Fluorinated Diaminocyclopentanes as Chiral Sensitive NMR Probes of RNA Structure
Publication type: Journal Article
Publication date: 2010-09-29
scimago Q1
wos Q1
SJR: 5.554
CiteScore: 22.5
Impact factor: 15.6
ISSN: 00027863, 15205126
PubMed ID:
20809569
General Chemistry
Catalysis
Biochemistry
Colloid and Surface Chemistry
Abstract
The supramolecular chiral recognition between rac-2a and several structured RNA leads to a distinct (19)F NMR signal splitting. The (19)F NMR analysis of the diastereomeric pairs formed upon binding of this racemic probe delivers a topological footprint of the RNA. This phenomenon can be exploited to investigate dynamic events involving structural equilibria, as demonstrated in a melting experiment. This work provides a proof of concept that small fluorinated moderate binders can act as external probes of RNA structures.
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Metrics
38
Total citations:
38
Citations from 2025:
0
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GOST
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Moumné R. et al. Fluorinated Diaminocyclopentanes as Chiral Sensitive NMR Probes of RNA Structure // Journal of the American Chemical Society. 2010. Vol. 132. No. 38. pp. 13111-13113.
GOST all authors (up to 50)
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Moumné R. Fluorinated Diaminocyclopentanes as Chiral Sensitive NMR Probes of RNA Structure // Journal of the American Chemical Society. 2010. Vol. 132. No. 38. pp. 13111-13113.
Cite this
RIS
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TY - JOUR
DO - 10.1021/ja1037885
UR - https://doi.org/10.1021/ja1037885
TI - Fluorinated Diaminocyclopentanes as Chiral Sensitive NMR Probes of RNA Structure
T2 - Journal of the American Chemical Society
AU - Moumné, Roba
PY - 2010
DA - 2010/09/29
PB - American Chemical Society (ACS)
SP - 13111-13113
IS - 38
VL - 132
PMID - 20809569
SN - 0002-7863
SN - 1520-5126
ER -
Cite this
BibTex (up to 50 authors)
Copy
@article{2010_Moumné,
author = {Roba Moumné},
title = {Fluorinated Diaminocyclopentanes as Chiral Sensitive NMR Probes of RNA Structure},
journal = {Journal of the American Chemical Society},
year = {2010},
volume = {132},
publisher = {American Chemical Society (ACS)},
month = {sep},
url = {https://doi.org/10.1021/ja1037885},
number = {38},
pages = {13111--13113},
doi = {10.1021/ja1037885}
}
Cite this
MLA
Copy
Moumné, Roba, et al. “Fluorinated Diaminocyclopentanes as Chiral Sensitive NMR Probes of RNA Structure.” Journal of the American Chemical Society, vol. 132, no. 38, Sep. 2010, pp. 13111-13113. https://doi.org/10.1021/ja1037885.