Journal of the American Chemical Society, volume 136, issue 8, pages 3002-3005
Photocatalytic Hydrodefluorination: Facile Access to Partially Fluorinated Aromatics
1
Department of Chemistry, Oklahoma State University, 107 Physical Science, Stillwater, Oklahoma 74078, United States
|
Publication type: Journal Article
Publication date: 2014-02-18
Quartile SCImago
Q1
Quartile WOS
Q1
Impact factor: 15
ISSN: 00027863, 15205126
General Chemistry
Catalysis
Biochemistry
Colloid and Surface Chemistry
Abstract
Polyfluorinated aromatics are essential to materials science as well as the pharmaceutical and agrochemical industries and yet are often difficult to access. This Communication describes a photocatalytic hydrodefluorination approach which begins with easily accessible perfluoroarenes and selectively reduces the C-F bonds. The method allows facile access to a number of partially fluorinated arenes and takes place with unprecedented catalytic activity using a safe and inexpensive amine as the reductant.
Top-30
Citations by journals
|
2
4
6
8
10
12
14
16
18
|
|
|
Angewandte Chemie
17 publications, 8.99%
|
|
|
Angewandte Chemie - International Edition
17 publications, 8.99%
|
|
|
Journal of the American Chemical Society
11 publications, 5.82%
|
|
|
Chemical Science
10 publications, 5.29%
|
|
|
Journal of Organic Chemistry
10 publications, 5.29%
|
|
|
Organic Letters
9 publications, 4.76%
|
|
|
ACS Catalysis
9 publications, 4.76%
|
|
|
Chemical Communications
7 publications, 3.7%
|
|
|
Chemistry - A European Journal
7 publications, 3.7%
|
|
|
Organometallics
6 publications, 3.17%
|
|
|
Journal of Fluorine Chemistry
5 publications, 2.65%
|
|
|
Advanced Synthesis and Catalysis
5 publications, 2.65%
|
|
|
Dalton Transactions
4 publications, 2.12%
|
|
|
European Journal of Organic Chemistry
3 publications, 1.59%
|
|
|
Organic Chemistry Frontiers
3 publications, 1.59%
|
|
|
Chemical Society Reviews
3 publications, 1.59%
|
|
|
Chinese Journal of Catalysis
2 publications, 1.06%
|
|
|
Molecules
2 publications, 1.06%
|
|
|
Russian Chemical Reviews
2 publications, 1.06%
|
|
|
Tetrahedron Letters
2 publications, 1.06%
|
|
|
Asian Journal of Organic Chemistry
2 publications, 1.06%
|
|
|
MolBank
2 publications, 1.06%
|
|
|
RSC Advances
2 publications, 1.06%
|
|
|
Organic and Biomolecular Chemistry
2 publications, 1.06%
|
|
|
Green Chemistry
2 publications, 1.06%
|
|
|
Topics in Organometallic Chemistry
2 publications, 1.06%
|
|
|
Synlett
2 publications, 1.06%
|
|
|
Organics
1 publication, 0.53%
|
|
|
Yuki Gosei Kagaku Kyokaishi/Journal of Synthetic Organic Chemistry
1 publication, 0.53%
|
|
|
2
4
6
8
10
12
14
16
18
|
Citations by publishers
|
10
20
30
40
50
60
70
|
|
|
Wiley
61 publications, 32.28%
|
|
|
American Chemical Society (ACS)
53 publications, 28.04%
|
|
|
Royal Society of Chemistry (RSC)
38 publications, 20.11%
|
|
|
Elsevier
17 publications, 8.99%
|
|
|
Multidisciplinary Digital Publishing Institute (MDPI)
6 publications, 3.17%
|
|
|
Springer Nature
6 publications, 3.17%
|
|
|
Thieme
3 publications, 1.59%
|
|
|
Autonomous Non-profit Organization Editorial Board of the journal Uspekhi Khimii
2 publications, 1.06%
|
|
|
Society of Synthetic Organic Chemistry
1 publication, 0.53%
|
|
|
The Electrochemical Society of Japan
1 publication, 0.53%
|
|
|
10
20
30
40
50
60
70
|
- We do not take into account publications without a DOI.
- Statistics recalculated only for publications connected to researchers, organizations and labs registered on the platform.
- Statistics recalculated weekly.
{"yearsCitations":{"type":"bar","data":{"show":true,"labels":[2014,2015,2016,2017,2018,2019,2020,2021,2022,2023,2024],"ids":[0,0,0,0,0,0,0,0,0,0,0],"codes":[0,0,0,0,0,0,0,0,0,0,0],"imageUrls":["","","","","","","","","","",""],"datasets":[{"label":"Citations number","data":[8,14,18,22,22,20,16,21,20,17,11],"backgroundColor":["#3B82F6","#3B82F6","#3B82F6","#3B82F6","#3B82F6","#3B82F6","#3B82F6","#3B82F6","#3B82F6","#3B82F6","#3B82F6"],"percentage":["4.23","7.41","9.52","11.64","11.64","10.58","8.47","11.11","10.58","8.99","5.82"],"barThickness":null}]},"options":{"indexAxis":"x","maintainAspectRatio":true,"scales":{"y":{"ticks":{"precision":0,"autoSkip":false,"font":{"family":"Montserrat"},"color":"#000000"},"stacked":false},"x":{"ticks":{"stepSize":1,"precision":0,"font":{"family":"Montserrat"},"color":"#000000"},"stacked":false}},"plugins":{"legend":{"position":"top","labels":{"font":{"family":"Montserrat"},"color":"#000000"}},"title":{"display":true,"text":"Citations per year","font":{"size":24,"family":"Montserrat","weight":600},"color":"#000000"}}}},"journals":{"type":"bar","data":{"show":true,"labels":["Angewandte Chemie","Angewandte Chemie - International Edition","Journal of the American Chemical Society","Chemical Science","Journal of Organic Chemistry","Organic Letters","ACS Catalysis","Chemical Communications","Chemistry - A European Journal","Organometallics","Journal of Fluorine Chemistry","Advanced Synthesis and Catalysis","Dalton Transactions","European Journal of Organic Chemistry","Organic Chemistry Frontiers","Chemical Society Reviews","Chinese Journal of Catalysis","Molecules","Russian Chemical Reviews","Tetrahedron Letters","Asian Journal of Organic Chemistry","MolBank","RSC Advances","Organic and Biomolecular Chemistry","Green Chemistry","Topics in Organometallic Chemistry","Synlett","Organics","Yuki Gosei Kagaku Kyokaishi\/Journal of Synthetic Organic Chemistry"],"ids":[25450,19215,4813,9646,8697,3315,4873,9073,24708,1409,14755,3906,8473,19472,3991,20586,14622,1770,23802,6133,9409,20017,3100,541,1017,23840,10217,26415,3551],"codes":[0,0,0,0,0,0,0,0,0,0,0,0,0,0,0,0,0,0,0,0,0,0,0,0,0,0,0,0,0],"imageUrls":["\/storage\/images\/resized\/bRyGpdm98BkAUYiK1YFNpl5Z7hPu6Gd87gbIeuG3_medium.webp","\/storage\/images\/resized\/bRyGpdm98BkAUYiK1YFNpl5Z7hPu6Gd87gbIeuG3_medium.webp","\/storage\/images\/resized\/iLiQsFqFaSEx6chlGQ5fbAwF6VYU3WWa08hkss0g_medium.webp","\/storage\/images\/resized\/leiAYcRDGTSl5B1eCnwpSGqmDEUEfDPPoYisFGhT_medium.webp","\/storage\/images\/resized\/iLiQsFqFaSEx6chlGQ5fbAwF6VYU3WWa08hkss0g_medium.webp","\/storage\/images\/resized\/iLiQsFqFaSEx6chlGQ5fbAwF6VYU3WWa08hkss0g_medium.webp","\/storage\/images\/resized\/iLiQsFqFaSEx6chlGQ5fbAwF6VYU3WWa08hkss0g_medium.webp","\/storage\/images\/resized\/leiAYcRDGTSl5B1eCnwpSGqmDEUEfDPPoYisFGhT_medium.webp","\/storage\/images\/resized\/bRyGpdm98BkAUYiK1YFNpl5Z7hPu6Gd87gbIeuG3_medium.webp","\/storage\/images\/resized\/iLiQsFqFaSEx6chlGQ5fbAwF6VYU3WWa08hkss0g_medium.webp","\/storage\/images\/resized\/GDnYOu1UpMMfMMRV6Aqle4H0YLLsraeD9IP9qScG_medium.webp","\/storage\/images\/resized\/bRyGpdm98BkAUYiK1YFNpl5Z7hPu6Gd87gbIeuG3_medium.webp","\/storage\/images\/resized\/leiAYcRDGTSl5B1eCnwpSGqmDEUEfDPPoYisFGhT_medium.webp","\/storage\/images\/resized\/bRyGpdm98BkAUYiK1YFNpl5Z7hPu6Gd87gbIeuG3_medium.webp","\/storage\/images\/resized\/leiAYcRDGTSl5B1eCnwpSGqmDEUEfDPPoYisFGhT_medium.webp","\/storage\/images\/resized\/leiAYcRDGTSl5B1eCnwpSGqmDEUEfDPPoYisFGhT_medium.webp","\/storage\/images\/resized\/GDnYOu1UpMMfMMRV6Aqle4H0YLLsraeD9IP9qScG_medium.webp","\/storage\/images\/resized\/MjH1ITP7lMYGxeqUZfkt2BnVLgjkk413jwBV97XX_medium.webp","\/storage\/images\/resized\/9Mus3KG1Tkd7Bwaurt8H3RwWh0CxRlGoO6ng9UK1_medium.webp","\/storage\/images\/resized\/GDnYOu1UpMMfMMRV6Aqle4H0YLLsraeD9IP9qScG_medium.webp","\/storage\/images\/resized\/bRyGpdm98BkAUYiK1YFNpl5Z7hPu6Gd87gbIeuG3_medium.webp","\/storage\/images\/resized\/MjH1ITP7lMYGxeqUZfkt2BnVLgjkk413jwBV97XX_medium.webp","\/storage\/images\/resized\/leiAYcRDGTSl5B1eCnwpSGqmDEUEfDPPoYisFGhT_medium.webp","\/storage\/images\/resized\/leiAYcRDGTSl5B1eCnwpSGqmDEUEfDPPoYisFGhT_medium.webp","\/storage\/images\/resized\/leiAYcRDGTSl5B1eCnwpSGqmDEUEfDPPoYisFGhT_medium.webp","\/storage\/images\/resized\/voXLqlsvTwv5p3iMQ8Dhs95nqB4AXOG7Taj7G4ra_medium.webp","\/storage\/images\/resized\/xqixcltwJYe6H8Uco2JbAFfIOzt7UNKH0OcPOPzO_medium.webp","\/storage\/images\/resized\/MjH1ITP7lMYGxeqUZfkt2BnVLgjkk413jwBV97XX_medium.webp","\/storage\/images\/resized\/QzzkQMUwda0fYU3txrAv3z24JfXJEjptEQpWMERc_medium.webp"],"datasets":[{"label":"","data":[17,17,11,10,10,9,9,7,7,6,5,5,4,3,3,3,2,2,2,2,2,2,2,2,2,2,2,1,1],"backgroundColor":["#3B82F6","#3B82F6","#3B82F6","#3B82F6","#3B82F6","#3B82F6","#3B82F6","#3B82F6","#3B82F6","#3B82F6","#3B82F6","#3B82F6","#3B82F6","#3B82F6","#3B82F6","#3B82F6","#3B82F6","#3B82F6","#3B82F6","#3B82F6","#3B82F6","#3B82F6","#3B82F6","#3B82F6","#3B82F6","#3B82F6","#3B82F6","#3B82F6","#3B82F6"],"percentage":[8.99,8.99,5.82,5.29,5.29,4.76,4.76,3.7,3.7,3.17,2.65,2.65,2.12,1.59,1.59,1.59,1.06,1.06,1.06,1.06,1.06,1.06,1.06,1.06,1.06,1.06,1.06,0.53,0.53],"barThickness":13}]},"options":{"indexAxis":"y","maintainAspectRatio":false,"scales":{"y":{"ticks":{"precision":0,"autoSkip":false,"font":{"family":"Montserrat"},"color":"#000000"},"stacked":false},"x":{"ticks":{"stepSize":null,"precision":0,"font":{"family":"Montserrat"},"color":"#000000"},"stacked":false}},"plugins":{"legend":{"position":"top","labels":{"font":{"family":"Montserrat"},"color":"#000000"}},"title":{"display":true,"text":"Journals","font":{"size":24,"family":"Montserrat","weight":600},"color":"#000000"}}}},"publishers":{"type":"bar","data":{"show":true,"labels":["Wiley","American Chemical Society (ACS)","Royal Society of Chemistry (RSC)","Elsevier","Multidisciplinary Digital Publishing Institute (MDPI)","Springer Nature","Thieme","Autonomous Non-profit Organization Editorial Board of the journal Uspekhi Khimii","Society of Synthetic Organic Chemistry","The Electrochemical Society of Japan"],"ids":[11,40,123,17,202,8,135,9422,1303,7035],"codes":[0,0,0,0,0,0,0,0,0,0],"imageUrls":["\/storage\/images\/resized\/bRyGpdm98BkAUYiK1YFNpl5Z7hPu6Gd87gbIeuG3_medium.webp","\/storage\/images\/resized\/iLiQsFqFaSEx6chlGQ5fbAwF6VYU3WWa08hkss0g_medium.webp","\/storage\/images\/resized\/leiAYcRDGTSl5B1eCnwpSGqmDEUEfDPPoYisFGhT_medium.webp","\/storage\/images\/resized\/GDnYOu1UpMMfMMRV6Aqle4H0YLLsraeD9IP9qScG_medium.webp","\/storage\/images\/resized\/MjH1ITP7lMYGxeqUZfkt2BnVLgjkk413jwBV97XX_medium.webp","\/storage\/images\/resized\/voXLqlsvTwv5p3iMQ8Dhs95nqB4AXOG7Taj7G4ra_medium.webp","\/storage\/images\/resized\/xqixcltwJYe6H8Uco2JbAFfIOzt7UNKH0OcPOPzO_medium.webp","\/storage\/images\/resized\/9Mus3KG1Tkd7Bwaurt8H3RwWh0CxRlGoO6ng9UK1_medium.webp","\/storage\/images\/resized\/QzzkQMUwda0fYU3txrAv3z24JfXJEjptEQpWMERc_medium.webp","\/storage\/images\/resized\/JWkRrt4U4oPa4E6W7adkLpyIMTatGmlu51Ge50zC_medium.webp"],"datasets":[{"label":"","data":[61,53,38,17,6,6,3,2,1,1],"backgroundColor":["#3B82F6","#3B82F6","#3B82F6","#3B82F6","#3B82F6","#3B82F6","#3B82F6","#3B82F6","#3B82F6","#3B82F6"],"percentage":[32.28,28.04,20.11,8.99,3.17,3.17,1.59,1.06,0.53,0.53],"barThickness":13}]},"options":{"indexAxis":"y","maintainAspectRatio":false,"scales":{"y":{"ticks":{"precision":0,"autoSkip":false,"font":{"family":"Montserrat"},"color":"#000000"},"stacked":false},"x":{"ticks":{"stepSize":null,"precision":0,"font":{"family":"Montserrat"},"color":"#000000"},"stacked":false}},"plugins":{"legend":{"position":"top","labels":{"font":{"family":"Montserrat"},"color":"#000000"}},"title":{"display":true,"text":"Publishers","font":{"size":24,"family":"Montserrat","weight":600},"color":"#000000"}}}},"yearsCitationsQuartiles":{"type":"bar","data":{"show":true,"labels":[2014,2015,2016,2017,2018,2019,2020,2021,2022,2023,2024],"ids":[],"codes":[],"imageUrls":[],"datasets":[{"label":"Q4","backgroundColor":"rgb(221,90,78)","data":[0,0,0,0,1,0,0,0,0,3,0],"percentage":["0","0","0","0","0.53","0","0","0","0","1.59","0"]},{"label":"Q3","backgroundColor":"rgb(251, 163,83)","data":[0,2,1,0,0,2,0,2,0,0,1],"percentage":["0","1.06","0.53","0","0","1.06","0","1.06","0","0","0.53"]},{"label":"Q2","backgroundColor":"rgb(232, 213, 89)","data":[2,3,0,4,1,4,0,1,0,1,0],"percentage":["1.06","1.59","0","2.12","0.53","2.12","0","0.53","0","0.53","0"]},{"label":"Q1","backgroundColor":"rgb(164, 207, 99)","data":[5,7,16,18,19,12,16,18,18,13,10],"percentage":["2.65","3.7","8.47","9.52","10.05","6.35","8.47","9.52","9.52","6.88","5.29"]},{"label":"Quartile not defined","backgroundColor":"#E5E7EB","data":[1,2,1,0,1,2,0,0,2,0,0],"percentage":["0.53","1.06","0.53","0","0.53","1.06","0","0","1.06","0","0"]}]},"options":{"indexAxis":"x","maintainAspectRatio":true,"scales":{"y":{"ticks":{"precision":0,"autoSkip":false,"font":{"family":"Montserrat"},"color":"#000000"},"stacked":true},"x":{"ticks":{"stepSize":1,"precision":0,"font":{"family":"Montserrat"},"color":"#000000"},"stacked":true}},"plugins":{"legend":{"position":"top","labels":{"font":{"family":"Montserrat"},"color":"#000000"}},"title":{"display":true,"text":"Citations quartiles by SCImago per year","font":{"size":24,"family":"Montserrat","weight":600},"color":"#000000"}}}},"yearsCitationsQuartilesWs":{"type":"bar","data":{"show":true,"labels":[2014,2015,2016,2017,2018,2019,2020,2021,2022,2023,2024],"ids":[],"codes":[],"imageUrls":[],"datasets":[{"label":"Q4","backgroundColor":"rgb(221,90,78)","data":[0,0,0,0,1,0,0,0,0,1,0],"percentage":["0","0","0","0","0.53","0","0","0","0","0.53","0"]},{"label":"Q3","backgroundColor":"rgb(251, 163,83)","data":[2,3,1,1,0,2,0,2,0,0,1],"percentage":["1.06","1.59","0.53","0.53","0","1.06","0","1.06","0","0","0.53"]},{"label":"Q2","backgroundColor":"rgb(232, 213, 89)","data":[3,4,0,6,8,5,2,5,4,3,1],"percentage":["1.59","2.12","0","3.17","4.23","2.65","1.06","2.65","2.12","1.59","0.53"]},{"label":"Q1","backgroundColor":"rgb(164, 207, 99)","data":[2,5,14,10,11,10,12,12,12,9,8],"percentage":["1.06","2.65","7.41","5.29","5.82","5.29","6.35","6.35","6.35","4.76","4.23"]},{"label":"Quartile not defined","backgroundColor":"#E5E7EB","data":[1,2,3,5,2,3,2,2,4,4,1],"percentage":["0.53","1.06","1.59","2.65","1.06","1.59","1.06","1.06","2.12","2.12","0.53"]}]},"options":{"indexAxis":"x","maintainAspectRatio":true,"scales":{"y":{"ticks":{"precision":0,"autoSkip":false,"font":{"family":"Montserrat"},"color":"#000000"},"stacked":true},"x":{"ticks":{"stepSize":1,"precision":0,"font":{"family":"Montserrat"},"color":"#000000"},"stacked":true}},"plugins":{"legend":{"position":"top","labels":{"font":{"family":"Montserrat"},"color":"#000000"}},"title":{"display":true,"text":"Citations quartiles by WoS per year","font":{"size":24,"family":"Montserrat","weight":600},"color":"#000000"}}}}}
Are you a researcher?
Create a profile to get free access to personal recommendations for colleagues and new articles.
Metrics
Cite this
GOST |
RIS |
BibTex |
MLA
Cite this
GOST
Copy
Senaweera S. M., Singh A., Weaver J. D. Photocatalytic Hydrodefluorination: Facile Access to Partially Fluorinated Aromatics // Journal of the American Chemical Society. 2014. Vol. 136. No. 8. pp. 3002-3005.
GOST all authors (up to 50)
Copy
Senaweera S. M., Singh A., Weaver J. D. Photocatalytic Hydrodefluorination: Facile Access to Partially Fluorinated Aromatics // Journal of the American Chemical Society. 2014. Vol. 136. No. 8. pp. 3002-3005.
Cite this
RIS
Copy
TY - JOUR
DO - 10.1021/ja500031m
UR - https://doi.org/10.1021/ja500031m
TI - Photocatalytic Hydrodefluorination: Facile Access to Partially Fluorinated Aromatics
T2 - Journal of the American Chemical Society
AU - Senaweera, Sameera M
AU - Singh, Anuradha
AU - Weaver, Jimmie D
PY - 2014
DA - 2014/02/18 00:00:00
PB - American Chemical Society (ACS)
SP - 3002-3005
IS - 8
VL - 136
SN - 0002-7863
SN - 1520-5126
ER -
Cite this
BibTex
Copy
@article{2014_Senaweera,
author = {Sameera M Senaweera and Anuradha Singh and Jimmie D Weaver},
title = {Photocatalytic Hydrodefluorination: Facile Access to Partially Fluorinated Aromatics},
journal = {Journal of the American Chemical Society},
year = {2014},
volume = {136},
publisher = {American Chemical Society (ACS)},
month = {feb},
url = {https://doi.org/10.1021/ja500031m},
number = {8},
pages = {3002--3005},
doi = {10.1021/ja500031m}
}
Cite this
MLA
Copy
Senaweera, Sameera M., et al. “Photocatalytic Hydrodefluorination: Facile Access to Partially Fluorinated Aromatics.” Journal of the American Chemical Society, vol. 136, no. 8, Feb. 2014, pp. 3002-3005. https://doi.org/10.1021/ja500031m.