Low-Potential Sodium Insertion in a NASICON-Type Structure through the Ti(III)/Ti(II) Redox Couple
1
3
Publication type: Journal Article
Publication date: 2013-03-05
scimago Q1
wos Q1
SJR: 5.554
CiteScore: 22.5
Impact factor: 15.6
ISSN: 00027863, 15205126
PubMed ID:
23421416
General Chemistry
Catalysis
Biochemistry
Colloid and Surface Chemistry
Abstract
We report the direct synthesis of powder Na3Ti2(PO4)3 together with its low-potential electrochemical performance and crystal structure elucidation for the reduced and oxidized phases. First-principles calculations at the density functional theory level have been performed to gain further insight into the electrochemistry of Ti(IV)/Ti(III) and Ti(III)/Ti(II) redox couples in these sodium superionic conductor (NASICON) compounds. Finally, we have validated the concept of full-titanium-based sodium ion cells through the assembly of symmetric cells involving Na3Ti2(PO4)3 as both positive and negative electrode materials operating at an average potential of 1.7 V.
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234
Total citations:
234
Citations from 2025:
14
(5.98%)
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GOST
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Senguttuvan P. et al. Low-Potential Sodium Insertion in a NASICON-Type Structure through the Ti(III)/Ti(II) Redox Couple // Journal of the American Chemical Society. 2013. Vol. 135. No. 10. pp. 3897-3903.
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Senguttuvan P., Rousse G., Arroyo y de Dompablo M. E., Vezin H., Tarascon J., Palacin M. R. Low-Potential Sodium Insertion in a NASICON-Type Structure through the Ti(III)/Ti(II) Redox Couple // Journal of the American Chemical Society. 2013. Vol. 135. No. 10. pp. 3897-3903.
Cite this
RIS
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TY - JOUR
DO - 10.1021/ja311044t
UR - https://doi.org/10.1021/ja311044t
TI - Low-Potential Sodium Insertion in a NASICON-Type Structure through the Ti(III)/Ti(II) Redox Couple
T2 - Journal of the American Chemical Society
AU - Senguttuvan, Premkumar
AU - Rousse, Gwenaelle
AU - Arroyo y de Dompablo, M. E.
AU - Vezin, Hervé
AU - Tarascon, Jean-Marie
AU - Palacin, M. Rosa
PY - 2013
DA - 2013/03/05
PB - American Chemical Society (ACS)
SP - 3897-3903
IS - 10
VL - 135
PMID - 23421416
SN - 0002-7863
SN - 1520-5126
ER -
Cite this
BibTex (up to 50 authors)
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@article{2013_Senguttuvan,
author = {Premkumar Senguttuvan and Gwenaelle Rousse and M. E. Arroyo y de Dompablo and Hervé Vezin and Jean-Marie Tarascon and M. Rosa Palacin},
title = {Low-Potential Sodium Insertion in a NASICON-Type Structure through the Ti(III)/Ti(II) Redox Couple},
journal = {Journal of the American Chemical Society},
year = {2013},
volume = {135},
publisher = {American Chemical Society (ACS)},
month = {mar},
url = {https://doi.org/10.1021/ja311044t},
number = {10},
pages = {3897--3903},
doi = {10.1021/ja311044t}
}
Cite this
MLA
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Senguttuvan, Premkumar, et al. “Low-Potential Sodium Insertion in a NASICON-Type Structure through the Ti(III)/Ti(II) Redox Couple.” Journal of the American Chemical Society, vol. 135, no. 10, Mar. 2013, pp. 3897-3903. https://doi.org/10.1021/ja311044t.