A Ru−η6-Arene Complex as a C-Based Lewis Acid in the Activation of Hydrogen and Hydrogenation Catalysis
Publication type: Journal Article
Publication date: 2013-06-03
scimago Q1
wos Q1
SJR: 5.554
CiteScore: 22.5
Impact factor: 15.6
ISSN: 00027863, 15205126
PubMed ID:
23718884
General Chemistry
Catalysis
Biochemistry
Colloid and Surface Chemistry
Abstract
The PBP ligand (Ph2PC6H4)2BPh was used to prepare ((Ph2PC6H4)2B(Cl)(η(6)-Ph)RuCl (1) and subsequently [((Ph2PC6H4)2B(η(6)-Ph))RuCl][B(C6F5)4] (2). The latter species exhibited Lewis acidity on the η(6)-Ph ring, as reaction with Cy3P gave the donor-acceptor adduct [(Ph2PC6H4)2B(η(5)-C6H5-o-PCy3)RuCl][B(C6F5)4] (3). Steric frustration of this binding was seen with Mes3P, and yet the combination of 2 and Mes3P reacted with H2 to give a 2:1 mixture of 5-o and 5-p, two isomers of [(Ph2PC6H4)2B(η(5)-C6H6)RuCl] (5), along with [Mes3PH][HB(C6F5)3]. Compound 2 behaves as C-based Lewis acid and thus can also be used for catalytic hydrogenation of aldimines at room temperature via a frustrated Lewis pair mechanism.
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Boone M. P., Stephan D. W. A Ru−η6-Arene Complex as a C-Based Lewis Acid in the Activation of Hydrogen and Hydrogenation Catalysis // Journal of the American Chemical Society. 2013. Vol. 135. No. 23. pp. 8508-8511.
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Boone M. P., Stephan D. W. A Ru−η6-Arene Complex as a C-Based Lewis Acid in the Activation of Hydrogen and Hydrogenation Catalysis // Journal of the American Chemical Society. 2013. Vol. 135. No. 23. pp. 8508-8511.
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RIS
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TY - JOUR
DO - 10.1021/ja403912n
UR - https://doi.org/10.1021/ja403912n
TI - A Ru−η6-Arene Complex as a C-Based Lewis Acid in the Activation of Hydrogen and Hydrogenation Catalysis
T2 - Journal of the American Chemical Society
AU - Boone, Michael P
AU - Stephan, Douglas W.
PY - 2013
DA - 2013/06/03
PB - American Chemical Society (ACS)
SP - 8508-8511
IS - 23
VL - 135
PMID - 23718884
SN - 0002-7863
SN - 1520-5126
ER -
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BibTex (up to 50 authors)
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@article{2013_Boone,
author = {Michael P Boone and Douglas W. Stephan},
title = {A Ru−η6-Arene Complex as a C-Based Lewis Acid in the Activation of Hydrogen and Hydrogenation Catalysis},
journal = {Journal of the American Chemical Society},
year = {2013},
volume = {135},
publisher = {American Chemical Society (ACS)},
month = {jun},
url = {https://doi.org/10.1021/ja403912n},
number = {23},
pages = {8508--8511},
doi = {10.1021/ja403912n}
}
Cite this
MLA
Copy
Boone, Michael P., and Douglas W. Stephan. “A Ru−η6-Arene Complex as a C-Based Lewis Acid in the Activation of Hydrogen and Hydrogenation Catalysis.” Journal of the American Chemical Society, vol. 135, no. 23, Jun. 2013, pp. 8508-8511. https://doi.org/10.1021/ja403912n.