11-Step Enantioselective Synthesis of (−)-Lomaiviticin Aglycon
Тип публикации: Journal Article
Дата публикации: 2011-01-31
scimago Q1
wos Q1
БС1
SJR: 5.489
CiteScore: 24.4
Impact factor: 15.6
ISSN: 00027863, 15205126
PubMed ID:
21280607
General Chemistry
Catalysis
Biochemistry
Colloid and Surface Chemistry
Краткое описание
Lomaiviticins A and B are complex antitumor antibiotics that were isolated from a strain of Micromonospora. A confluence of several unusual structural features renders the lomaiviticins exceedingly challenging targets for chemical synthesis. We report an 11-step, enantioselective synthetic route to lomaiviticin aglycon. Our route proceeds by late-stage, stereoselective dimerization of two equivalent monomeric intermediates, a transformation that may share parallels with the natural products' biosyntheses. The route we describe is scalable and convergent, and it lays the foundation for determination of the mode of action of these natural products.
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ГОСТ
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Herzon S. B. et al. 11-Step Enantioselective Synthesis of (−)-Lomaiviticin Aglycon // Journal of the American Chemical Society. 2011. Vol. 133. No. 19. pp. 7260-7263.
ГОСТ со всеми авторами (до 50)
Скопировать
Herzon S. B., Lu L., Woo C. M., Gholap S. L. 11-Step Enantioselective Synthesis of (−)-Lomaiviticin Aglycon // Journal of the American Chemical Society. 2011. Vol. 133. No. 19. pp. 7260-7263.
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RIS
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TY - JOUR
DO - 10.1021/ja200034b
UR - https://doi.org/10.1021/ja200034b
TI - 11-Step Enantioselective Synthesis of (−)-Lomaiviticin Aglycon
T2 - Journal of the American Chemical Society
AU - Herzon, Seth B.
AU - Lu, Liang
AU - Woo, Christina M.
AU - Gholap, Shivajirao L
PY - 2011
DA - 2011/01/31
PB - American Chemical Society (ACS)
SP - 7260-7263
IS - 19
VL - 133
PMID - 21280607
SN - 0002-7863
SN - 1520-5126
ER -
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BibTex (до 50 авторов)
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@article{2011_Herzon,
author = {Seth B. Herzon and Liang Lu and Christina M. Woo and Shivajirao L Gholap},
title = {11-Step Enantioselective Synthesis of (−)-Lomaiviticin Aglycon},
journal = {Journal of the American Chemical Society},
year = {2011},
volume = {133},
publisher = {American Chemical Society (ACS)},
month = {jan},
url = {https://doi.org/10.1021/ja200034b},
number = {19},
pages = {7260--7263},
doi = {10.1021/ja200034b}
}
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MLA
Скопировать
Herzon, Seth B., et al. “11-Step Enantioselective Synthesis of (−)-Lomaiviticin Aglycon.” Journal of the American Chemical Society, vol. 133, no. 19, Jan. 2011, pp. 7260-7263. https://doi.org/10.1021/ja200034b.