On the Mechanism of Lead Chalcogenide Nanocrystal Formation
Publication type: Journal Article
Publication date: 2006-09-16
scimago Q1
wos Q1
SJR: 5.554
CiteScore: 22.5
Impact factor: 15.6
ISSN: 00027863, 15205126
PubMed ID:
17017765
General Chemistry
Catalysis
Biochemistry
Colloid and Surface Chemistry
Abstract
On the basis of evidence from 31P NMR spectroscopy, and using PbSe as a model, we propose two simultaneous mechanisms through which "monomers" are formed in preparations of lead chalcogenide nanocrystals (NCs). In one mechanism, selenium is delivered as a Se2- species, whereas in the other, Se0 reacts with metal already reduced by the organophosphine. This latter mechanism helps explain the sensitivity of NC preparations to the purity of organophosphines and allows the rational modification of batch NC reactions to increase yield.
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Metrics
282
Total citations:
282
Citations from 2024:
12
(4.26%)
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GOST
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Steckel J. S. et al. On the Mechanism of Lead Chalcogenide Nanocrystal Formation // Journal of the American Chemical Society. 2006. Vol. 128. No. 40. pp. 13032-13033.
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Steckel J. S., Yen B. K. H., Oertel D. C., Bawendi M. G. On the Mechanism of Lead Chalcogenide Nanocrystal Formation // Journal of the American Chemical Society. 2006. Vol. 128. No. 40. pp. 13032-13033.
Cite this
RIS
Copy
TY - JOUR
DO - 10.1021/ja062626g
UR - https://doi.org/10.1021/ja062626g
TI - On the Mechanism of Lead Chalcogenide Nanocrystal Formation
T2 - Journal of the American Chemical Society
AU - Steckel, Jonathan S.
AU - Yen, Brian K H
AU - Oertel, David C.
AU - Bawendi, Moungi G.
PY - 2006
DA - 2006/09/16
PB - American Chemical Society (ACS)
SP - 13032-13033
IS - 40
VL - 128
PMID - 17017765
SN - 0002-7863
SN - 1520-5126
ER -
Cite this
BibTex (up to 50 authors)
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@article{2006_Steckel,
author = {Jonathan S. Steckel and Brian K H Yen and David C. Oertel and Moungi G. Bawendi},
title = {On the Mechanism of Lead Chalcogenide Nanocrystal Formation},
journal = {Journal of the American Chemical Society},
year = {2006},
volume = {128},
publisher = {American Chemical Society (ACS)},
month = {sep},
url = {https://doi.org/10.1021/ja062626g},
number = {40},
pages = {13032--13033},
doi = {10.1021/ja062626g}
}
Cite this
MLA
Copy
Steckel, Jonathan S., et al. “On the Mechanism of Lead Chalcogenide Nanocrystal Formation.” Journal of the American Chemical Society, vol. 128, no. 40, Sep. 2006, pp. 13032-13033. https://doi.org/10.1021/ja062626g.