Journal of the American Chemical Society, volume 128, issue 40, pages 13032-13033

On the Mechanism of Lead Chalcogenide Nanocrystal Formation

Publication typeJournal Article
Publication date2006-09-16
Quartile SCImago
Q1
Quartile WOS
Q1
Impact factor15
ISSN00027863, 15205126
General Chemistry
Catalysis
Biochemistry
Colloid and Surface Chemistry
Abstract
On the basis of evidence from 31P NMR spectroscopy, and using PbSe as a model, we propose two simultaneous mechanisms through which "monomers" are formed in preparations of lead chalcogenide nanocrystals (NCs). In one mechanism, selenium is delivered as a Se2- species, whereas in the other, Se0 reacts with metal already reduced by the organophosphine. This latter mechanism helps explain the sensitivity of NC preparations to the purity of organophosphines and allows the rational modification of batch NC reactions to increase yield.

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GOST |
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GOST Copy
Steckel J. S. et al. On the Mechanism of Lead Chalcogenide Nanocrystal Formation // Journal of the American Chemical Society. 2006. Vol. 128. No. 40. pp. 13032-13033.
GOST all authors (up to 50) Copy
Steckel J. S., Yen B. K. H., Oertel D. C., Bawendi M. G. On the Mechanism of Lead Chalcogenide Nanocrystal Formation // Journal of the American Chemical Society. 2006. Vol. 128. No. 40. pp. 13032-13033.
RIS |
Cite this
RIS Copy
TY - JOUR
DO - 10.1021/ja062626g
UR - https://doi.org/10.1021/ja062626g
TI - On the Mechanism of Lead Chalcogenide Nanocrystal Formation
T2 - Journal of the American Chemical Society
AU - Yen, Brian K H
AU - Oertel, David C.
AU - Steckel, Jonathan S.
AU - Bawendi, Moungi G.
PY - 2006
DA - 2006/09/16 00:00:00
PB - American Chemical Society (ACS)
SP - 13032-13033
IS - 40
VL - 128
SN - 0002-7863
SN - 1520-5126
ER -
BibTex |
Cite this
BibTex Copy
@article{2006_Steckel,
author = {Brian K H Yen and David C. Oertel and Jonathan S. Steckel and Moungi G. Bawendi},
title = {On the Mechanism of Lead Chalcogenide Nanocrystal Formation},
journal = {Journal of the American Chemical Society},
year = {2006},
volume = {128},
publisher = {American Chemical Society (ACS)},
month = {sep},
url = {https://doi.org/10.1021/ja062626g},
number = {40},
pages = {13032--13033},
doi = {10.1021/ja062626g}
}
MLA
Cite this
MLA Copy
Steckel, Jonathan S., et al. “On the Mechanism of Lead Chalcogenide Nanocrystal Formation.” Journal of the American Chemical Society, vol. 128, no. 40, Sep. 2006, pp. 13032-13033. https://doi.org/10.1021/ja062626g.
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