Unique Spatial Heterogeneity in Ionic Liquids
Тип публикации: Journal Article
Дата публикации: 2005-08-16
scimago Q1
wos Q1
БС1
SJR: 5.489
CiteScore: 24.4
Impact factor: 15.6
ISSN: 00027863, 15205126
PubMed ID:
16131175
General Chemistry
Catalysis
Biochemistry
Colloid and Surface Chemistry
Краткое описание
A multiscale coarse-graining model for ionic liquids has been extended to investigate the unique aggregation of cations in ionic liquids through computer simulation. It has been found that, with sufficiently long side chains, the tail groups of cations aggregate to form spatially heterogeneous domains, while headgroups of the cations and the anions distribute as uniformly as possible. This is understood as the result of competition between the charged electrostatic interactions between headgroups and anions and the collective short-range interactions between the neutral tail groups. This aggregation can help to explain a number of experimentally observed physical phenomena in ionic liquids.
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ГОСТ
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Wang Y., Voth G. A. Unique Spatial Heterogeneity in Ionic Liquids // Journal of the American Chemical Society. 2005. Vol. 127. No. 35. pp. 12192-12193.
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Wang Y., Voth G. A. Unique Spatial Heterogeneity in Ionic Liquids // Journal of the American Chemical Society. 2005. Vol. 127. No. 35. pp. 12192-12193.
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TY - JOUR
DO - 10.1021/ja053796g
UR - https://doi.org/10.1021/ja053796g
TI - Unique Spatial Heterogeneity in Ionic Liquids
T2 - Journal of the American Chemical Society
AU - Wang, Yan-Ting
AU - Voth, Gregory A.
PY - 2005
DA - 2005/08/16
PB - American Chemical Society (ACS)
SP - 12192-12193
IS - 35
VL - 127
PMID - 16131175
SN - 0002-7863
SN - 1520-5126
ER -
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@article{2005_Wang,
author = {Yan-Ting Wang and Gregory A. Voth},
title = {Unique Spatial Heterogeneity in Ionic Liquids},
journal = {Journal of the American Chemical Society},
year = {2005},
volume = {127},
publisher = {American Chemical Society (ACS)},
month = {aug},
url = {https://doi.org/10.1021/ja053796g},
number = {35},
pages = {12192--12193},
doi = {10.1021/ja053796g}
}
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MLA
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Wang, Yan-Ting, and Gregory A. Voth. “Unique Spatial Heterogeneity in Ionic Liquids.” Journal of the American Chemical Society, vol. 127, no. 35, Aug. 2005, pp. 12192-12193. https://doi.org/10.1021/ja053796g.