Journal of the American Chemical Society, volume 134, issue 24, pages 9946-9949

Tungsten-Catalyzed Heterocycloisomerization Approach to 4,5-Dihydro-benzo[b]furans and -indoles

Publication typeJournal Article
Publication date2012-06-06
Quartile SCImago
Q1
Quartile WOS
Q1
Impact factor15
ISSN00027863, 15205126
General Chemistry
Catalysis
Biochemistry
Colloid and Surface Chemistry
Abstract
A W(CO)(5)·THF-catalyzed cycloisomerization of bicyclo[4.1.0] substrates to afford mono C4-substituted 4,5-dihydro-benzo[b]furans and -indoles is reported. The title compounds are versatile intermediates that lead to a range of fused bicycles including the cores of various furan-, benzofuran-, and indole-containing natural products. In many cases, the functionalization of the dihydro-benzo[b]furans and -indoles is orthogonal to that of the corresponding benzofurans and indoles and, thus, offers complementary approaches for synthesis.

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GOST |
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GOST Copy
Fisher E. L., Wilkerson Hill S. M., Sarpong R. Tungsten-Catalyzed Heterocycloisomerization Approach to 4,5-Dihydro-benzo[b]furans and -indoles // Journal of the American Chemical Society. 2012. Vol. 134. No. 24. pp. 9946-9949.
GOST all authors (up to 50) Copy
Fisher E. L., Wilkerson Hill S. M., Sarpong R. Tungsten-Catalyzed Heterocycloisomerization Approach to 4,5-Dihydro-benzo[b]furans and -indoles // Journal of the American Chemical Society. 2012. Vol. 134. No. 24. pp. 9946-9949.
RIS |
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RIS Copy
TY - JOUR
DO - 10.1021/ja3045647
UR - https://doi.org/10.1021/ja3045647
TI - Tungsten-Catalyzed Heterocycloisomerization Approach to 4,5-Dihydro-benzo[b]furans and -indoles
T2 - Journal of the American Chemical Society
AU - Fisher, Ethan L
AU - Wilkerson Hill, Sidney M
AU - Sarpong, Richmond
PY - 2012
DA - 2012/06/06 00:00:00
PB - American Chemical Society (ACS)
SP - 9946-9949
IS - 24
VL - 134
SN - 0002-7863
SN - 1520-5126
ER -
BibTex |
Cite this
BibTex Copy
@article{2012_Fisher,
author = {Ethan L Fisher and Sidney M Wilkerson Hill and Richmond Sarpong},
title = {Tungsten-Catalyzed Heterocycloisomerization Approach to 4,5-Dihydro-benzo[b]furans and -indoles},
journal = {Journal of the American Chemical Society},
year = {2012},
volume = {134},
publisher = {American Chemical Society (ACS)},
month = {jun},
url = {https://doi.org/10.1021/ja3045647},
number = {24},
pages = {9946--9949},
doi = {10.1021/ja3045647}
}
MLA
Cite this
MLA Copy
Fisher, Ethan L., et al. “Tungsten-Catalyzed Heterocycloisomerization Approach to 4,5-Dihydro-benzo[b]furans and -indoles.” Journal of the American Chemical Society, vol. 134, no. 24, Jun. 2012, pp. 9946-9949. https://doi.org/10.1021/ja3045647.
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