Ruthenium-Catalyzed Intramolecular Hydrocarbamoylation of Allylic Formamides: Convenient Access to Chiral Pyrrolidones
Publication type: Journal Article
Publication date: 2013-04-26
scimago Q1
wos Q1
SJR: 5.554
CiteScore: 22.5
Impact factor: 15.6
ISSN: 00027863, 15205126
PubMed ID:
23597311
General Chemistry
Catalysis
Biochemistry
Colloid and Surface Chemistry
Abstract
An attractive strategy for the synthesis of saturated nitrogen-containing heterocycles is described herein, involving the implementation of ruthenium-catalyzed intramolecular hydrocarbamoylation of olefins. The process proceeds by formal C-H bond cleavage of an allylic formamide followed by construction of a new C-C bond in a reaction that is characterized by complete atom-economy. The method is particularly valuable in conjunction with the numerous efficient strategies available for the preparation of optically active allylic formamides.
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58
Total citations:
58
Citations from 2025:
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(6.9%)
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GOST
Copy
Armanino N., Miller S. Ruthenium-Catalyzed Intramolecular Hydrocarbamoylation of Allylic Formamides: Convenient Access to Chiral Pyrrolidones // Journal of the American Chemical Society. 2013. Vol. 135. No. 18. pp. 6814-6817.
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Armanino N., Miller S. Ruthenium-Catalyzed Intramolecular Hydrocarbamoylation of Allylic Formamides: Convenient Access to Chiral Pyrrolidones // Journal of the American Chemical Society. 2013. Vol. 135. No. 18. pp. 6814-6817.
Cite this
RIS
Copy
TY - JOUR
DO - 10.1021/ja4026787
UR - https://doi.org/10.1021/ja4026787
TI - Ruthenium-Catalyzed Intramolecular Hydrocarbamoylation of Allylic Formamides: Convenient Access to Chiral Pyrrolidones
T2 - Journal of the American Chemical Society
AU - Armanino, Nicolas
AU - Miller, Scott
PY - 2013
DA - 2013/04/26
PB - American Chemical Society (ACS)
SP - 6814-6817
IS - 18
VL - 135
PMID - 23597311
SN - 0002-7863
SN - 1520-5126
ER -
Cite this
BibTex (up to 50 authors)
Copy
@article{2013_Armanino,
author = {Nicolas Armanino and Scott Miller},
title = {Ruthenium-Catalyzed Intramolecular Hydrocarbamoylation of Allylic Formamides: Convenient Access to Chiral Pyrrolidones},
journal = {Journal of the American Chemical Society},
year = {2013},
volume = {135},
publisher = {American Chemical Society (ACS)},
month = {apr},
url = {https://doi.org/10.1021/ja4026787},
number = {18},
pages = {6814--6817},
doi = {10.1021/ja4026787}
}
Cite this
MLA
Copy
Armanino, Nicolas, and Scott Miller. “Ruthenium-Catalyzed Intramolecular Hydrocarbamoylation of Allylic Formamides: Convenient Access to Chiral Pyrrolidones.” Journal of the American Chemical Society, vol. 135, no. 18, Apr. 2013, pp. 6814-6817. https://doi.org/10.1021/ja4026787.