Crossing the Insulator-to-Metal Barrier with a Thiazyl Radical Conductor
Aaron Mailman
1
,
STEPHEN M. WINTER
1
,
Xin Yu
1
,
Craig M Robertson
2
,
Wenjun Yong
3
,
JOHN S. TSE
4
,
Richard A. Secco
3
,
Zhenxian Liu
5
,
Paul A. Dube
6
,
Judith A. K. Howard
2
,
Richard T. Oakley
1
Publication type: Journal Article
Publication date: 2012-06-08
scimago Q1
wos Q1
SJR: 5.554
CiteScore: 22.5
Impact factor: 15.6
ISSN: 00027863, 15205126
PubMed ID:
22681388
General Chemistry
Catalysis
Biochemistry
Colloid and Surface Chemistry
Abstract
The layered-sheet architecture of the crystal structure of the fluoro-substituted oxobenzene-bridged bisdithiazolyl radical FBBO affords a 2D π-electronic structure with a large calculated bandwidth. The material displays high electrical conductivity for a f = 1/2 system, with σ(300 K) = 2 × 10(-2) S cm(-1). While the conductivity is thermally activated at ambient pressure, with E(act) = 0.10 eV at 300 K, indicative of a Mott insulating state, E(act) is eliminated at 3 GPa, suggesting the formation of a metallic state. The onset of metallization is supported by infrared measurements, which show closure of the Mott-Hubbard gap above 3 GPa.
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Total citations:
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Citations from 2024:
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Mailman A. et al. Crossing the Insulator-to-Metal Barrier with a Thiazyl Radical Conductor // Journal of the American Chemical Society. 2012. Vol. 134. No. 24. pp. 9886-9889.
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Mailman A., WINTER S. M., Yu X., Robertson C. M., Yong W., TSE J. S., Secco R. A., Liu Z., Dube P. A., Howard J. A. K., Oakley R. T. Crossing the Insulator-to-Metal Barrier with a Thiazyl Radical Conductor // Journal of the American Chemical Society. 2012. Vol. 134. No. 24. pp. 9886-9889.
Cite this
RIS
Copy
TY - JOUR
DO - 10.1021/ja303169y
UR - https://doi.org/10.1021/ja303169y
TI - Crossing the Insulator-to-Metal Barrier with a Thiazyl Radical Conductor
T2 - Journal of the American Chemical Society
AU - Mailman, Aaron
AU - WINTER, STEPHEN M.
AU - Yu, Xin
AU - Robertson, Craig M
AU - Yong, Wenjun
AU - TSE, JOHN S.
AU - Secco, Richard A.
AU - Liu, Zhenxian
AU - Dube, Paul A.
AU - Howard, Judith A. K.
AU - Oakley, Richard T.
PY - 2012
DA - 2012/06/08
PB - American Chemical Society (ACS)
SP - 9886-9889
IS - 24
VL - 134
PMID - 22681388
SN - 0002-7863
SN - 1520-5126
ER -
Cite this
BibTex (up to 50 authors)
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@article{2012_Mailman,
author = {Aaron Mailman and STEPHEN M. WINTER and Xin Yu and Craig M Robertson and Wenjun Yong and JOHN S. TSE and Richard A. Secco and Zhenxian Liu and Paul A. Dube and Judith A. K. Howard and Richard T. Oakley},
title = {Crossing the Insulator-to-Metal Barrier with a Thiazyl Radical Conductor},
journal = {Journal of the American Chemical Society},
year = {2012},
volume = {134},
publisher = {American Chemical Society (ACS)},
month = {jun},
url = {https://doi.org/10.1021/ja303169y},
number = {24},
pages = {9886--9889},
doi = {10.1021/ja303169y}
}
Cite this
MLA
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Mailman, Aaron, et al. “Crossing the Insulator-to-Metal Barrier with a Thiazyl Radical Conductor.” Journal of the American Chemical Society, vol. 134, no. 24, Jun. 2012, pp. 9886-9889. https://doi.org/10.1021/ja303169y.