Journal of the American Chemical Society, volume 135, issue 40, pages 15071-15076
Control of PbSe Nanorod Aspect Ratio by Limiting Phosphine Hydrolysis
Publication type: Journal Article
Publication date: 2013-09-27
Q1
Q1
SJR: 5.489
CiteScore: 24.4
Impact factor: 14.4
ISSN: 00027863, 15205126
General Chemistry
Catalysis
Biochemistry
Colloid and Surface Chemistry
Abstract
The aspect ratio and yield of PbSe nanorods synthesized by the reaction of Pb-oleate with tris(diethylamino)phosphine selenide are highly sensitive to the presence of water, making it critical to control the amount of water present in the reaction. By carefully drying the reaction precursors and then intentionally adding water back into the reaction, the nanorod aspect ratio can be controlled from 1.1 to 10 and the yield from 1 to 14% by varying the water concentration from 0 to 204 mM. (31)P{(1)H} and (1)H NMR show that water reacts with tris(diethylamino)phosphine to create bis(diethylamido)phosphorous acid. It was determined that bis(diethylamido)phosphorous acid is responsible for the observed aspect ratio and yield changes. Finally, it was found that excess oleic acid in the reaction can also react with tris(diethylamino)phosphine to create bis(diethylamido)phosphorous acid, and upon the removal of both excess oleic acid and water, highly uniform, nonbranching nanorods were formed.
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Boercker J. et al. Control of PbSe Nanorod Aspect Ratio by Limiting Phosphine Hydrolysis // Journal of the American Chemical Society. 2013. Vol. 135. No. 40. pp. 15071-15076.
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Boercker J., Foos E. E., Placencia D., Tischler J. Z. Control of PbSe Nanorod Aspect Ratio by Limiting Phosphine Hydrolysis // Journal of the American Chemical Society. 2013. Vol. 135. No. 40. pp. 15071-15076.
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TY - JOUR
DO - 10.1021/ja404576j
UR - https://doi.org/10.1021/ja404576j
TI - Control of PbSe Nanorod Aspect Ratio by Limiting Phosphine Hydrolysis
T2 - Journal of the American Chemical Society
AU - Boercker, J.E.
AU - Foos, Edward E
AU - Placencia, Diogenes
AU - Tischler, J. Z.
PY - 2013
DA - 2013/09/27
PB - American Chemical Society (ACS)
SP - 15071-15076
IS - 40
VL - 135
SN - 0002-7863
SN - 1520-5126
ER -
Cite this
BibTex (up to 50 authors)
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@article{2013_Boercker,
author = {J.E. Boercker and Edward E Foos and Diogenes Placencia and J. Z. Tischler},
title = {Control of PbSe Nanorod Aspect Ratio by Limiting Phosphine Hydrolysis},
journal = {Journal of the American Chemical Society},
year = {2013},
volume = {135},
publisher = {American Chemical Society (ACS)},
month = {sep},
url = {https://doi.org/10.1021/ja404576j},
number = {40},
pages = {15071--15076},
doi = {10.1021/ja404576j}
}
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MLA
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Boercker, J.E., et al. “Control of PbSe Nanorod Aspect Ratio by Limiting Phosphine Hydrolysis.” Journal of the American Chemical Society, vol. 135, no. 40, Sep. 2013, pp. 15071-15076. https://doi.org/10.1021/ja404576j.