Nickel-Catalyzed Addition of Alkynylboranes to Alkynes
Тип публикации: Journal Article
Дата публикации: 2006-10-24
SCImago Q1
Tоп 10% SCImago
WOS Q1
БС1
SJR: 5.491
CiteScore: 22.5
Impact factor: 15.6
ISSN: 00027863, 15205126
PubMed ID:
17090009
General Chemistry
Catalysis
Biochemistry
Colloid and Surface Chemistry
Краткое описание
Alkynylboration has been achieved in the reaction of alkynyl(pinacol)boranes with alkynes in the presence of nickel catalysts, giving cis-1-borylbut-1-en-3-yne derivatives. 1-Aryl-1-alkynes underwent the alkynylboration regioselectively with the selective introduction of the alkynyl groups at their 1-positions, where the aryl groups were attached. The boryl-substituted enynes were reacted with sp2 halides under the Suzuki-Miyaura coupling conditions, giving highly conjugated enynes in high yields.
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ГОСТ
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Suginome M., Shirakura M., Yamamoto A. Nickel-Catalyzed Addition of Alkynylboranes to Alkynes // Journal of the American Chemical Society. 2006. Vol. 128. No. 45. pp. 14438-14439.
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Suginome M., Shirakura M., Yamamoto A. Nickel-Catalyzed Addition of Alkynylboranes to Alkynes // Journal of the American Chemical Society. 2006. Vol. 128. No. 45. pp. 14438-14439.
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TY - JOUR
DO - 10.1021/ja064970j
UR - https://doi.org/10.1021/ja064970j
TI - Nickel-Catalyzed Addition of Alkynylboranes to Alkynes
T2 - Journal of the American Chemical Society
AU - Suginome, Michinori
AU - Shirakura, Masamichi
AU - Yamamoto, Akihiko
PY - 2006
DA - 2006/10/24
PB - American Chemical Society (ACS)
SP - 14438-14439
IS - 45
VL - 128
PMID - 17090009
SN - 0002-7863
SN - 1520-5126
ER -
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BibTex (до 50 авторов)
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@article{2006_Suginome,
author = {Michinori Suginome and Masamichi Shirakura and Akihiko Yamamoto},
title = {Nickel-Catalyzed Addition of Alkynylboranes to Alkynes},
journal = {Journal of the American Chemical Society},
year = {2006},
volume = {128},
publisher = {American Chemical Society (ACS)},
month = {oct},
url = {https://doi.org/10.1021/ja064970j},
number = {45},
pages = {14438--14439},
doi = {10.1021/ja064970j}
}
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MLA
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Suginome, Michinori, et al. “Nickel-Catalyzed Addition of Alkynylboranes to Alkynes.” Journal of the American Chemical Society, vol. 128, no. 45, Oct. 2006, pp. 14438-14439. https://doi.org/10.1021/ja064970j.
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