A Seven-Membered Aluminum Sulfur Allenyl Heterocycle Arising from the Conversion of an Aluminacyclopropene with CS2
Тип публикации: Journal Article
Дата публикации: 2004-07-29
SCImago Q1
Tоп 10% SCImago
WOS Q1
БС1
SJR: 5.491
CiteScore: 22
Impact factor: 16.6
ISSN: 00027863, 15205126
PubMed ID:
15315402
General Chemistry
Catalysis
Biochemistry
Colloid and Surface Chemistry
Краткое описание
The reaction of an aluminacyclopropene LAl[eta2-C2(SiMe3)2] (1, L = HC(CMeNAr)2, Ar = 2,6-iPr2C6H3) with CS2 in the temperature range from -78 degrees C to room temperature affords the first seven-membered aluminum sulfur-containing heterocyclic compound [LAl]2(mu-S)[eta2-SC(SiMe3)=C=C(SiMe3)] (2) bearing an allenyl group. The structural characterization of 2 and the analogous compound LAl[OC(O)C2(SiMe3)2] (3) of the proposed intermediate A and the variable-temperature 1H NMR kinetic study of this reaction may give a better understanding on this unusual conversion.
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ГОСТ
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Zhu H. et al. A Seven-Membered Aluminum Sulfur Allenyl Heterocycle Arising from the Conversion of an Aluminacyclopropene with CS2 // Journal of the American Chemical Society. 2004. Vol. 126. No. 33. pp. 10194-10195.
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Zhu H., Chai J., Ma Q., Jancik V., Roesky H. W., Fan H., Herbst-Irmer R. A Seven-Membered Aluminum Sulfur Allenyl Heterocycle Arising from the Conversion of an Aluminacyclopropene with CS2 // Journal of the American Chemical Society. 2004. Vol. 126. No. 33. pp. 10194-10195.
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TY - JOUR
DO - 10.1021/ja049462t
UR - https://doi.org/10.1021/ja049462t
TI - A Seven-Membered Aluminum Sulfur Allenyl Heterocycle Arising from the Conversion of an Aluminacyclopropene with CS2
T2 - Journal of the American Chemical Society
AU - Zhu, Hongping
AU - Chai, Jianfang
AU - Ma, Qingjun
AU - Jancik, V.
AU - Roesky, Herbert W.
AU - Fan, Hongjun
AU - Herbst-Irmer, Regine
PY - 2004
DA - 2004/07/29
PB - American Chemical Society (ACS)
SP - 10194-10195
IS - 33
VL - 126
PMID - 15315402
SN - 0002-7863
SN - 1520-5126
ER -
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@article{2004_Zhu,
author = {Hongping Zhu and Jianfang Chai and Qingjun Ma and V. Jancik and Herbert W. Roesky and Hongjun Fan and Regine Herbst-Irmer},
title = {A Seven-Membered Aluminum Sulfur Allenyl Heterocycle Arising from the Conversion of an Aluminacyclopropene with CS2},
journal = {Journal of the American Chemical Society},
year = {2004},
volume = {126},
publisher = {American Chemical Society (ACS)},
month = {jul},
url = {https://doi.org/10.1021/ja049462t},
number = {33},
pages = {10194--10195},
doi = {10.1021/ja049462t}
}
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MLA
Скопировать
Zhu, Hongping, et al. “A Seven-Membered Aluminum Sulfur Allenyl Heterocycle Arising from the Conversion of an Aluminacyclopropene with CS2.” Journal of the American Chemical Society, vol. 126, no. 33, Jul. 2004, pp. 10194-10195. https://doi.org/10.1021/ja049462t.
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