Journal of the American Chemical Society, volume 133, issue 27, pages 10612-10620
Metal-free inorganic ligands for colloidal nanocrystals: S2-, HS-, Se2-, HSe-, Te2-, HTe-, TeS3(2-), OH-, and NH2- as surface ligands.
Publication type: Journal Article
Publication date: 2011-06-17
Quartile SCImago
Q1
Quartile WOS
Q1
Impact factor: 15
ISSN: 00027863, 15205126
General Chemistry
Catalysis
Biochemistry
Colloid and Surface Chemistry
Abstract
All-inorganic colloidal nanocrystals were synthesized by replacing organic capping ligands on chemically synthesized nanocrystals with metal-free inorganic ions such as S(2-), HS(-), Se(2-), HSe(-), Te(2-), HTe(-), TeS(3)(2-), OH(-) and NH(2)(-). These simple ligands adhered to the NC surface and provided colloidal stability in polar solvents. The versatility of such ligand exchange has been demonstrated for various semiconductor and metal nanocrystals of different size and shape. We showed that the key aspects of Pearson's hard and soft acids and bases (HSAB) principle, originally developed for metal coordination compounds, can be applied to the bonding of molecular species to the nanocrystal surface. The use of small inorganic ligands instead of traditional ligands with long hydrocarbon tails facilitated the charge transport between individual nanocrystals and opened up interesting opportunities for device integration of colloidal nanostructures.
Top-30
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Citations by publishers
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American Chemical Society (ACS)
294 publications, 45.79%
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Royal Society of Chemistry (RSC)
96 publications, 14.95%
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Wiley
85 publications, 13.24%
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Elsevier
55 publications, 8.57%
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Springer Nature
48 publications, 7.48%
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Multidisciplinary Digital Publishing Institute (MDPI)
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Cambridge University Press
4 publications, 0.62%
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American Physical Society (APS)
2 publications, 0.31%
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Autonomous Non-profit Organization Editorial Board of the journal Uspekhi Khimii
2 publications, 0.31%
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IEEE
2 publications, 0.31%
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Walter de Gruyter
2 publications, 0.31%
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Optical Society of America
2 publications, 0.31%
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American Vacuum Society
1 publication, 0.16%
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Materials Research Society
1 publication, 0.16%
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Public Library of Science (PLoS)
1 publication, 0.16%
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Korean Society of Industrial Engineering Chemistry
1 publication, 0.16%
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1 publication, 0.16%
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American Association for the Advancement of Science (AAAS)
1 publication, 0.16%
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Trans Tech Publications
1 publication, 0.16%
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Annual Reviews
1 publication, 0.16%
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SPIE
1 publication, 0.16%
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Pleiades Publishing
1 publication, 0.16%
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- We do not take into account publications without a DOI.
- Statistics recalculated only for publications connected to researchers, organizations and labs registered on the platform.
- Statistics recalculated weekly.
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Nag A. et al. Metal-free inorganic ligands for colloidal nanocrystals: S2-, HS-, Se2-, HSe-, Te2-, HTe-, TeS3(2-), OH-, and NH2- as surface ligands. // Journal of the American Chemical Society. 2011. Vol. 133. No. 27. pp. 10612-10620.
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Nag A., Kovalenko M. V., Lee J., Liu W., Spokoyny B., Talapin D. V. Metal-free inorganic ligands for colloidal nanocrystals: S2-, HS-, Se2-, HSe-, Te2-, HTe-, TeS3(2-), OH-, and NH2- as surface ligands. // Journal of the American Chemical Society. 2011. Vol. 133. No. 27. pp. 10612-10620.
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TY - JOUR
DO - 10.1021/ja2029415
UR - https://doi.org/10.1021/ja2029415
TI - Metal-free inorganic ligands for colloidal nanocrystals: S2-, HS-, Se2-, HSe-, Te2-, HTe-, TeS3(2-), OH-, and NH2- as surface ligands.
T2 - Journal of the American Chemical Society
AU - Liu, Wenyong
AU - Nag, Angshuman
AU - Kovalenko, Maksym V.
AU - Lee, Joohyoung
AU - Spokoyny, Boris
AU - Talapin, Dmitri V.
PY - 2011
DA - 2011/06/17 00:00:00
PB - American Chemical Society (ACS)
SP - 10612-10620
IS - 27
VL - 133
SN - 0002-7863
SN - 1520-5126
ER -
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@article{2011_Nag,
author = {Wenyong Liu and Angshuman Nag and Maksym V. Kovalenko and Joohyoung Lee and Boris Spokoyny and Dmitri V. Talapin},
title = {Metal-free inorganic ligands for colloidal nanocrystals: S2-, HS-, Se2-, HSe-, Te2-, HTe-, TeS3(2-), OH-, and NH2- as surface ligands.},
journal = {Journal of the American Chemical Society},
year = {2011},
volume = {133},
publisher = {American Chemical Society (ACS)},
month = {jun},
url = {https://doi.org/10.1021/ja2029415},
number = {27},
pages = {10612--10620},
doi = {10.1021/ja2029415}
}
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Nag, Angshuman, et al. “Metal-free inorganic ligands for colloidal nanocrystals: S2-, HS-, Se2-, HSe-, Te2-, HTe-, TeS3(2-), OH-, and NH2- as surface ligands..” Journal of the American Chemical Society, vol. 133, no. 27, Jun. 2011, pp. 10612-10620. https://doi.org/10.1021/ja2029415.