Toward a Silicon Version of Metathesis: From Schrock-Type Titanium Silylidenes to Silatitanacyclobutenes
Vladimir Ya. Lee
1
,
Shinji AOKI
1
,
Taka Yokoyama
1
,
Satoru Horiguchi
1
,
Akira Sekiguchi
1
,
Heinz Gornitzka
2, 3
,
Jingdong Guo
4
,
Shigeru Nagase
4
2
CNRS, Laboratoire de Chimie de Coordination, 205 route de Narbonne, BP
44099, F-31077 Toulouse Cedex 4, France
|
3
Publication type: Journal Article
Publication date: 2013-02-18
scimago Q1
wos Q1
SJR: 5.554
CiteScore: 22.5
Impact factor: 15.6
ISSN: 00027863, 15205126
PubMed ID:
23406539
General Chemistry
Catalysis
Biochemistry
Colloid and Surface Chemistry
Abstract
Olefin metathesis is one of the most important industrial processes for the production of alkenes. In contrast, silicon versions of metathesis are unknown given the lack of available silylene transition-metal complexes suitable for [2 + 2] cycloaddition with unsaturated substrates. Here, we report the synthesis of 18-electron titanium silylene complexes featuring different Lewis base ligands and classified on the basis of structural, computational, and reactivity studies as Schrock-type silylene complexes. Because of the presence of loosely bound Lewis base ligands, such silylene complexes readily undergo reaction with simple unsaturated hydrocarbons, such as alkynes, forming the corresponding [2 + 2] cycloaddition products.
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Total citations:
42
Citations from 2025:
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GOST
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Lee V. Y. et al. Toward a Silicon Version of Metathesis: From Schrock-Type Titanium Silylidenes to Silatitanacyclobutenes // Journal of the American Chemical Society. 2013. Vol. 135. No. 8. pp. 2987-2990.
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Lee V. Y., AOKI S., Yokoyama T., Horiguchi S., Sekiguchi A., Gornitzka H., Guo J., Nagase S. Toward a Silicon Version of Metathesis: From Schrock-Type Titanium Silylidenes to Silatitanacyclobutenes // Journal of the American Chemical Society. 2013. Vol. 135. No. 8. pp. 2987-2990.
Cite this
RIS
Copy
TY - JOUR
DO - 10.1021/ja401072j
UR - https://doi.org/10.1021/ja401072j
TI - Toward a Silicon Version of Metathesis: From Schrock-Type Titanium Silylidenes to Silatitanacyclobutenes
T2 - Journal of the American Chemical Society
AU - Lee, Vladimir Ya.
AU - AOKI, Shinji
AU - Yokoyama, Taka
AU - Horiguchi, Satoru
AU - Sekiguchi, Akira
AU - Gornitzka, Heinz
AU - Guo, Jingdong
AU - Nagase, Shigeru
PY - 2013
DA - 2013/02/18
PB - American Chemical Society (ACS)
SP - 2987-2990
IS - 8
VL - 135
PMID - 23406539
SN - 0002-7863
SN - 1520-5126
ER -
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BibTex (up to 50 authors)
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@article{2013_Lee,
author = {Vladimir Ya. Lee and Shinji AOKI and Taka Yokoyama and Satoru Horiguchi and Akira Sekiguchi and Heinz Gornitzka and Jingdong Guo and Shigeru Nagase},
title = {Toward a Silicon Version of Metathesis: From Schrock-Type Titanium Silylidenes to Silatitanacyclobutenes},
journal = {Journal of the American Chemical Society},
year = {2013},
volume = {135},
publisher = {American Chemical Society (ACS)},
month = {feb},
url = {https://doi.org/10.1021/ja401072j},
number = {8},
pages = {2987--2990},
doi = {10.1021/ja401072j}
}
Cite this
MLA
Copy
Lee, Vladimir Ya., et al. “Toward a Silicon Version of Metathesis: From Schrock-Type Titanium Silylidenes to Silatitanacyclobutenes.” Journal of the American Chemical Society, vol. 135, no. 8, Feb. 2013, pp. 2987-2990. https://doi.org/10.1021/ja401072j.
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