Bistability and the Phase Transition in 1,3,2-Dithiazolo[4,5-b]pyrazin-2-yl
Benoît H. Lessard
1
,
Owen P Clements
1
,
Robert C. Haddon
1
,
Mikhail E Itkis
1
,
Alicea A. Leitch
1
,
Richard Oakley
1
,
Robert W Reed
1
,
John F. Richardson
1
Publication type: Journal Article
Publication date: 2004-10-23
scimago Q1
wos Q1
SJR: 5.554
CiteScore: 22.5
Impact factor: 15.6
ISSN: 00027863, 15205126
PubMed ID:
15535673
General Chemistry
Catalysis
Biochemistry
Colloid and Surface Chemistry
Abstract
The molecular radical 1,3,2-dithiazolo[4,5-b]pyrazin-2-yl (PDTA) exhibits magnetic bistability just above room temperature, undergoing a well-defined hysteretic phase change with TC downward arrow = 297(1) K and TC upward arrow = 343(1) K. The crystal structures of the two phases of PDTA have been determined by single-crystal X-ray diffraction at 323(2) K. LT-PDTA consists of diamagnetic (S = 0) nearly superimposed pi-dimer stacks, while that of HT-PDTA comprises slipped stacks of pi-radicals (S = 1/2). The structural interconversion is suggested to proceed via the cooperative breaking and making of intermolecular S- - -N interactions and an inversion symmetry-preserving "domino cascade" of the pi-stacked rings.
Found
Nothing found, try to update filter.
Found
Nothing found, try to update filter.
Top-30
Journals
|
2
4
6
8
10
12
14
16
18
|
|
|
Journal of the American Chemical Society
17 publications, 14.29%
|
|
|
Angewandte Chemie
7 publications, 5.88%
|
|
|
Angewandte Chemie - International Edition
7 publications, 5.88%
|
|
|
Inorganic Chemistry
7 publications, 5.88%
|
|
|
Crystal Growth and Design
7 publications, 5.88%
|
|
|
Dalton Transactions
5 publications, 4.2%
|
|
|
CrystEngComm
5 publications, 4.2%
|
|
|
Chemistry - A European Journal
4 publications, 3.36%
|
|
|
Chemical Communications
4 publications, 3.36%
|
|
|
Journal of Materials Chemistry C
4 publications, 3.36%
|
|
|
Coordination Chemistry Reviews
3 publications, 2.52%
|
|
|
Journal of Organometallic Chemistry
2 publications, 1.68%
|
|
|
Synthetic Metals
2 publications, 1.68%
|
|
|
Chinese Journal of Chemistry
2 publications, 1.68%
|
|
|
ChemPhysChem
2 publications, 1.68%
|
|
|
Journal of Physical Chemistry B
2 publications, 1.68%
|
|
|
Chemistry of Materials
2 publications, 1.68%
|
|
|
Journal of Materials Chemistry A
2 publications, 1.68%
|
|
|
Physical Chemistry Chemical Physics
2 publications, 1.68%
|
|
|
Advances in Heterocyclic Chemistry
2 publications, 1.68%
|
|
|
Tetrahedron
1 publication, 0.84%
|
|
|
Tetrahedron Letters
1 publication, 0.84%
|
|
|
Physical Review B
1 publication, 0.84%
|
|
|
Bulletin of the Chemical Society of Japan
1 publication, 0.84%
|
|
|
Yuki Gosei Kagaku Kyokaishi/Journal of Synthetic Organic Chemistry
1 publication, 0.84%
|
|
|
Theoretical and Experimental Chemistry
1 publication, 0.84%
|
|
|
Nature Communications
1 publication, 0.84%
|
|
|
Inorganic Chemistry Communication
1 publication, 0.84%
|
|
|
Chem
1 publication, 0.84%
|
|
|
2
4
6
8
10
12
14
16
18
|
Publishers
|
5
10
15
20
25
30
35
40
|
|
|
American Chemical Society (ACS)
39 publications, 32.77%
|
|
|
Wiley
26 publications, 21.85%
|
|
|
Royal Society of Chemistry (RSC)
25 publications, 21.01%
|
|
|
Elsevier
22 publications, 18.49%
|
|
|
Springer Nature
2 publications, 1.68%
|
|
|
American Physical Society (APS)
1 publication, 0.84%
|
|
|
The Chemical Society of Japan
1 publication, 0.84%
|
|
|
The Society of Synthetic Organic Chemistry, Japan
1 publication, 0.84%
|
|
|
5
10
15
20
25
30
35
40
|
- We do not take into account publications without a DOI.
- Statistics recalculated weekly.
Are you a researcher?
Create a profile to get free access to personal recommendations for colleagues and new articles.
Metrics
119
Total citations:
119
Citations from 2025:
0
Cite this
GOST |
RIS |
BibTex |
MLA
Cite this
GOST
Copy
Lessard B. H. et al. Bistability and the Phase Transition in 1,3,2-Dithiazolo[4,5-b]pyrazin-2-yl // Journal of the American Chemical Society. 2004. Vol. 126. No. 45. pp. 14692-14693.
GOST all authors (up to 50)
Copy
Lessard B. H., Clements O. P., Haddon R. C., Itkis M. E., Leitch A. A., Oakley R., Reed R. W., Richardson J. F. Bistability and the Phase Transition in 1,3,2-Dithiazolo[4,5-b]pyrazin-2-yl // Journal of the American Chemical Society. 2004. Vol. 126. No. 45. pp. 14692-14693.
Cite this
RIS
Copy
TY - JOUR
DO - 10.1021/ja044979q
UR - https://doi.org/10.1021/ja044979q
TI - Bistability and the Phase Transition in 1,3,2-Dithiazolo[4,5-b]pyrazin-2-yl
T2 - Journal of the American Chemical Society
AU - Lessard, Benoît H.
AU - Clements, Owen P
AU - Haddon, Robert C.
AU - Itkis, Mikhail E
AU - Leitch, Alicea A.
AU - Oakley, Richard
AU - Reed, Robert W
AU - Richardson, John F.
PY - 2004
DA - 2004/10/23
PB - American Chemical Society (ACS)
SP - 14692-14693
IS - 45
VL - 126
PMID - 15535673
SN - 0002-7863
SN - 1520-5126
ER -
Cite this
BibTex (up to 50 authors)
Copy
@article{2004_Lessard,
author = {Benoît H. Lessard and Owen P Clements and Robert C. Haddon and Mikhail E Itkis and Alicea A. Leitch and Richard Oakley and Robert W Reed and John F. Richardson},
title = {Bistability and the Phase Transition in 1,3,2-Dithiazolo[4,5-b]pyrazin-2-yl},
journal = {Journal of the American Chemical Society},
year = {2004},
volume = {126},
publisher = {American Chemical Society (ACS)},
month = {oct},
url = {https://doi.org/10.1021/ja044979q},
number = {45},
pages = {14692--14693},
doi = {10.1021/ja044979q}
}
Cite this
MLA
Copy
Lessard, Benoît H., et al. “Bistability and the Phase Transition in 1,3,2-Dithiazolo[4,5-b]pyrazin-2-yl.” Journal of the American Chemical Society, vol. 126, no. 45, Oct. 2004, pp. 14692-14693. https://doi.org/10.1021/ja044979q.