Enantioselective Epoxide Polymerization Using a Bimetallic Cobalt Catalyst
Тип публикации: Journal Article
Дата публикации: 2010-11-02
scimago Q1
wos Q1
БС1
SJR: 5.554
CiteScore: 22.5
Impact factor: 15.6
ISSN: 00027863, 15205126
PubMed ID:
21043488
General Chemistry
Catalysis
Biochemistry
Colloid and Surface Chemistry
Краткое описание
A highly active enantiopure bimetallic cobalt complex was explored for the enantioselective polymerization of a variety of monosubstituted epoxides. The polymerizations were optimized for high rates and stereoselectivity, with s-factors (k(fast)/k(slow)) for most epoxides exceeding 50 and some exceeding 300, well above the threshold for preparative utility of enantiopure epoxides and isotactic polyethers. Values for mm triads of the resulting polymers are typically greater than 95%, with some even surpassing 98%. In addition, the use of a racemic catalyst allowed the preparation of isotactic polyethers in quantitative yields. The thermal properties of these isotactic polyethers are presented, with many polymers exhibiting high T(m) values. This is the first report of the rapid synthesis of a broad range of highly isotactic polyethers via the enantioselective polymerization of racemic epoxides.
Найдено
Ничего не найдено, попробуйте изменить настройки фильтра.
Найдено
Ничего не найдено, попробуйте изменить настройки фильтра.
Топ-30
Журналы
|
2
4
6
8
10
12
|
|
|
Macromolecules
12 публикаций, 8.11%
|
|
|
Journal of the American Chemical Society
11 публикаций, 7.43%
|
|
|
Angewandte Chemie - International Edition
10 публикаций, 6.76%
|
|
|
Angewandte Chemie
10 публикаций, 6.76%
|
|
|
Chemical Communications
8 публикаций, 5.41%
|
|
|
Inorganic Chemistry
6 публикаций, 4.05%
|
|
|
Dalton Transactions
6 публикаций, 4.05%
|
|
|
Chemistry - A European Journal
5 публикаций, 3.38%
|
|
|
Polymer Chemistry
4 публикации, 2.7%
|
|
|
Chemical Science
4 публикации, 2.7%
|
|
|
RSC Advances
4 публикации, 2.7%
|
|
|
Organometallics
3 публикации, 2.03%
|
|
|
Chinese Journal of Polymer Science (English Edition)
2 публикации, 1.35%
|
|
|
Nature Communications
2 публикации, 1.35%
|
|
|
Inorganica Chimica Acta
2 публикации, 1.35%
|
|
|
Inorganic Chemistry Communication
2 публикации, 1.35%
|
|
|
Polymer
2 публикации, 1.35%
|
|
|
European Polymer Journal
2 публикации, 1.35%
|
|
|
ChemCatChem
2 публикации, 1.35%
|
|
|
Macromolecular Chemistry and Physics
2 публикации, 1.35%
|
|
|
European Journal of Organic Chemistry
2 публикации, 1.35%
|
|
|
Chemical Reviews
2 публикации, 1.35%
|
|
|
Topics in Organometallic Chemistry
2 публикации, 1.35%
|
|
|
Journal of Porphyrins and Phthalocyanines
1 публикация, 0.68%
|
|
|
Nature Reviews Chemistry
1 публикация, 0.68%
|
|
|
Journal of Inorganic and Organometallic Polymers and Materials
1 публикация, 0.68%
|
|
|
Colloid and Polymer Science
1 публикация, 0.68%
|
|
|
Fuel
1 публикация, 0.68%
|
|
|
Spectrochimica Acta - Part A: Molecular and Biomolecular Spectroscopy
1 публикация, 0.68%
|
|
|
2
4
6
8
10
12
|
Издатели
|
5
10
15
20
25
30
35
40
45
|
|
|
Wiley
42 публикации, 28.38%
|
|
|
American Chemical Society (ACS)
40 публикаций, 27.03%
|
|
|
Royal Society of Chemistry (RSC)
30 публикаций, 20.27%
|
|
|
Elsevier
18 публикаций, 12.16%
|
|
|
Springer Nature
11 публикаций, 7.43%
|
|
|
World Scientific
1 публикация, 0.68%
|
|
|
Pleiades Publishing
1 публикация, 0.68%
|
|
|
Taylor & Francis
1 публикация, 0.68%
|
|
|
Georg Thieme Verlag KG
1 публикация, 0.68%
|
|
|
Autonomous Non-profit Organization Editorial Board of the journal Uspekhi Khimii
1 публикация, 0.68%
|
|
|
MDPI
1 публикация, 0.68%
|
|
|
5
10
15
20
25
30
35
40
45
|
- Мы не учитываем публикации, у которых нет DOI.
- Статистика публикаций обновляется еженедельно.
Вы ученый?
Создайте профиль, чтобы получать персональные рекомендации коллег, конференций и новых статей.
Метрики
148
Всего цитирований:
148
Цитирований c 2024:
26
(17%)
Цитировать
ГОСТ |
RIS |
BibTex |
MLA
Цитировать
ГОСТ
Скопировать
Thomas R. M. et al. Enantioselective Epoxide Polymerization Using a Bimetallic Cobalt Catalyst // Journal of the American Chemical Society. 2010. Vol. 132. No. 46. pp. 16520-16525.
ГОСТ со всеми авторами (до 50)
Скопировать
Thomas R. M., Widger P. C. B., Ahmed S. M., Jeske R. C., Hirahata W., Lobkovsky E. B., Coates G. W. Enantioselective Epoxide Polymerization Using a Bimetallic Cobalt Catalyst // Journal of the American Chemical Society. 2010. Vol. 132. No. 46. pp. 16520-16525.
Цитировать
RIS
Скопировать
TY - JOUR
DO - 10.1021/ja1058422
UR - https://doi.org/10.1021/ja1058422
TI - Enantioselective Epoxide Polymerization Using a Bimetallic Cobalt Catalyst
T2 - Journal of the American Chemical Society
AU - Thomas, Renee M
AU - Widger, Peter C B
AU - Ahmed, Syud M
AU - Jeske, Ryan C
AU - Hirahata, Wataru
AU - Lobkovsky, Emil B.
AU - Coates, Geoffrey W.
PY - 2010
DA - 2010/11/02
PB - American Chemical Society (ACS)
SP - 16520-16525
IS - 46
VL - 132
PMID - 21043488
SN - 0002-7863
SN - 1520-5126
ER -
Цитировать
BibTex (до 50 авторов)
Скопировать
@article{2010_Thomas,
author = {Renee M Thomas and Peter C B Widger and Syud M Ahmed and Ryan C Jeske and Wataru Hirahata and Emil B. Lobkovsky and Geoffrey W. Coates},
title = {Enantioselective Epoxide Polymerization Using a Bimetallic Cobalt Catalyst},
journal = {Journal of the American Chemical Society},
year = {2010},
volume = {132},
publisher = {American Chemical Society (ACS)},
month = {nov},
url = {https://doi.org/10.1021/ja1058422},
number = {46},
pages = {16520--16525},
doi = {10.1021/ja1058422}
}
Цитировать
MLA
Скопировать
Thomas, Renee M., et al. “Enantioselective Epoxide Polymerization Using a Bimetallic Cobalt Catalyst.” Journal of the American Chemical Society, vol. 132, no. 46, Nov. 2010, pp. 16520-16525. https://doi.org/10.1021/ja1058422.