Radical Deoxygenation of Hydroxyl Groups via Phosphites
Publication type: Journal Article
Publication date: 2004-09-25
scimago Q1
wos Q1
SJR: 5.554
CiteScore: 22.5
Impact factor: 15.6
ISSN: 00027863, 15205126
PubMed ID:
15479050
General Chemistry
Catalysis
Biochemistry
Colloid and Surface Chemistry
Abstract
A highly efficient, two-step sequence method for the deoxygenation of hydroxyl groups has been developed. The method involves the preparation of the 2-(2-iodophenyl)ethyl methyl phosphite derivative of an alcohol using methyl dichlorophosphite and 2-(2-iodophenyl)ethanol. Treatment of the phosphite intermediate with (n-Bu)3SnH/AIBN in refluxing benzene cleanly produces the deoxygenation product of the original alcohol.
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83
Total citations:
83
Citations from 2025:
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(6.02%)
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MLA
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GOST
Copy
Zhang L., Koreeda M. Radical Deoxygenation of Hydroxyl Groups via Phosphites // Journal of the American Chemical Society. 2004. Vol. 126. No. 41. pp. 13190-13191.
GOST all authors (up to 50)
Copy
Zhang L., Koreeda M. Radical Deoxygenation of Hydroxyl Groups via Phosphites // Journal of the American Chemical Society. 2004. Vol. 126. No. 41. pp. 13190-13191.
Cite this
RIS
Copy
TY - JOUR
DO - 10.1021/ja0462777
UR - https://doi.org/10.1021/ja0462777
TI - Radical Deoxygenation of Hydroxyl Groups via Phosphites
T2 - Journal of the American Chemical Society
AU - Zhang, Liming
AU - Koreeda, Masato
PY - 2004
DA - 2004/09/25
PB - American Chemical Society (ACS)
SP - 13190-13191
IS - 41
VL - 126
PMID - 15479050
SN - 0002-7863
SN - 1520-5126
ER -
Cite this
BibTex (up to 50 authors)
Copy
@article{2004_Zhang,
author = {Liming Zhang and Masato Koreeda},
title = {Radical Deoxygenation of Hydroxyl Groups via Phosphites},
journal = {Journal of the American Chemical Society},
year = {2004},
volume = {126},
publisher = {American Chemical Society (ACS)},
month = {sep},
url = {https://doi.org/10.1021/ja0462777},
number = {41},
pages = {13190--13191},
doi = {10.1021/ja0462777}
}
Cite this
MLA
Copy
Zhang, Liming, and Masato Koreeda. “Radical Deoxygenation of Hydroxyl Groups via Phosphites.” Journal of the American Chemical Society, vol. 126, no. 41, Sep. 2004, pp. 13190-13191. https://doi.org/10.1021/ja0462777.