A Pyrrolyl-Based Triazolophane: A Macrocyclic Receptor With CH and NH Donor Groups That Exhibits a Preference for Pyrophosphate Anions
Jonathan Sessler
1
,
Jiajia Cai
1
,
Han-Yuan Gong
1
,
Xiaoping Yang
1
,
Jonathan F. Arambula
1
,
Benjamin P. Hay
1
Publication type: Journal Article
Publication date: 2010-09-20
scimago Q1
wos Q1
SJR: 5.554
CiteScore: 22.5
Impact factor: 15.6
ISSN: 00027863, 15205126
PubMed ID:
20853896
General Chemistry
Catalysis
Biochemistry
Colloid and Surface Chemistry
Abstract
A pyrrolyl-based triazolophane, incorporating CH and NH donor groups, acts as a receptor for the pyrophosphate anion in chloroform solution. It shows selectivity for this trianion, followed by HSO4− > H2PO4− > Cl− > Br− (all as the corresponding tetrabutylammonium salts), with NH−anion interactions being more important than CH−anion interactions. In the solid state, the receptor binds the pyrophosphate anion in a clip-like slot via NH and CH hydrogen bonds.
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131
Total citations:
131
Citations from 2025:
1
(0.76%)
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GOST
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Sessler J. et al. A Pyrrolyl-Based Triazolophane: A Macrocyclic Receptor With CH and NH Donor Groups That Exhibits a Preference for Pyrophosphate Anions // Journal of the American Chemical Society. 2010. Vol. 132. No. 40. pp. 14058-14060.
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Sessler J., Cai J., Gong H., Yang X., F. Arambula J., Hay B. P. A Pyrrolyl-Based Triazolophane: A Macrocyclic Receptor With CH and NH Donor Groups That Exhibits a Preference for Pyrophosphate Anions // Journal of the American Chemical Society. 2010. Vol. 132. No. 40. pp. 14058-14060.
Cite this
RIS
Copy
TY - JOUR
DO - 10.1021/ja107098r
UR - https://doi.org/10.1021/ja107098r
TI - A Pyrrolyl-Based Triazolophane: A Macrocyclic Receptor With CH and NH Donor Groups That Exhibits a Preference for Pyrophosphate Anions
T2 - Journal of the American Chemical Society
AU - Sessler, Jonathan
AU - Cai, Jiajia
AU - Gong, Han-Yuan
AU - Yang, Xiaoping
AU - F. Arambula, Jonathan
AU - Hay, Benjamin P.
PY - 2010
DA - 2010/09/20
PB - American Chemical Society (ACS)
SP - 14058-14060
IS - 40
VL - 132
PMID - 20853896
SN - 0002-7863
SN - 1520-5126
ER -
Cite this
BibTex (up to 50 authors)
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@article{2010_Sessler,
author = {Jonathan Sessler and Jiajia Cai and Han-Yuan Gong and Xiaoping Yang and Jonathan F. Arambula and Benjamin P. Hay},
title = {A Pyrrolyl-Based Triazolophane: A Macrocyclic Receptor With CH and NH Donor Groups That Exhibits a Preference for Pyrophosphate Anions},
journal = {Journal of the American Chemical Society},
year = {2010},
volume = {132},
publisher = {American Chemical Society (ACS)},
month = {sep},
url = {https://doi.org/10.1021/ja107098r},
number = {40},
pages = {14058--14060},
doi = {10.1021/ja107098r}
}
Cite this
MLA
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Sessler, Jonathan, et al. “A Pyrrolyl-Based Triazolophane: A Macrocyclic Receptor With CH and NH Donor Groups That Exhibits a Preference for Pyrophosphate Anions.” Journal of the American Chemical Society, vol. 132, no. 40, Sep. 2010, pp. 14058-14060. https://doi.org/10.1021/ja107098r.