Coordination Bond Formation at Charge-Transfer Phase Transition in (BDTA)2[Co(mnt)2]
Publication type: Journal Article
Publication date: 2006-01-05
scimago Q1
wos Q1
SJR: 5.554
CiteScore: 22.5
Impact factor: 15.6
ISSN: 00027863, 15205126
PubMed ID:
16433518
General Chemistry
Catalysis
Biochemistry
Colloid and Surface Chemistry
Abstract
The crystal structure of a charge-transfer salt, (BDTA)2[Co(mnt)2], where BDTA is 1,3,2-benzodithiazolyl and mnt is maleonitriledithiolate, consisted of an alternating stacking column of a head-to-head BDTA+ dimer and a planar [Co(mnt)2]2- dianion at 253 K. Magnetic measurements and structural analyses revealed a phase transition at 190 K, where a partial electron transfer occurred from [Co(mnt)2]2- to one of the BDTA+ cations, forming a coordination bond between the two.
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70
Total citations:
70
Citations from 2025:
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(1.43%)
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Umezono Y., FUJITA W., Awaga K. Coordination Bond Formation at Charge-Transfer Phase Transition in (BDTA)2[Co(mnt)2] // Journal of the American Chemical Society. 2006. Vol. 128. No. 4. pp. 1084-1085.
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Umezono Y., FUJITA W., Awaga K. Coordination Bond Formation at Charge-Transfer Phase Transition in (BDTA)2[Co(mnt)2] // Journal of the American Chemical Society. 2006. Vol. 128. No. 4. pp. 1084-1085.
Cite this
RIS
Copy
TY - JOUR
DO - 10.1021/ja057207i
UR - https://doi.org/10.1021/ja057207i
TI - Coordination Bond Formation at Charge-Transfer Phase Transition in (BDTA)2[Co(mnt)2]
T2 - Journal of the American Chemical Society
AU - Umezono, Yoshikatsu
AU - FUJITA, Wataru
AU - Awaga, Kunio
PY - 2006
DA - 2006/01/05
PB - American Chemical Society (ACS)
SP - 1084-1085
IS - 4
VL - 128
PMID - 16433518
SN - 0002-7863
SN - 1520-5126
ER -
Cite this
BibTex (up to 50 authors)
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@article{2006_Umezono,
author = {Yoshikatsu Umezono and Wataru FUJITA and Kunio Awaga},
title = {Coordination Bond Formation at Charge-Transfer Phase Transition in (BDTA)2[Co(mnt)2]},
journal = {Journal of the American Chemical Society},
year = {2006},
volume = {128},
publisher = {American Chemical Society (ACS)},
month = {jan},
url = {https://doi.org/10.1021/ja057207i},
number = {4},
pages = {1084--1085},
doi = {10.1021/ja057207i}
}
Cite this
MLA
Copy
Umezono, Yoshikatsu, et al. “Coordination Bond Formation at Charge-Transfer Phase Transition in (BDTA)2[Co(mnt)2].” Journal of the American Chemical Society, vol. 128, no. 4, Jan. 2006, pp. 1084-1085. https://doi.org/10.1021/ja057207i.