Electrocatalytic Activity of Ordered Intermetallic Phases for Fuel Cell Applications
Тип публикации: Journal Article
Дата публикации: 2004-03-01
scimago Q1
wos Q1
БС1
SJR: 5.489
CiteScore: 24.4
Impact factor: 15.6
ISSN: 00027863, 15205126
PubMed ID:
15038758
General Chemistry
Catalysis
Biochemistry
Colloid and Surface Chemistry
Краткое описание
The electrocatalytic activities of a wide range of ordered intermetallic phases toward a variety of potential fuels have been studied, and results have been compared to those of a pure polycrystalline platinum (Pt(pc)) electrode. A significant number of the ordered intermetallic phases exhibited enhanced electrocatalytic activity when compared to that of Pt, in terms of both oxidation onset potential and current density. The PtBi, PtIn, and PtPb ordered intermetallic phases appeared to be the most promising electrocatalysts tested thus far for fuel cell applications. PtPb, in particular, showed an onset potential that was 100 mV less positive and a peak current density approximately 40 times higher than those observed for Pt in the case of methanol oxidation. The ability to control the geometric and electronic structures of the electrocatalytic material by using ordered intermetallic phases has been shown to be a promising direction of inquiry in the search for superior electrocatalysts for fuel cell applications.
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Casado Rivera E. et al. Electrocatalytic Activity of Ordered Intermetallic Phases for Fuel Cell Applications // Journal of the American Chemical Society. 2004. Vol. 126. No. 12. pp. 4043-4049.
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Скопировать
Casado Rivera E., Volpe D. J., Alden L., Lind C., Downie C., Vázquez-Alvarez T., Angelo A. C., DiSalvo F. J., Abruña H. D. Electrocatalytic Activity of Ordered Intermetallic Phases for Fuel Cell Applications // Journal of the American Chemical Society. 2004. Vol. 126. No. 12. pp. 4043-4049.
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RIS
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TY - JOUR
DO - 10.1021/ja038497a
UR - https://doi.org/10.1021/ja038497a
TI - Electrocatalytic Activity of Ordered Intermetallic Phases for Fuel Cell Applications
T2 - Journal of the American Chemical Society
AU - Casado Rivera, Emerilis
AU - Volpe, David J
AU - Alden, Laif
AU - Lind, C.
AU - Downie, Craig
AU - Vázquez-Alvarez, Terannie
AU - Angelo, Antonio C.D.
AU - DiSalvo, Francis J.
AU - Abruña, Héctor D.
PY - 2004
DA - 2004/03/01
PB - American Chemical Society (ACS)
SP - 4043-4049
IS - 12
VL - 126
PMID - 15038758
SN - 0002-7863
SN - 1520-5126
ER -
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@article{2004_Casado Rivera,
author = {Emerilis Casado Rivera and David J Volpe and Laif Alden and C. Lind and Craig Downie and Terannie Vázquez-Alvarez and Antonio C.D. Angelo and Francis J. DiSalvo and Héctor D. Abruña},
title = {Electrocatalytic Activity of Ordered Intermetallic Phases for Fuel Cell Applications},
journal = {Journal of the American Chemical Society},
year = {2004},
volume = {126},
publisher = {American Chemical Society (ACS)},
month = {mar},
url = {https://doi.org/10.1021/ja038497a},
number = {12},
pages = {4043--4049},
doi = {10.1021/ja038497a}
}
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MLA
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Casado Rivera, Emerilis, et al. “Electrocatalytic Activity of Ordered Intermetallic Phases for Fuel Cell Applications.” Journal of the American Chemical Society, vol. 126, no. 12, Mar. 2004, pp. 4043-4049. https://doi.org/10.1021/ja038497a.