Open Access
A polar corundum oxide displaying weak ferromagnetism at room temperature
Man-Rong Li
1
,
U. Adem
1
,
Zhongling Xu
1
,
Christopher Thomas
1
,
J. Warren
1
,
Duong V Giap
1
,
Hongjun Niu
1
,
Xinming Wan
1
,
R. G. Palgrave
1
,
Florian Schiffmann
2
,
Furio Corà
2
,
Ben Slater
2
,
Tim Burnett
3
,
Markys G. Cain
3
,
Gustaaf Van Tendeloo
4
,
Michael F. THOMAS
5
,
Publication type: Journal Article
Publication date: 2012-02-15
scimago Q1
wos Q1
SJR: 5.554
CiteScore: 22.5
Impact factor: 15.6
ISSN: 00027863, 15205126
PubMed ID:
22280499
General Chemistry
Catalysis
Biochemistry
Colloid and Surface Chemistry
Abstract
Combining long-range magnetic order with polarity in the same structure is a prerequisite for the design of (magnetoelectric) multiferroic materials. There are now several demonstrated strategies to achieve this goal, but retaining magnetic order above room temperature remains a difficult target. Iron oxides in the +3 oxidation state have high magnetic ordering temperatures due to the size of the coupled moments. Here we prepare and characterize ScFeO3 (SFO), which under pressure and in strain-stabilized thin films adopts a polar variant of the corundum structure, one of the archetypal binary oxide structures. Polar corundum ScFeO3 has a weak ferromagnetic ground state below 356 K—this is in contrast to the purely antiferromagnetic ground state adopted by the well-studied ferroelectric BiFeO3.
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Metrics
78
Total citations:
78
Citations from 2024:
7
(8.98%)
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GOST
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Li M. et al. A polar corundum oxide displaying weak ferromagnetism at room temperature // Journal of the American Chemical Society. 2012. Vol. 134. No. 8. pp. 3737-3747.
GOST all authors (up to 50)
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Li M., Adem U., Mcmitchell S. R. C., Xu Z., Thomas C., Warren J., Giap D. V., Niu H., Wan X., Palgrave R. G., Schiffmann F., Corà F., Slater B., Burnett T., Cain M. G., Abakumov A. M., Van Tendeloo G., THOMAS M. F., Rosseinsky M. J., Claridge J. B. A polar corundum oxide displaying weak ferromagnetism at room temperature // Journal of the American Chemical Society. 2012. Vol. 134. No. 8. pp. 3737-3747.
Cite this
RIS
Copy
TY - JOUR
DO - 10.1021/ja208395z
UR - https://doi.org/10.1021/ja208395z
TI - A polar corundum oxide displaying weak ferromagnetism at room temperature
T2 - Journal of the American Chemical Society
AU - Li, Man-Rong
AU - Adem, U.
AU - Mcmitchell, Sean R C
AU - Xu, Zhongling
AU - Thomas, Christopher
AU - Warren, J.
AU - Giap, Duong V
AU - Niu, Hongjun
AU - Wan, Xinming
AU - Palgrave, R. G.
AU - Schiffmann, Florian
AU - Corà, Furio
AU - Slater, Ben
AU - Burnett, Tim
AU - Cain, Markys G.
AU - Abakumov, Artem M.
AU - Van Tendeloo, Gustaaf
AU - THOMAS, Michael F.
AU - Rosseinsky, Matthew J.
AU - Claridge, John B.
PY - 2012
DA - 2012/02/15
PB - American Chemical Society (ACS)
SP - 3737-3747
IS - 8
VL - 134
PMID - 22280499
SN - 0002-7863
SN - 1520-5126
ER -
Cite this
BibTex (up to 50 authors)
Copy
@article{2012_Li,
author = {Man-Rong Li and U. Adem and Sean R C Mcmitchell and Zhongling Xu and Christopher Thomas and J. Warren and Duong V Giap and Hongjun Niu and Xinming Wan and R. G. Palgrave and Florian Schiffmann and Furio Corà and Ben Slater and Tim Burnett and Markys G. Cain and Artem M. Abakumov and Gustaaf Van Tendeloo and Michael F. THOMAS and Matthew J. Rosseinsky and John B. Claridge},
title = {A polar corundum oxide displaying weak ferromagnetism at room temperature},
journal = {Journal of the American Chemical Society},
year = {2012},
volume = {134},
publisher = {American Chemical Society (ACS)},
month = {feb},
url = {https://doi.org/10.1021/ja208395z},
number = {8},
pages = {3737--3747},
doi = {10.1021/ja208395z}
}
Cite this
MLA
Copy
Li, Man-Rong, et al. “A polar corundum oxide displaying weak ferromagnetism at room temperature.” Journal of the American Chemical Society, vol. 134, no. 8, Feb. 2012, pp. 3737-3747. https://doi.org/10.1021/ja208395z.
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