Enhanced Catalytic Properties of Copper in O- and N-Arylation and Vinylation Reactions, Using Phosphorus Dendrimers as Ligands
1
AM2N, UMR CNRS 5076, ENSCM, 8 rue de l'Ecole Normale, 34296 Montpellier Cedex 5, France, and Laboratoire de Chimie de Coordination du CNRS, 205 route de Narbonne, 31077 Toulouse Cedex 4, France
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Publication type: Journal Article
Publication date: 2006-11-21
scimago Q1
wos Q1
SJR: 5.554
CiteScore: 22.5
Impact factor: 15.6
ISSN: 00027863, 15205126
PubMed ID:
17165724
General Chemistry
Catalysis
Biochemistry
Colloid and Surface Chemistry
Abstract
Imino pyridine-capped phosphorus dendrimers were found to strongly enhance the catalytic activity of copper in arylations and vinylations of O- and N-nucleophiles. These reactions could indeed be performed under very mild conditions, often the mildest to date. Interestingly, such performances could not be obtained when using the monomeric imino pyridine chelating ligand alone. To the best of our knowledge, this constitutes a rare example of such a positive dendritic effect in the field of organometallic catalysis.
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189
Total citations:
189
Citations from 2025:
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(0.53%)
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GOST
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Ouali A. et al. Enhanced Catalytic Properties of Copper in O- and N-Arylation and Vinylation Reactions, Using Phosphorus Dendrimers as Ligands // Journal of the American Chemical Society. 2006. Vol. 128. No. 50. pp. 15990-15991.
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Ouali A., Laurent R., Caminade A., Majoral J., Taillefer M. Enhanced Catalytic Properties of Copper in O- and N-Arylation and Vinylation Reactions, Using Phosphorus Dendrimers as Ligands // Journal of the American Chemical Society. 2006. Vol. 128. No. 50. pp. 15990-15991.
Cite this
RIS
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TY - JOUR
DO - 10.1021/ja066505s
UR - https://doi.org/10.1021/ja066505s
TI - Enhanced Catalytic Properties of Copper in O- and N-Arylation and Vinylation Reactions, Using Phosphorus Dendrimers as Ligands
T2 - Journal of the American Chemical Society
AU - Ouali, Armelle
AU - Laurent, Régis
AU - Caminade, Anne-Marie
AU - Majoral, Jean-Pierre
AU - Taillefer, Marc
PY - 2006
DA - 2006/11/21
PB - American Chemical Society (ACS)
SP - 15990-15991
IS - 50
VL - 128
PMID - 17165724
SN - 0002-7863
SN - 1520-5126
ER -
Cite this
BibTex (up to 50 authors)
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@article{2006_Ouali,
author = {Armelle Ouali and Régis Laurent and Anne-Marie Caminade and Jean-Pierre Majoral and Marc Taillefer},
title = {Enhanced Catalytic Properties of Copper in O- and N-Arylation and Vinylation Reactions, Using Phosphorus Dendrimers as Ligands},
journal = {Journal of the American Chemical Society},
year = {2006},
volume = {128},
publisher = {American Chemical Society (ACS)},
month = {nov},
url = {https://doi.org/10.1021/ja066505s},
number = {50},
pages = {15990--15991},
doi = {10.1021/ja066505s}
}
Cite this
MLA
Copy
Ouali, Armelle, et al. “Enhanced Catalytic Properties of Copper in O- and N-Arylation and Vinylation Reactions, Using Phosphorus Dendrimers as Ligands.” Journal of the American Chemical Society, vol. 128, no. 50, Nov. 2006, pp. 15990-15991. https://doi.org/10.1021/ja066505s.