Journal of the American Chemical Society, volume 136, issue 8, pages 3002-3005
Photocatalytic Hydrodefluorination: Facile Access to Partially Fluorinated Aromatics
1
Department of Chemistry, Oklahoma State University, 107 Physical Science, Stillwater, Oklahoma 74078, United States
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Publication type: Journal Article
Publication date: 2014-02-18
Quartile SCImago
Q1
Quartile WOS
Q1
SJR: 5.489
CiteScore: 24.4
Impact factor: 14.4
ISSN: 00027863, 15205126
General Chemistry
Catalysis
Biochemistry
Colloid and Surface Chemistry
Abstract
Polyfluorinated aromatics are essential to materials science as well as the pharmaceutical and agrochemical industries and yet are often difficult to access. This Communication describes a photocatalytic hydrodefluorination approach which begins with easily accessible perfluoroarenes and selectively reduces the C-F bonds. The method allows facile access to a number of partially fluorinated arenes and takes place with unprecedented catalytic activity using a safe and inexpensive amine as the reductant.
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GOST
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Senaweera S. M., Singh A., Weaver J. D. Photocatalytic Hydrodefluorination: Facile Access to Partially Fluorinated Aromatics // Journal of the American Chemical Society. 2014. Vol. 136. No. 8. pp. 3002-3005.
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Senaweera S. M., Singh A., Weaver J. D. Photocatalytic Hydrodefluorination: Facile Access to Partially Fluorinated Aromatics // Journal of the American Chemical Society. 2014. Vol. 136. No. 8. pp. 3002-3005.
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TY - JOUR
DO - 10.1021/ja500031m
UR - https://doi.org/10.1021/ja500031m
TI - Photocatalytic Hydrodefluorination: Facile Access to Partially Fluorinated Aromatics
T2 - Journal of the American Chemical Society
AU - Senaweera, Sameera M
AU - Singh, Anuradha
AU - Weaver, Jimmie D
PY - 2014
DA - 2014/02/18
PB - American Chemical Society (ACS)
SP - 3002-3005
IS - 8
VL - 136
SN - 0002-7863
SN - 1520-5126
ER -
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BibTex
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@article{2014_Senaweera,
author = {Sameera M Senaweera and Anuradha Singh and Jimmie D Weaver},
title = {Photocatalytic Hydrodefluorination: Facile Access to Partially Fluorinated Aromatics},
journal = {Journal of the American Chemical Society},
year = {2014},
volume = {136},
publisher = {American Chemical Society (ACS)},
month = {feb},
url = {https://doi.org/10.1021/ja500031m},
number = {8},
pages = {3002--3005},
doi = {10.1021/ja500031m}
}
Cite this
MLA
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Senaweera, Sameera M., et al. “Photocatalytic Hydrodefluorination: Facile Access to Partially Fluorinated Aromatics.” Journal of the American Chemical Society, vol. 136, no. 8, Feb. 2014, pp. 3002-3005. https://doi.org/10.1021/ja500031m.