Journal of the American Chemical Society, volume 133, issue 13, pages 5036-5041
From Sulfur−Amine Solutions to Metal Sulfide Nanocrystals: Peering into the Oleylamine−Sulfur Black Box
1
Department of Chemistry, University of Toronto, 80 St. George Street, Toronto, Ontario M5S 3H6, Canada
|
2
Department of Chemical and Physical Sciences, University of Toronto Mississauga, 3359 Mississauga Road North, Mississauga, Ontario L5L 1C6, Canada
|
Publication type: Journal Article
Publication date: 2011-03-08
Quartile SCImago
Q1
Quartile WOS
Q1
Impact factor: 15
ISSN: 00027863, 15205126
General Chemistry
Catalysis
Biochemistry
Colloid and Surface Chemistry
Abstract
In this Article, we present our findings on the formation of metal sulfide nanocrystals from sulfur−alkylamine solutions. By pulsed field gradient diffusion NMR along with the standard toolbox of 1D and 2D NMR, we determined that sulfur−amine solutions used as a sulfur precursor exist as alkylammonium polysulfides at low temperatures. Upon heating to temperatures used in nanocrystal synthesis, the polysulfide ions react with excess amine to generate H2S, which combines with the metal precursor to form metal sulfide. Four different reaction pathways were found, each of which produced H2S and the byproducts identified in this Article. Thioamides were identified as an intermediate and were shown to exhibit much more rapid kinetics than sulfur−alkylamine solutions at low temperatures in the synthesis of metal sulfide nanocrystals.
Top-30
Citations by journals
|
5
10
15
20
25
30
35
|
|
|
Chemistry of Materials
32 publications, 13.06%
|
|
|
Journal of the American Chemical Society
15 publications, 6.12%
|
|
|
Nanoscale
8 publications, 3.27%
|
|
|
RSC Advances
8 publications, 3.27%
|
|
|
Inorganic Chemistry
7 publications, 2.86%
|
|
|
Journal of Physical Chemistry C
7 publications, 2.86%
|
|
|
ACS Nano
6 publications, 2.45%
|
|
|
ACS applied materials & interfaces
5 publications, 2.04%
|
|
|
Scientific Reports
4 publications, 1.63%
|
|
|
Small
4 publications, 1.63%
|
|
|
Particle and Particle Systems Characterization
4 publications, 1.63%
|
|
|
Nano Letters
4 publications, 1.63%
|
|
|
Chemical Communications
4 publications, 1.63%
|
|
|
CrystEngComm
4 publications, 1.63%
|
|
|
ACS Sustainable Chemistry and Engineering
3 publications, 1.22%
|
|
|
Nature Communications
3 publications, 1.22%
|
|
|
Journal of Solid State Chemistry
3 publications, 1.22%
|
|
|
Applied Surface Science
3 publications, 1.22%
|
|
|
Nano Energy
3 publications, 1.22%
|
|
|
Advanced Materials
3 publications, 1.22%
|
|
|
ACS Applied Nano Materials
3 publications, 1.22%
|
|
|
Nanoscale Horizons
3 publications, 1.22%
|
|
|
Journal of Materials Chemistry A
3 publications, 1.22%
|
|
|
Dalton Transactions
3 publications, 1.22%
|
|
|
Journal of Materials Chemistry C
3 publications, 1.22%
|
|
|
Nanomaterials
2 publications, 0.82%
|
|
|
Nano Research
2 publications, 0.82%
|
|
|
Advanced Energy Materials
2 publications, 0.82%
|
|
|
Russian Chemical Reviews
2 publications, 0.82%
|
|
|
5
10
15
20
25
30
35
|
Citations by publishers
|
20
40
60
80
100
120
|
|
|
American Chemical Society (ACS)
107 publications, 43.67%
|
|
|
Royal Society of Chemistry (RSC)
45 publications, 18.37%
|
|
|
Wiley
31 publications, 12.65%
|
|
|
Elsevier
29 publications, 11.84%
|
|
|
Springer Nature
13 publications, 5.31%
|
|
|
Multidisciplinary Digital Publishing Institute (MDPI)
5 publications, 2.04%
|
|
|
Autonomous Non-profit Organization Editorial Board of the journal Uspekhi Khimii
2 publications, 0.82%
|
|
|
Beilstein-Institut
1 publication, 0.41%
|
|
|
American Vacuum Society
1 publication, 0.41%
|
|
|
The Chemical Society of Japan
1 publication, 0.41%
|
|
|
Frontiers Media S.A.
1 publication, 0.41%
|
|
|
Cambridge University Press
1 publication, 0.41%
|
|
|
Taylor & Francis
1 publication, 0.41%
|
|
|
Pleiades Publishing
1 publication, 0.41%
|
|
|
Walter de Gruyter
1 publication, 0.41%
|
|
|
American Association for the Advancement of Science (AAAS)
1 publication, 0.41%
|
|
|
Thieme
1 publication, 0.41%
|
|
|
20
40
60
80
100
120
|
- We do not take into account publications without a DOI.
- Statistics recalculated only for publications connected to researchers, organizations and labs registered on the platform.
- Statistics recalculated weekly.
{"yearsCitations":{"type":"bar","data":{"show":true,"labels":[2011,2012,2013,2014,2015,2016,2017,2018,2019,2020,2021,2022,2023,2024],"ids":[0,0,0,0,0,0,0,0,0,0,0,0,0,0],"codes":[0,0,0,0,0,0,0,0,0,0,0,0,0,0],"imageUrls":["","","","","","","","","","","","","",""],"datasets":[{"label":"Citations number","data":[4,11,14,20,25,18,16,20,21,20,18,20,19,19],"backgroundColor":["#3B82F6","#3B82F6","#3B82F6","#3B82F6","#3B82F6","#3B82F6","#3B82F6","#3B82F6","#3B82F6","#3B82F6","#3B82F6","#3B82F6","#3B82F6","#3B82F6"],"percentage":["1.63","4.49","5.71","8.16","10.2","7.35","6.53","8.16","8.57","8.16","7.35","8.16","7.76","7.76"],"barThickness":null}]},"options":{"indexAxis":"x","maintainAspectRatio":true,"scales":{"y":{"ticks":{"precision":0,"autoSkip":false,"font":{"family":"Montserrat"},"color":"#000000"},"stacked":false},"x":{"ticks":{"stepSize":1,"precision":0,"font":{"family":"Montserrat"},"color":"#000000"},"stacked":false}},"plugins":{"legend":{"position":"top","labels":{"font":{"family":"Montserrat"},"color":"#000000"}},"title":{"display":true,"text":"Citations per year","font":{"size":24,"family":"Montserrat","weight":600},"color":"#000000"}}}},"journals":{"type":"bar","data":{"show":true,"labels":["Chemistry of Materials","Journal of the American Chemical Society","Nanoscale","RSC Advances","Inorganic Chemistry","Journal of Physical Chemistry C","ACS Nano","ACS applied materials & interfaces","Scientific Reports","Small","Particle and Particle Systems Characterization","Nano Letters","Chemical Communications","CrystEngComm","ACS Sustainable Chemistry and Engineering","Nature Communications","Journal of Solid State Chemistry","Applied Surface Science","Nano Energy","Advanced Materials","ACS Applied Nano Materials","Nanoscale Horizons","Journal of Materials Chemistry A","Dalton Transactions","Journal of Materials Chemistry C","Nanomaterials","Nano Research","Advanced Energy Materials","Russian Chemical Reviews"],"ids":[6428,4813,228,3100,24714,8859,8724,1458,13767,9872,12914,10312,9073,7359,18886,3231,2684,12539,23236,25159,1600,3623,14919,8473,3848,10051,12211,22475,23802],"codes":[0,0,0,0,0,0,0,0,0,0,0,0,0,0,0,0,0,0,0,0,0,0,0,0,0,0,0,0,0],"imageUrls":["\/storage\/images\/resized\/iLiQsFqFaSEx6chlGQ5fbAwF6VYU3WWa08hkss0g_medium.webp","\/storage\/images\/resized\/iLiQsFqFaSEx6chlGQ5fbAwF6VYU3WWa08hkss0g_medium.webp","\/storage\/images\/resized\/leiAYcRDGTSl5B1eCnwpSGqmDEUEfDPPoYisFGhT_medium.webp","\/storage\/images\/resized\/leiAYcRDGTSl5B1eCnwpSGqmDEUEfDPPoYisFGhT_medium.webp","\/storage\/images\/resized\/iLiQsFqFaSEx6chlGQ5fbAwF6VYU3WWa08hkss0g_medium.webp","\/storage\/images\/resized\/iLiQsFqFaSEx6chlGQ5fbAwF6VYU3WWa08hkss0g_medium.webp","\/storage\/images\/resized\/iLiQsFqFaSEx6chlGQ5fbAwF6VYU3WWa08hkss0g_medium.webp","\/storage\/images\/resized\/iLiQsFqFaSEx6chlGQ5fbAwF6VYU3WWa08hkss0g_medium.webp","\/storage\/images\/resized\/voXLqlsvTwv5p3iMQ8Dhs95nqB4AXOG7Taj7G4ra_medium.webp","\/storage\/images\/resized\/bRyGpdm98BkAUYiK1YFNpl5Z7hPu6Gd87gbIeuG3_medium.webp","\/storage\/images\/resized\/bRyGpdm98BkAUYiK1YFNpl5Z7hPu6Gd87gbIeuG3_medium.webp","\/storage\/images\/resized\/iLiQsFqFaSEx6chlGQ5fbAwF6VYU3WWa08hkss0g_medium.webp","\/storage\/images\/resized\/leiAYcRDGTSl5B1eCnwpSGqmDEUEfDPPoYisFGhT_medium.webp","\/storage\/images\/resized\/leiAYcRDGTSl5B1eCnwpSGqmDEUEfDPPoYisFGhT_medium.webp","\/storage\/images\/resized\/iLiQsFqFaSEx6chlGQ5fbAwF6VYU3WWa08hkss0g_medium.webp","\/storage\/images\/resized\/voXLqlsvTwv5p3iMQ8Dhs95nqB4AXOG7Taj7G4ra_medium.webp","\/storage\/images\/resized\/GDnYOu1UpMMfMMRV6Aqle4H0YLLsraeD9IP9qScG_medium.webp","\/storage\/images\/resized\/GDnYOu1UpMMfMMRV6Aqle4H0YLLsraeD9IP9qScG_medium.webp","\/storage\/images\/resized\/GDnYOu1UpMMfMMRV6Aqle4H0YLLsraeD9IP9qScG_medium.webp","\/storage\/images\/resized\/bRyGpdm98BkAUYiK1YFNpl5Z7hPu6Gd87gbIeuG3_medium.webp","\/storage\/images\/resized\/iLiQsFqFaSEx6chlGQ5fbAwF6VYU3WWa08hkss0g_medium.webp","\/storage\/images\/resized\/leiAYcRDGTSl5B1eCnwpSGqmDEUEfDPPoYisFGhT_medium.webp","\/storage\/images\/resized\/leiAYcRDGTSl5B1eCnwpSGqmDEUEfDPPoYisFGhT_medium.webp","\/storage\/images\/resized\/leiAYcRDGTSl5B1eCnwpSGqmDEUEfDPPoYisFGhT_medium.webp","\/storage\/images\/resized\/leiAYcRDGTSl5B1eCnwpSGqmDEUEfDPPoYisFGhT_medium.webp","\/storage\/images\/resized\/MjH1ITP7lMYGxeqUZfkt2BnVLgjkk413jwBV97XX_medium.webp","\/storage\/images\/resized\/voXLqlsvTwv5p3iMQ8Dhs95nqB4AXOG7Taj7G4ra_medium.webp","\/storage\/images\/resized\/bRyGpdm98BkAUYiK1YFNpl5Z7hPu6Gd87gbIeuG3_medium.webp","\/storage\/images\/resized\/9Mus3KG1Tkd7Bwaurt8H3RwWh0CxRlGoO6ng9UK1_medium.webp"],"datasets":[{"label":"","data":[32,15,8,8,7,7,6,5,4,4,4,4,4,4,3,3,3,3,3,3,3,3,3,3,3,2,2,2,2],"backgroundColor":["#3B82F6","#3B82F6","#3B82F6","#3B82F6","#3B82F6","#3B82F6","#3B82F6","#3B82F6","#3B82F6","#3B82F6","#3B82F6","#3B82F6","#3B82F6","#3B82F6","#3B82F6","#3B82F6","#3B82F6","#3B82F6","#3B82F6","#3B82F6","#3B82F6","#3B82F6","#3B82F6","#3B82F6","#3B82F6","#3B82F6","#3B82F6","#3B82F6","#3B82F6"],"percentage":[13.06,6.12,3.27,3.27,2.86,2.86,2.45,2.04,1.63,1.63,1.63,1.63,1.63,1.63,1.22,1.22,1.22,1.22,1.22,1.22,1.22,1.22,1.22,1.22,1.22,0.82,0.82,0.82,0.82],"barThickness":13}]},"options":{"indexAxis":"y","maintainAspectRatio":false,"scales":{"y":{"ticks":{"precision":0,"autoSkip":false,"font":{"family":"Montserrat"},"color":"#000000"},"stacked":false},"x":{"ticks":{"stepSize":null,"precision":0,"font":{"family":"Montserrat"},"color":"#000000"},"stacked":false}},"plugins":{"legend":{"position":"top","labels":{"font":{"family":"Montserrat"},"color":"#000000"}},"title":{"display":true,"text":"Journals","font":{"size":24,"family":"Montserrat","weight":600},"color":"#000000"}}}},"publishers":{"type":"bar","data":{"show":true,"labels":["American Chemical Society (ACS)","Royal Society of Chemistry (RSC)","Wiley","Elsevier","Springer Nature","Multidisciplinary Digital Publishing Institute (MDPI)","Autonomous Non-profit Organization Editorial Board of the journal Uspekhi Khimii","Beilstein-Institut","American Vacuum Society","The Chemical Society of Japan","Frontiers Media S.A.","Cambridge University Press","Taylor & Francis","Pleiades Publishing","Walter de Gruyter","American Association for the Advancement of Science (AAAS)","Thieme"],"ids":[40,123,11,17,8,202,9422,6139,4511,6950,208,1,18,101,4,189,135],"codes":[0,0,0,0,0,0,0,0,0,0,0,0,0,0,0,0,0],"imageUrls":["\/storage\/images\/resized\/iLiQsFqFaSEx6chlGQ5fbAwF6VYU3WWa08hkss0g_medium.webp","\/storage\/images\/resized\/leiAYcRDGTSl5B1eCnwpSGqmDEUEfDPPoYisFGhT_medium.webp","\/storage\/images\/resized\/bRyGpdm98BkAUYiK1YFNpl5Z7hPu6Gd87gbIeuG3_medium.webp","\/storage\/images\/resized\/GDnYOu1UpMMfMMRV6Aqle4H0YLLsraeD9IP9qScG_medium.webp","\/storage\/images\/resized\/voXLqlsvTwv5p3iMQ8Dhs95nqB4AXOG7Taj7G4ra_medium.webp","\/storage\/images\/resized\/MjH1ITP7lMYGxeqUZfkt2BnVLgjkk413jwBV97XX_medium.webp","\/storage\/images\/resized\/9Mus3KG1Tkd7Bwaurt8H3RwWh0CxRlGoO6ng9UK1_medium.webp","\/storage\/images\/resized\/ex6KJoZujZOZFZh7jGfeHauiftuB3CI7iwJVFRDg_medium.webp","\/storage\/images\/resized\/uCIAsivcf0PwzbBKNlcVk4osRd48viDZSveDRvyx_medium.webp","\/storage\/images\/resized\/ktSZPrGjOMvauY6mn7jk8bqo3Af0S6abv653w90B_medium.webp","\/storage\/images\/resized\/4QWA67eqfcfyOiA8Wk7YnqroHFqQbTsmDJUYTCTg_medium.webp","\/storage\/images\/resized\/cF81zWlLdkmYekymGuDcSdvgBGNKaIDoMoeJtHS1_medium.webp","\/storage\/images\/resized\/5YZtvLvkPZuc2JHOaZsjCvGSHFCuC3drUwN3YAc5_medium.webp","\/storage\/images\/resized\/oZgeErrVFhuDksyqFURLvYS1wtVSBWczh001igGo_medium.webp","\/storage\/images\/resized\/3SpVxcYL33bOvPq4sHxJLH2NeKNeDloahSUpNiO4_medium.webp","\/storage\/images\/resized\/s10mcsCV4OAUg9O2KrqOquQC0PhyLMI8hUUkuflM_medium.webp","\/storage\/images\/resized\/xqixcltwJYe6H8Uco2JbAFfIOzt7UNKH0OcPOPzO_medium.webp"],"datasets":[{"label":"","data":[107,45,31,29,13,5,2,1,1,1,1,1,1,1,1,1,1],"backgroundColor":["#3B82F6","#3B82F6","#3B82F6","#3B82F6","#3B82F6","#3B82F6","#3B82F6","#3B82F6","#3B82F6","#3B82F6","#3B82F6","#3B82F6","#3B82F6","#3B82F6","#3B82F6","#3B82F6","#3B82F6"],"percentage":[43.67,18.37,12.65,11.84,5.31,2.04,0.82,0.41,0.41,0.41,0.41,0.41,0.41,0.41,0.41,0.41,0.41],"barThickness":13}]},"options":{"indexAxis":"y","maintainAspectRatio":false,"scales":{"y":{"ticks":{"precision":0,"autoSkip":false,"font":{"family":"Montserrat"},"color":"#000000"},"stacked":false},"x":{"ticks":{"stepSize":null,"precision":0,"font":{"family":"Montserrat"},"color":"#000000"},"stacked":false}},"plugins":{"legend":{"position":"top","labels":{"font":{"family":"Montserrat"},"color":"#000000"}},"title":{"display":true,"text":"Publishers","font":{"size":24,"family":"Montserrat","weight":600},"color":"#000000"}}}},"yearsCitationsQuartiles":{"type":"bar","data":{"show":true,"labels":[2011,2012,2013,2014,2015,2016,2017,2018,2019,2020,2021,2022,2023,2024],"ids":[],"codes":[],"imageUrls":[],"datasets":[{"label":"Q4","backgroundColor":"rgb(221,90,78)","data":[0,0,0,0,0,0,0,0,0,0,0,0,0,0],"percentage":["0","0","0","0","0","0","0","0","0","0","0","0","0","0"]},{"label":"Q3","backgroundColor":"rgb(251, 163,83)","data":[0,0,0,0,0,0,0,0,0,1,1,1,0,0],"percentage":["0","0","0","0","0","0","0","0","0","0.41","0.41","0.41","0","0"]},{"label":"Q2","backgroundColor":"rgb(232, 213, 89)","data":[1,0,2,2,7,4,4,4,3,3,3,2,1,4],"percentage":["0.41","0","0.82","0.82","2.86","1.63","1.63","1.63","1.22","1.22","1.22","0.82","0.41","1.63"]},{"label":"Q1","backgroundColor":"rgb(164, 207, 99)","data":[3,10,11,18,18,13,11,16,18,16,12,16,18,14],"percentage":["1.22","4.08","4.49","7.35","7.35","5.31","4.49","6.53","7.35","6.53","4.9","6.53","7.35","5.71"]},{"label":"Quartile not defined","backgroundColor":"#E5E7EB","data":[0,1,1,0,0,1,1,0,0,0,2,1,0,1],"percentage":["0","0.41","0.41","0","0","0.41","0.41","0","0","0","0.82","0.41","0","0.41"]}]},"options":{"indexAxis":"x","maintainAspectRatio":true,"scales":{"y":{"ticks":{"precision":0,"autoSkip":false,"font":{"family":"Montserrat"},"color":"#000000"},"stacked":true},"x":{"ticks":{"stepSize":1,"precision":0,"font":{"family":"Montserrat"},"color":"#000000"},"stacked":true}},"plugins":{"legend":{"position":"top","labels":{"font":{"family":"Montserrat"},"color":"#000000"}},"title":{"display":true,"text":"Citations quartiles by SCImago per year","font":{"size":24,"family":"Montserrat","weight":600},"color":"#000000"}}}},"yearsCitationsQuartilesWs":{"type":"bar","data":{"show":true,"labels":[2011,2012,2013,2014,2015,2016,2017,2018,2019,2020,2021,2022,2023,2024],"ids":[],"codes":[],"imageUrls":[],"datasets":[{"label":"Q4","backgroundColor":"rgb(221,90,78)","data":[0,0,0,0,0,0,1,0,0,1,0,0,0,0],"percentage":["0","0","0","0","0","0","0.41","0","0","0.41","0","0","0","0"]},{"label":"Q3","backgroundColor":"rgb(251, 163,83)","data":[0,0,0,0,1,2,2,0,1,1,3,0,1,1],"percentage":["0","0","0","0","0.41","0.82","0.82","0","0.41","0.41","1.22","0","0.41","0.41"]},{"label":"Q2","backgroundColor":"rgb(232, 213, 89)","data":[1,0,3,6,6,2,4,6,6,4,4,3,1,4],"percentage":["0.41","0","1.22","2.45","2.45","0.82","1.63","2.45","2.45","1.63","1.63","1.22","0.41","1.63"]},{"label":"Q1","backgroundColor":"rgb(164, 207, 99)","data":[3,10,9,13,18,13,7,14,13,14,9,13,16,11],"percentage":["1.22","4.08","3.67","5.31","7.35","5.31","2.86","5.71","5.31","5.71","3.67","5.31","6.53","4.49"]},{"label":"Quartile not defined","backgroundColor":"#E5E7EB","data":[0,1,2,1,0,1,2,0,1,0,2,4,1,3],"percentage":["0","0.41","0.82","0.41","0","0.41","0.82","0","0.41","0","0.82","1.63","0.41","1.22"]}]},"options":{"indexAxis":"x","maintainAspectRatio":true,"scales":{"y":{"ticks":{"precision":0,"autoSkip":false,"font":{"family":"Montserrat"},"color":"#000000"},"stacked":true},"x":{"ticks":{"stepSize":1,"precision":0,"font":{"family":"Montserrat"},"color":"#000000"},"stacked":true}},"plugins":{"legend":{"position":"top","labels":{"font":{"family":"Montserrat"},"color":"#000000"}},"title":{"display":true,"text":"Citations quartiles by WoS per year","font":{"size":24,"family":"Montserrat","weight":600},"color":"#000000"}}}}}
Are you a researcher?
Create a profile to get free access to personal recommendations for colleagues and new articles.
Metrics
Cite this
GOST |
RIS |
BibTex |
MLA
Cite this
GOST
Copy
Thomson J. W. et al. From Sulfur−Amine Solutions to Metal Sulfide Nanocrystals: Peering into the Oleylamine−Sulfur Black Box // Journal of the American Chemical Society. 2011. Vol. 133. No. 13. pp. 5036-5041.
GOST all authors (up to 50)
Copy
Thomson J. W., Nagashima K., MacDonald P., Ozin G. A. From Sulfur−Amine Solutions to Metal Sulfide Nanocrystals: Peering into the Oleylamine−Sulfur Black Box // Journal of the American Chemical Society. 2011. Vol. 133. No. 13. pp. 5036-5041.
Cite this
RIS
Copy
TY - JOUR
DO - 10.1021/ja1109997
UR - https://doi.org/10.1021/ja1109997
TI - From Sulfur−Amine Solutions to Metal Sulfide Nanocrystals: Peering into the Oleylamine−Sulfur Black Box
T2 - Journal of the American Chemical Society
AU - Thomson, Jordan W
AU - Nagashima, Kaz
AU - MacDonald, Paul
AU - Ozin, G A.
PY - 2011
DA - 2011/03/08 00:00:00
PB - American Chemical Society (ACS)
SP - 5036-5041
IS - 13
VL - 133
SN - 0002-7863
SN - 1520-5126
ER -
Cite this
BibTex
Copy
@article{2011_Thomson,
author = {Jordan W Thomson and Kaz Nagashima and Paul MacDonald and G A. Ozin},
title = {From Sulfur−Amine Solutions to Metal Sulfide Nanocrystals: Peering into the Oleylamine−Sulfur Black Box},
journal = {Journal of the American Chemical Society},
year = {2011},
volume = {133},
publisher = {American Chemical Society (ACS)},
month = {mar},
url = {https://doi.org/10.1021/ja1109997},
number = {13},
pages = {5036--5041},
doi = {10.1021/ja1109997}
}
Cite this
MLA
Copy
Thomson, Jordan W., et al. “From Sulfur−Amine Solutions to Metal Sulfide Nanocrystals: Peering into the Oleylamine−Sulfur Black Box.” Journal of the American Chemical Society, vol. 133, no. 13, Mar. 2011, pp. 5036-5041. https://doi.org/10.1021/ja1109997.