том 126 издание 42 страницы 13622-13623

Dirhodium(II) Caprolactamate:  An Exceptional Catalyst for Allylic Oxidation

Тип публикацииJournal Article
Дата публикации2004-10-01
scimago Q1
wos Q1
БС1
SJR5.489
CiteScore24.4
Impact factor15.6
ISSN00027863, 15205126
General Chemistry
Catalysis
Biochemistry
Colloid and Surface Chemistry
Краткое описание
The oxidation of organic molecules represents a fundamentally important chemical process. Particularly important is allylic oxidation, whereby a single methylene unit is converted directly into a carbonyl group. In this communication, we report that dirhodium(II) caprolactamate [Rh2(cap)4] in combination with tert-butyl hydroperoxide (terminal oxidant) effectively catalyzes the allylic oxidation of a variety of olefins and enones. The reaction is completely selective, tolerant of air/moisture, and can be performed with as little as 0.1 mol % catalyst in minutes. A mechanistic proposal involving redox chain catalysis has been put forth, as well as evidence for the intermediacy of a higher valent dirhodium tert-butyl peroxy complex.
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ГОСТ |
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Catino A. J., Forslund R. E., Doyle M. P. Dirhodium(II) Caprolactamate: An Exceptional Catalyst for Allylic Oxidation // Journal of the American Chemical Society. 2004. Vol. 126. No. 42. pp. 13622-13623.
ГОСТ со всеми авторами (до 50) Скопировать
Catino A. J., Forslund R. E., Doyle M. P. Dirhodium(II) Caprolactamate: An Exceptional Catalyst for Allylic Oxidation // Journal of the American Chemical Society. 2004. Vol. 126. No. 42. pp. 13622-13623.
RIS |
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TY - JOUR
DO - 10.1021/ja045330o
UR - https://doi.org/10.1021/ja045330o
TI - Dirhodium(II) Caprolactamate: An Exceptional Catalyst for Allylic Oxidation
T2 - Journal of the American Chemical Society
AU - Catino, Arthur J
AU - Forslund, Raymond E
AU - Doyle, Michael P
PY - 2004
DA - 2004/10/01
PB - American Chemical Society (ACS)
SP - 13622-13623
IS - 42
VL - 126
PMID - 15493912
SN - 0002-7863
SN - 1520-5126
ER -
BibTex |
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BibTex (до 50 авторов) Скопировать
@article{2004_Catino,
author = {Arthur J Catino and Raymond E Forslund and Michael P Doyle},
title = {Dirhodium(II) Caprolactamate: An Exceptional Catalyst for Allylic Oxidation},
journal = {Journal of the American Chemical Society},
year = {2004},
volume = {126},
publisher = {American Chemical Society (ACS)},
month = {oct},
url = {https://doi.org/10.1021/ja045330o},
number = {42},
pages = {13622--13623},
doi = {10.1021/ja045330o}
}
MLA
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Catino, Arthur J., et al. “Dirhodium(II) Caprolactamate: An Exceptional Catalyst for Allylic Oxidation.” Journal of the American Chemical Society, vol. 126, no. 42, Oct. 2004, pp. 13622-13623. https://doi.org/10.1021/ja045330o.