Journal of the American Chemical Society, volume 128, issue 42, pages 13652-13653
Advanced Fine-Tuning of Grubbs/Hoveyda Olefin Metathesis Catalysts: A Further Step toward an Optimum Balance between Antinomic Properties
1
Institute of Organic Chemistry, Polish Academy of Sciences, Kasprzaka 44/52, 01-224 Warsaw, Poland, Faculty of Chemistry, Warsaw University of Technology, Koszykowa 75, 00-662 Warsaw, Poland, Laboratoire de Chimie de Coordination du CNRS, 205 route de Narbonne, 31077 Toulouse Cedex 4, France, and Ligand Chemie GmbH Papenhauser Strausse 10, Lemgo D-32657, Germany
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Publication type: Journal Article
Publication date: 2006-10-01
Quartile SCImago
Q1
Quartile WOS
Q1
Impact factor: 15
ISSN: 00027863, 15205126
General Chemistry
Catalysis
Biochemistry
Colloid and Surface Chemistry
Abstract
A 95% yield in the cross metathesis of acrylonitrile with a model olefin is achieved at 25 degrees C with only 3 mol % of the new air-stable ruthenium catalyst 1f shown in the enclosed structural diagram. Even more remarkable are the performances of its boosted version 1g incorporating an electron-withdrawing group. Both these new enhanced versions of Hoveyda catalyst are readily available from Grubbs second generation precatalyst upon reaction with a styrenyl ether the end group of which has been functionalized by an ester function. The latter acts as a weakly coordinating ligand allowing to reach a desirable balance between antinomic properties such as the catalyst's stability, a high activity for challenging substrates, and a high initiation rate.
Top-30
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2 publications, 1.47%
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1 publication, 0.74%
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1 publication, 0.74%
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1 publication, 0.74%
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Theoretical Chemistry Accounts
1 publication, 0.74%
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1 publication, 0.74%
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Procedia Computer Science
1 publication, 0.74%
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Citations by publishers
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5
10
15
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25
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35
40
45
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Wiley
45 publications, 33.09%
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American Chemical Society (ACS)
35 publications, 25.74%
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Elsevier
18 publications, 13.24%
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Royal Society of Chemistry (RSC)
17 publications, 12.5%
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Springer Nature
6 publications, 4.41%
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Beilstein-Institut
2 publications, 1.47%
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Multidisciplinary Digital Publishing Institute (MDPI)
2 publications, 1.47%
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Thieme
2 publications, 1.47%
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Bentham Science
1 publication, 0.74%
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CSIRO Publishing
1 publication, 0.74%
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Canadian Science Publishing
1 publication, 0.74%
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Editions Technip
1 publication, 0.74%
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Autonomous Non-profit Organization Editorial Board of the journal Uspekhi Khimii
1 publication, 0.74%
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5
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15
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25
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- We do not take into account publications without a DOI.
- Statistics recalculated only for publications connected to researchers, organizations and labs registered on the platform.
- Statistics recalculated weekly.
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Bieniek M. et al. Advanced Fine-Tuning of Grubbs/Hoveyda Olefin Metathesis Catalysts: A Further Step toward an Optimum Balance between Antinomic Properties // Journal of the American Chemical Society. 2006. Vol. 128. No. 42. pp. 13652-13653.
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Bieniek M., Bujok R., Cabaj M., Lugan N., Lavigne G., Arlt D., Grela K. Advanced Fine-Tuning of Grubbs/Hoveyda Olefin Metathesis Catalysts: A Further Step toward an Optimum Balance between Antinomic Properties // Journal of the American Chemical Society. 2006. Vol. 128. No. 42. pp. 13652-13653.
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TY - JOUR
DO - 10.1021/ja063186w
UR - https://doi.org/10.1021/ja063186w
TI - Advanced Fine-Tuning of Grubbs/Hoveyda Olefin Metathesis Catalysts: A Further Step toward an Optimum Balance between Antinomic Properties
T2 - Journal of the American Chemical Society
AU - Bieniek, Michał
AU - Bujok, Robert
AU - Cabaj, Maciej
AU - Lavigne, Guy
AU - Arlt, Dieter
AU - Lugan, Noël
AU - Grela, Karol
PY - 2006
DA - 2006/10/01 00:00:00
PB - American Chemical Society (ACS)
SP - 13652-13653
IS - 42
VL - 128
SN - 0002-7863
SN - 1520-5126
ER -
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@article{2006_Bieniek,
author = {Michał Bieniek and Robert Bujok and Maciej Cabaj and Guy Lavigne and Dieter Arlt and Noël Lugan and Karol Grela},
title = {Advanced Fine-Tuning of Grubbs/Hoveyda Olefin Metathesis Catalysts: A Further Step toward an Optimum Balance between Antinomic Properties},
journal = {Journal of the American Chemical Society},
year = {2006},
volume = {128},
publisher = {American Chemical Society (ACS)},
month = {oct},
url = {https://doi.org/10.1021/ja063186w},
number = {42},
pages = {13652--13653},
doi = {10.1021/ja063186w}
}
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Bieniek, Michał, et al. “Advanced Fine-Tuning of Grubbs/Hoveyda Olefin Metathesis Catalysts: A Further Step toward an Optimum Balance between Antinomic Properties.” Journal of the American Chemical Society, vol. 128, no. 42, Oct. 2006, pp. 13652-13653. https://doi.org/10.1021/ja063186w.