal structure of which showed a unique trimeric assembly, extruded one ethylene molecule at 240-310 degrees C to give a porphyrin-naphthoporphyrin diad, and the second retro-Diels-Alder reaction and concomitant decomposition of the methoxy groups occurred at 280-350 degrees C to give the anthraquinone-fused diporphyrin, while the first thermal conversion of the anti-diporphyrin zinc complex occurred in a much lower temperature range (180-230 degrees C).
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Uno H., Masumoto A., Ono N. Hexagonal Columnar Porphyrin Assembly by Unique Trimeric Complexation of a Porphyrin Dimer with π−π Stacking: Remarkable Thermal Behavior in a Solid // Journal of the American Chemical Society. 2003. Vol. 125. No. 40. pp. 12082-12083.
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Uno H., Masumoto A., Ono N. Hexagonal Columnar Porphyrin Assembly by Unique Trimeric Complexation of a Porphyrin Dimer with π−π Stacking: Remarkable Thermal Behavior in a Solid // Journal of the American Chemical Society. 2003. Vol. 125. No. 40. pp. 12082-12083.
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TY - JOUR
DO - 10.1021/ja036203f
UR - https://doi.org/10.1021/ja036203f
TI - Hexagonal Columnar Porphyrin Assembly by Unique Trimeric Complexation of a Porphyrin Dimer with π−π Stacking: Remarkable Thermal Behavior in a Solid
T2 - Journal of the American Chemical Society
AU - Uno, Hidemitsu
AU - Masumoto, Akane
AU - Ono, Noboru
PY - 2003
DA - 2003/09/13
PB - American Chemical Society (ACS)
SP - 12082-12083
IS - 40
VL - 125
PMID - 14518980
SN - 0002-7863
SN - 1520-5126
ER -
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@article{2003_Uno,
author = {Hidemitsu Uno and Akane Masumoto and Noboru Ono},
title = {Hexagonal Columnar Porphyrin Assembly by Unique Trimeric Complexation of a Porphyrin Dimer with π−π Stacking: Remarkable Thermal Behavior in a Solid},
journal = {Journal of the American Chemical Society},
year = {2003},
volume = {125},
publisher = {American Chemical Society (ACS)},
month = {sep},
url = {https://doi.org/10.1021/ja036203f},
number = {40},
pages = {12082--12083},
doi = {10.1021/ja036203f}
}
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MLA
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Uno, Hidemitsu, et al. “Hexagonal Columnar Porphyrin Assembly by Unique Trimeric Complexation of a Porphyrin Dimer with π−π Stacking: Remarkable Thermal Behavior in a Solid.” Journal of the American Chemical Society, vol. 125, no. 40, Sep. 2003, pp. 12082-12083. https://doi.org/10.1021/ja036203f.