Journal of the American Chemical Society, volume 126, issue 37, pages 11404-11405
Alternating Copolymerization of Limonene Oxide and Carbon Dioxide
Publication type: Journal Article
Publication date: 2004-08-24
Q1
Q1
SJR: 5.489
CiteScore: 24.4
Impact factor: 14.4
ISSN: 00027863, 15205126
General Chemistry
Catalysis
Biochemistry
Colloid and Surface Chemistry
Abstract
The alternating copolymerization of (R)- or (S)-limonene oxide and CO2 using beta-diiminate zinc acetate catalysts is reported. At 100 psi CO2 and 25 degrees C, the catalyst exhibits a high selectivity for the trans isomer and produces regioregular polycarbonate. The copolymer contains >99% carbonate linkages, a narrow molecular weight distribution, and an Mn value consistent with the [epoxide]/[Zn] ratio.
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Byrne C. M. et al. Alternating Copolymerization of Limonene Oxide and Carbon Dioxide // Journal of the American Chemical Society. 2004. Vol. 126. No. 37. pp. 11404-11405.
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Byrne C. M., Allen S. D., Lobkovsky E. B., Coates G. W. Alternating Copolymerization of Limonene Oxide and Carbon Dioxide // Journal of the American Chemical Society. 2004. Vol. 126. No. 37. pp. 11404-11405.
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TY - JOUR
DO - 10.1021/ja0472580
UR - https://doi.org/10.1021/ja0472580
TI - Alternating Copolymerization of Limonene Oxide and Carbon Dioxide
T2 - Journal of the American Chemical Society
AU - Byrne, Christopher M
AU - Allen, Scott D
AU - Lobkovsky, Emil B.
AU - Coates, Geoffrey W.
PY - 2004
DA - 2004/08/24
PB - American Chemical Society (ACS)
SP - 11404-11405
IS - 37
VL - 126
SN - 0002-7863
SN - 1520-5126
ER -
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BibTex (up to 50 authors)
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@article{2004_Byrne,
author = {Christopher M Byrne and Scott D Allen and Emil B. Lobkovsky and Geoffrey W. Coates},
title = {Alternating Copolymerization of Limonene Oxide and Carbon Dioxide},
journal = {Journal of the American Chemical Society},
year = {2004},
volume = {126},
publisher = {American Chemical Society (ACS)},
month = {aug},
url = {https://doi.org/10.1021/ja0472580},
number = {37},
pages = {11404--11405},
doi = {10.1021/ja0472580}
}
Cite this
MLA
Copy
Byrne, Christopher M., et al. “Alternating Copolymerization of Limonene Oxide and Carbon Dioxide.” Journal of the American Chemical Society, vol. 126, no. 37, Aug. 2004, pp. 11404-11405. https://doi.org/10.1021/ja0472580.