Journal of the American Chemical Society, volume 132, issue 26, pages 8872-8873

An Efficient Nickel Catalyst for the Reduction of Carbon Dioxide with a Borane

Sumit Chakraborty 1
Alan M. Bond 1
Jeanette A. KRAUSE 1
Hairong Guan 1
1
 
Department of Chemistry, University of Cincinnati, P.O. Box 210172, Cincinnati, Ohio 45221-0172
Publication typeJournal Article
Publication date2010-06-14
Quartile SCImago
Q1
Quartile WOS
Q1
Impact factor15
ISSN00027863, 15205126
General Chemistry
Catalysis
Biochemistry
Colloid and Surface Chemistry
Abstract
Nickel hydride with a diphosphinite-based ligand catalyzes the highly efficient reduction of CO(2) with catecholborane, and the hydrolysis of the resulting methoxyboryl species produces CH(3)OH in good yield. The mechanism involves a nickel formate, formaldehyde, and a nickel methoxide as different reduced stages for CO(2). The reaction may also be catalyzed by an air-stable nickel formate.

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GOST |
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GOST Copy
Chakraborty S. et al. An Efficient Nickel Catalyst for the Reduction of Carbon Dioxide with a Borane // Journal of the American Chemical Society. 2010. Vol. 132. No. 26. pp. 8872-8873.
GOST all authors (up to 50) Copy
Chakraborty S., Bond A. M., KRAUSE J. A., Guan H. An Efficient Nickel Catalyst for the Reduction of Carbon Dioxide with a Borane // Journal of the American Chemical Society. 2010. Vol. 132. No. 26. pp. 8872-8873.
RIS |
Cite this
RIS Copy
TY - JOUR
DO - 10.1021/ja103982t
UR - https://doi.org/10.1021/ja103982t
TI - An Efficient Nickel Catalyst for the Reduction of Carbon Dioxide with a Borane
T2 - Journal of the American Chemical Society
AU - Chakraborty, Sumit
AU - Bond, Alan M.
AU - KRAUSE, Jeanette A.
AU - Guan, Hairong
PY - 2010
DA - 2010/06/14 00:00:00
PB - American Chemical Society (ACS)
SP - 8872-8873
IS - 26
VL - 132
SN - 0002-7863
SN - 1520-5126
ER -
BibTex |
Cite this
BibTex Copy
@article{2010_Chakraborty,
author = {Sumit Chakraborty and Alan M. Bond and Jeanette A. KRAUSE and Hairong Guan},
title = {An Efficient Nickel Catalyst for the Reduction of Carbon Dioxide with a Borane},
journal = {Journal of the American Chemical Society},
year = {2010},
volume = {132},
publisher = {American Chemical Society (ACS)},
month = {jun},
url = {https://doi.org/10.1021/ja103982t},
number = {26},
pages = {8872--8873},
doi = {10.1021/ja103982t}
}
MLA
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MLA Copy
Chakraborty, Sumit, et al. “An Efficient Nickel Catalyst for the Reduction of Carbon Dioxide with a Borane.” Journal of the American Chemical Society, vol. 132, no. 26, Jun. 2010, pp. 8872-8873. https://doi.org/10.1021/ja103982t.
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