Journal of the American Chemical Society, volume 127, issue 31, pages 10836-10837
A Reaction for sp3−sp3 C−C Bond Formation via Cooperation of Lewis Acid-Promoted/Rh-Catalyzed C−H Bond Activation
Publication type: Journal Article
Publication date: 2005-07-16
Q1
Q1
SJR: 5.489
CiteScore: 24.4
Impact factor: 14.4
ISSN: 00027863, 15205126
General Chemistry
Catalysis
Biochemistry
Colloid and Surface Chemistry
Abstract
A new method for intermolecular sp3-sp3 C-C bond formation between primary aliphatic alcohol and olefin by use of a RhCl(PPh3)3 (cat.)/BF3.OEt2 (2.5 equiv)/BuBr (0.5 equiv)/toluene system was first disclosed, which possessed quite significant utilities for organic synthesis, especially for that of secondary alcohols. The most significant aspect is the discovery that rhodium-catalyzed C-H bond activation of alcohols is feasible under Lewis acid-promoted conditions.
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GOST
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Shi L. et al. A Reaction for sp3−sp3 C−C Bond Formation via Cooperation of Lewis Acid-Promoted/Rh-Catalyzed C−H Bond Activation // Journal of the American Chemical Society. 2005. Vol. 127. No. 31. pp. 10836-10837.
GOST all authors (up to 50)
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Shi L., Tu Y., Wang M., Zhang F. M., Fan C., Zhao Yu. M., Xia W. J. A Reaction for sp3−sp3 C−C Bond Formation via Cooperation of Lewis Acid-Promoted/Rh-Catalyzed C−H Bond Activation // Journal of the American Chemical Society. 2005. Vol. 127. No. 31. pp. 10836-10837.
Cite this
RIS
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TY - JOUR
DO - 10.1021/ja0528331
UR - https://doi.org/10.1021/ja0528331
TI - A Reaction for sp3−sp3 C−C Bond Formation via Cooperation of Lewis Acid-Promoted/Rh-Catalyzed C−H Bond Activation
T2 - Journal of the American Chemical Society
AU - Shi, Lei
AU - Tu, Yong-Qiang
AU - Wang, Min
AU - Zhang, Fu Min
AU - Fan, Chun-An
AU - Zhao, Yu Ming
AU - Xia, Wu Jiong
PY - 2005
DA - 2005/07/16
PB - American Chemical Society (ACS)
SP - 10836-10837
IS - 31
VL - 127
SN - 0002-7863
SN - 1520-5126
ER -
Cite this
BibTex (up to 50 authors)
Copy
@article{2005_Shi,
author = {Lei Shi and Yong-Qiang Tu and Min Wang and Fu Min Zhang and Chun-An Fan and Yu Ming Zhao and Wu Jiong Xia},
title = {A Reaction for sp3−sp3 C−C Bond Formation via Cooperation of Lewis Acid-Promoted/Rh-Catalyzed C−H Bond Activation},
journal = {Journal of the American Chemical Society},
year = {2005},
volume = {127},
publisher = {American Chemical Society (ACS)},
month = {jul},
url = {https://doi.org/10.1021/ja0528331},
number = {31},
pages = {10836--10837},
doi = {10.1021/ja0528331}
}
Cite this
MLA
Copy
Shi, Lei, et al. “A Reaction for sp3−sp3 C−C Bond Formation via Cooperation of Lewis Acid-Promoted/Rh-Catalyzed C−H Bond Activation.” Journal of the American Chemical Society, vol. 127, no. 31, Jul. 2005, pp. 10836-10837. https://doi.org/10.1021/ja0528331.