volume 135 issue 42 pages 15674-15677

Photoinduced Solid State Conversion of a Radical σ-Dimer to a π-Radical Pair

Publication typeJournal Article
Publication date2013-10-09
scimago Q1
wos Q1
SJR5.554
CiteScore22.5
Impact factor15.6
ISSN00027863, 15205126
PubMed ID:  24107231
General Chemistry
Catalysis
Biochemistry
Colloid and Surface Chemistry
Abstract
Irradiation in the solid state of the hypervalent 4c-6e S···S-S···S bridged σ-dimer of a bisdithiazolyl radical leads to its photodissociation into a pair of π-radicals. The transformation has been monitored by optical spectroscopy, single crystal X-ray diffraction, and magnetic susceptibility measurements. As a result of the large electronic reorganization involved in the dimer-to-radical interconversion, the photogenerated S = 1/2 radical state is remarkably thermally stable, persisting to 242 K before reverting to the S = 0 dimer.
Found 
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GOST Copy
Phan H. et al. Photoinduced Solid State Conversion of a Radical σ-Dimer to a π-Radical Pair // Journal of the American Chemical Society. 2013. Vol. 135. No. 42. pp. 15674-15677.
GOST all authors (up to 50) Copy
Phan H., Lekin K., Winter S. M., Oakley R., Shatruk M. Photoinduced Solid State Conversion of a Radical σ-Dimer to a π-Radical Pair // Journal of the American Chemical Society. 2013. Vol. 135. No. 42. pp. 15674-15677.
RIS |
Cite this
RIS Copy
TY - JOUR
DO - 10.1021/ja4055806
UR - https://doi.org/10.1021/ja4055806
TI - Photoinduced Solid State Conversion of a Radical σ-Dimer to a π-Radical Pair
T2 - Journal of the American Chemical Society
AU - Phan, Hoa
AU - Lekin, Kristina
AU - Winter, Stephen M
AU - Oakley, Richard
AU - Shatruk, Michael
PY - 2013
DA - 2013/10/09
PB - American Chemical Society (ACS)
SP - 15674-15677
IS - 42
VL - 135
PMID - 24107231
SN - 0002-7863
SN - 1520-5126
ER -
BibTex |
Cite this
BibTex (up to 50 authors) Copy
@article{2013_Phan,
author = {Hoa Phan and Kristina Lekin and Stephen M Winter and Richard Oakley and Michael Shatruk},
title = {Photoinduced Solid State Conversion of a Radical σ-Dimer to a π-Radical Pair},
journal = {Journal of the American Chemical Society},
year = {2013},
volume = {135},
publisher = {American Chemical Society (ACS)},
month = {oct},
url = {https://doi.org/10.1021/ja4055806},
number = {42},
pages = {15674--15677},
doi = {10.1021/ja4055806}
}
MLA
Cite this
MLA Copy
Phan, Hoa, et al. “Photoinduced Solid State Conversion of a Radical σ-Dimer to a π-Radical Pair.” Journal of the American Chemical Society, vol. 135, no. 42, Oct. 2013, pp. 15674-15677. https://doi.org/10.1021/ja4055806.