Expanding the scope of C-H amination through catalyst design.
Publication type: Journal Article
Publication date: 2004-11-09
scimago Q1
wos Q1
SJR: 5.554
CiteScore: 22.5
Impact factor: 15.6
ISSN: 00027863, 15205126
PubMed ID:
15563154
General Chemistry
Catalysis
Biochemistry
Colloid and Surface Chemistry
Abstract
Analysis of the mechanism for Rh-mediated C-H amination has led to the development of a remarkably effective dinuclear Rh catalyst derived from 1,3-benzenedipropionic acid. This unique complex, Rh2(esp)2, is capable of promoting both intra- and intermolecular C-H oxidation reactions, and in all cases is superior to Rh2(O2CtBu)4. For the first time, C-H insertion is described with urea and sulfamide substrates to give 1,2- and 1,3-diamine derivatives, respectively. In addition, intermolecular amination of benzylic and secondary C-H bonds is shown to proceed efficiently even under conditions in which the starting alkane is employed as the limiting reagent.
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Metrics
604
Total citations:
604
Citations from 2025:
9
(1.49%)
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GOST
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Espino C. G. et al. Expanding the scope of C-H amination through catalyst design. // Journal of the American Chemical Society. 2004. Vol. 126. No. 47. pp. 15378-15379.
GOST all authors (up to 50)
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Espino C. G., Fiori K. W., Kim M., Du Bois J. S. Expanding the scope of C-H amination through catalyst design. // Journal of the American Chemical Society. 2004. Vol. 126. No. 47. pp. 15378-15379.
Cite this
RIS
Copy
TY - JOUR
DO - 10.1021/ja0446294
UR - https://doi.org/10.1021/ja0446294
TI - Expanding the scope of C-H amination through catalyst design.
T2 - Journal of the American Chemical Society
AU - Espino, Christine G
AU - Fiori, Kristin Williams
AU - Kim, Mihyong
AU - Du Bois, Jon S.
PY - 2004
DA - 2004/11/09
PB - American Chemical Society (ACS)
SP - 15378-15379
IS - 47
VL - 126
PMID - 15563154
SN - 0002-7863
SN - 1520-5126
ER -
Cite this
BibTex (up to 50 authors)
Copy
@article{2004_Espino,
author = {Christine G Espino and Kristin Williams Fiori and Mihyong Kim and Jon S. Du Bois},
title = {Expanding the scope of C-H amination through catalyst design.},
journal = {Journal of the American Chemical Society},
year = {2004},
volume = {126},
publisher = {American Chemical Society (ACS)},
month = {nov},
url = {https://doi.org/10.1021/ja0446294},
number = {47},
pages = {15378--15379},
doi = {10.1021/ja0446294}
}
Cite this
MLA
Copy
Espino, Christine G., et al. “Expanding the scope of C-H amination through catalyst design..” Journal of the American Chemical Society, vol. 126, no. 47, Nov. 2004, pp. 15378-15379. https://doi.org/10.1021/ja0446294.