Highly Regio- and Enantioselective Synthesis of Polysubstituted 2H-Pyrroles via Pd-Catalyzed Intermolecular Asymmetric Allylic Dearomatization of Pyrroles
Publication type: Journal Article
Publication date: 2014-04-28
scimago Q1
wos Q1
SJR: 5.554
CiteScore: 22.5
Impact factor: 15.6
ISSN: 00027863, 15205126
PubMed ID:
24758260
General Chemistry
Catalysis
Biochemistry
Colloid and Surface Chemistry
Abstract
A highly efficient synthesis of chiral polysubstituted 2H-pyrrole derivatives via a Pd-catalyzed intermolecular asymmetric allylic dearomatization reaction of pyrroles is presented. With the commercially available palladium precursor and chiral ligand, the polysubstituted 2H-pyrrole products containing a chiral quaternary carbon center were obtained with up to 97% ee and >95/5 regioselectivity.
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Total citations:
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Citations from 2025:
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GOST
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Zhuo C. X., Zhou Y., You S. Highly Regio- and Enantioselective Synthesis of Polysubstituted 2H-Pyrroles via Pd-Catalyzed Intermolecular Asymmetric Allylic Dearomatization of Pyrroles // Journal of the American Chemical Society. 2014. Vol. 136. No. 18. pp. 6590-6593.
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Zhuo C. X., Zhou Y., You S. Highly Regio- and Enantioselective Synthesis of Polysubstituted 2H-Pyrroles via Pd-Catalyzed Intermolecular Asymmetric Allylic Dearomatization of Pyrroles // Journal of the American Chemical Society. 2014. Vol. 136. No. 18. pp. 6590-6593.
Cite this
RIS
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TY - JOUR
DO - 10.1021/ja5028138
UR - https://doi.org/10.1021/ja5028138
TI - Highly Regio- and Enantioselective Synthesis of Polysubstituted 2H-Pyrroles via Pd-Catalyzed Intermolecular Asymmetric Allylic Dearomatization of Pyrroles
T2 - Journal of the American Chemical Society
AU - Zhuo, Chun Xiang
AU - Zhou, Yong
AU - You, Shu-Li
PY - 2014
DA - 2014/04/28
PB - American Chemical Society (ACS)
SP - 6590-6593
IS - 18
VL - 136
PMID - 24758260
SN - 0002-7863
SN - 1520-5126
ER -
Cite this
BibTex (up to 50 authors)
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@article{2014_Zhuo,
author = {Chun Xiang Zhuo and Yong Zhou and Shu-Li You},
title = {Highly Regio- and Enantioselective Synthesis of Polysubstituted 2H-Pyrroles via Pd-Catalyzed Intermolecular Asymmetric Allylic Dearomatization of Pyrroles},
journal = {Journal of the American Chemical Society},
year = {2014},
volume = {136},
publisher = {American Chemical Society (ACS)},
month = {apr},
url = {https://doi.org/10.1021/ja5028138},
number = {18},
pages = {6590--6593},
doi = {10.1021/ja5028138}
}
Cite this
MLA
Copy
Zhuo, Chun Xiang, et al. “Highly Regio- and Enantioselective Synthesis of Polysubstituted 2H-Pyrroles via Pd-Catalyzed Intermolecular Asymmetric Allylic Dearomatization of Pyrroles.” Journal of the American Chemical Society, vol. 136, no. 18, Apr. 2014, pp. 6590-6593. https://doi.org/10.1021/ja5028138.