Journal of the American Chemical Society, volume 134, issue 36, pages 15042-15047
Superionic Conductivity in Lithium-Rich Anti-Perovskites
1
Department
of Physics and Astronomy, University of Nevada, Las Vegas, Nevada 89154, United
States
|
Publication type: Journal Article
Publication date: 2012-08-30
Quartile SCImago
Q1
Quartile WOS
Q1
Impact factor: 15
ISSN: 00027863, 15205126
General Chemistry
Catalysis
Biochemistry
Colloid and Surface Chemistry
Abstract
Lithium ion batteries have shown great promise in electrical energy storage with enhanced energy density, power capacity, charge-discharge rates, and cycling lifetimes. However common fluid electrolytes consisting of lithium salts dissolved in solvents are toxic, corrosive, or flammable. Solid electrolytes with superionic conductivity can avoid those shortcomings and work with a metallic lithium anode, thereby allowing much higher energy densities. Here we present a novel class of solid electrolytes with three-dimensional conducting pathways based on lithium-rich anti-perovskites (LiRAP) with ionic conductivity of σ > 10(-3) S/cm at room temperature and activation energy of 0.2-0.3 eV. As temperature approaches the melting point, the ionic conductivity of the anti-perovskites increases to advanced superionic conductivity of σ > 10(-2) S/cm and beyond. The new crystalline materials can be readily manipulated via chemical, electronic, and structural means to boost ionic transport and serve as high-performance solid electrolytes for superionic Li(+) conduction in electrochemistry applications.
Top-30
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5 publications, 1.05%
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Nature Communications
5 publications, 1.05%
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5 publications, 1.05%
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5 publications, 1.05%
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5 publications, 1.05%
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Journal of Energy Storage
5 publications, 1.05%
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10
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20
25
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35
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Citations by publishers
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20
40
60
80
100
120
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Elsevier
102 publications, 21.52%
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Wiley
92 publications, 19.41%
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American Chemical Society (ACS)
90 publications, 18.99%
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Royal Society of Chemistry (RSC)
76 publications, 16.03%
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Springer Nature
33 publications, 6.96%
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American Physical Society (APS)
12 publications, 2.53%
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Multidisciplinary Digital Publishing Institute (MDPI)
10 publications, 2.11%
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The Electrochemical Society
8 publications, 1.69%
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IOP Publishing
8 publications, 1.69%
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American Institute of Physics (AIP)
6 publications, 1.27%
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Frontiers Media S.A.
5 publications, 1.05%
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The Royal Society
2 publications, 0.42%
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ASME
1 publication, 0.21%
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American Vacuum Society
1 publication, 0.21%
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Bentham Science
1 publication, 0.21%
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EDP Sciences
1 publication, 0.21%
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Institution of Engineering and Technology (IET)
1 publication, 0.21%
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International Union of Crystallography (IUCr)
1 publication, 0.21%
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Higher Education Press
1 publication, 0.21%
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World Scientific
1 publication, 0.21%
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University of Science and Technology Beijing
1 publication, 0.21%
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Tsinghua University Press
1 publication, 0.21%
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Cambridge University Press
1 publication, 0.21%
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Materials Research Society
1 publication, 0.21%
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Chinese Academy of Sciences
1 publication, 0.21%
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Chinese Ceramic Society
1 publication, 0.21%
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Japan Society of Applied Physics
1 publication, 0.21%
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Korean Ceramic Society
1 publication, 0.21%
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American Association for the Advancement of Science (AAAS)
1 publication, 0.21%
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20
40
60
80
100
120
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- We do not take into account publications without a DOI.
- Statistics recalculated only for publications connected to researchers, organizations and labs registered on the platform.
- Statistics recalculated weekly.
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Zhao Y., Daemen L. L. Superionic Conductivity in Lithium-Rich Anti-Perovskites // Journal of the American Chemical Society. 2012. Vol. 134. No. 36. pp. 15042-15047.
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Zhao Y., Daemen L. L. Superionic Conductivity in Lithium-Rich Anti-Perovskites // Journal of the American Chemical Society. 2012. Vol. 134. No. 36. pp. 15042-15047.
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RIS
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TY - JOUR
DO - 10.1021/ja305709z
UR - https://doi.org/10.1021/ja305709z
TI - Superionic Conductivity in Lithium-Rich Anti-Perovskites
T2 - Journal of the American Chemical Society
AU - Daemen, Luke L
AU - Zhao, Yusheng
PY - 2012
DA - 2012/08/30 00:00:00
PB - American Chemical Society (ACS)
SP - 15042-15047
IS - 36
VL - 134
SN - 0002-7863
SN - 1520-5126
ER -
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@article{2012_Zhao,
author = {Luke L Daemen and Yusheng Zhao},
title = {Superionic Conductivity in Lithium-Rich Anti-Perovskites},
journal = {Journal of the American Chemical Society},
year = {2012},
volume = {134},
publisher = {American Chemical Society (ACS)},
month = {aug},
url = {https://doi.org/10.1021/ja305709z},
number = {36},
pages = {15042--15047},
doi = {10.1021/ja305709z}
}
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MLA
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Zhao, Yusheng, et al. “Superionic Conductivity in Lithium-Rich Anti-Perovskites.” Journal of the American Chemical Society, vol. 134, no. 36, Aug. 2012, pp. 15042-15047. https://doi.org/10.1021/ja305709z.