Mechanochromic and Thermochromic Luminescence of a Copper Iodide Cluster
Xavier Le Goff
1
,
Sébastien Maron
1
,
I Maurin
1
,
François Guillen
1
,
Alain Garcia
1
,
Thierry Gacoin
1
,
Jean-Pierre Boilot
1
1
Laboratoire de Physique de la Matière Condensée
(PMC), CNRS - Ecole Polytechnique, 91128 Palaiseau Cedex, France,
Laboratoire Hétéroéléments et Coordination
(DCPH), CNRS - Ecole Polytechnique, 91128 Palaiseau Cedex, France,
and Institut de Chimie de la Matière Condensée de Bordeaux
(ICMCB) - CNRS, 87 Avenue du Docteur A. Schweitzer, 33608 Pessac Cedex,
France
|
Publication type: Journal Article
Publication date: 2010-07-26
scimago Q1
wos Q1
SJR: 5.554
CiteScore: 22.5
Impact factor: 15.6
ISSN: 00027863, 15205126
PubMed ID:
20698644
General Chemistry
Catalysis
Biochemistry
Colloid and Surface Chemistry
Abstract
The mechanochromic and thermochromic luminescence properties of a molecular copper(I) iodide cluster formulated [Cu(4)I(4)(PPh(2)(CH(2)CH=CH(2)))(4)] are reported. Upon mechanical grinding in a mortar, its solid-state emission properties are drastically modified as well as its thermochromic behavior. This reversible phenomenon has been attributed to distortions in the crystal packing leading to modifications of the intermolecular interactions and thus of the [Cu(4)I(4)] cluster core geometry. Notably, modification of the Cu-Cu interactions seems to be involved in this phenomenon directly affecting the emissive properties of the cluster.
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Perruchas S. et al. Mechanochromic and Thermochromic Luminescence of a Copper Iodide Cluster // Journal of the American Chemical Society. 2010. Vol. 132. No. 32. pp. 10967-10969.
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Perruchas S., Goff X. L., Maron S., Maurin I., Guillen F., Garcia A., Gacoin T., Boilot J. Mechanochromic and Thermochromic Luminescence of a Copper Iodide Cluster // Journal of the American Chemical Society. 2010. Vol. 132. No. 32. pp. 10967-10969.
Cite this
RIS
Copy
TY - JOUR
DO - 10.1021/ja103431d
UR - https://doi.org/10.1021/ja103431d
TI - Mechanochromic and Thermochromic Luminescence of a Copper Iodide Cluster
T2 - Journal of the American Chemical Society
AU - Perruchas, Sandrine
AU - Goff, Xavier Le
AU - Maron, Sébastien
AU - Maurin, I
AU - Guillen, François
AU - Garcia, Alain
AU - Gacoin, Thierry
AU - Boilot, Jean-Pierre
PY - 2010
DA - 2010/07/26
PB - American Chemical Society (ACS)
SP - 10967-10969
IS - 32
VL - 132
PMID - 20698644
SN - 0002-7863
SN - 1520-5126
ER -
Cite this
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@article{2010_Perruchas,
author = {Sandrine Perruchas and Xavier Le Goff and Sébastien Maron and I Maurin and François Guillen and Alain Garcia and Thierry Gacoin and Jean-Pierre Boilot},
title = {Mechanochromic and Thermochromic Luminescence of a Copper Iodide Cluster},
journal = {Journal of the American Chemical Society},
year = {2010},
volume = {132},
publisher = {American Chemical Society (ACS)},
month = {jul},
url = {https://doi.org/10.1021/ja103431d},
number = {32},
pages = {10967--10969},
doi = {10.1021/ja103431d}
}
Cite this
MLA
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Perruchas, Sandrine, et al. “Mechanochromic and Thermochromic Luminescence of a Copper Iodide Cluster.” Journal of the American Chemical Society, vol. 132, no. 32, Jul. 2010, pp. 10967-10969. https://doi.org/10.1021/ja103431d.