Oxidative Addition of σ Bonds to an Al(I) Center
Publication type: Journal Article
Publication date: 2014-06-12
scimago Q1
wos Q1
SJR: 5.554
CiteScore: 22.5
Impact factor: 15.6
ISSN: 00027863, 15205126
PubMed ID:
24893309
General Chemistry
Catalysis
Biochemistry
Colloid and Surface Chemistry
Abstract
The Al(I) compound NacNacAl (1, NacNac = [ArNC(Me)CHC(Me)NAr](-) and Ar = 2,6-Pr(i)2C6H3) reacts with H-X (X = H, Si, B, Al, C, N, P, O) σ bonds of H2, silanes, borane (HBpin, pin = pinacolate), allane (NacNacAlH2), phosphine (HPPh2), amines, alcohol (Pr(i)OH), and Cp*H (Cp* = pentamethylcyclopentadiene) to give a series of hydride derivatives of the four-coordinate aluminum NacNacAlH(X), which are characterized herein by spectroscopic methods (NMR and IR) and X-ray diffraction. This method allows for the syntheses of the first boryl hydride of aluminum and novel silyl hydride and phosphido hydride derivatives. In the case of the addition of NacNacAlH2, the reaction is reversible, proving the possibility of reductive elimination from the species NacNacAlH(X).
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207
Total citations:
207
Citations from 2025:
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(11.59%)
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Chu T., Korobkov I., Nikonov G. I. Oxidative Addition of σ Bonds to an Al(I) Center // Journal of the American Chemical Society. 2014. Vol. 136. No. 25. pp. 9195-9202.
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Chu T., Korobkov I., Nikonov G. I. Oxidative Addition of σ Bonds to an Al(I) Center // Journal of the American Chemical Society. 2014. Vol. 136. No. 25. pp. 9195-9202.
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RIS
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TY - JOUR
DO - 10.1021/ja5038337
UR - https://doi.org/10.1021/ja5038337
TI - Oxidative Addition of σ Bonds to an Al(I) Center
T2 - Journal of the American Chemical Society
AU - Chu, Terry
AU - Korobkov, Ilia
AU - Nikonov, G. I.
PY - 2014
DA - 2014/06/12
PB - American Chemical Society (ACS)
SP - 9195-9202
IS - 25
VL - 136
PMID - 24893309
SN - 0002-7863
SN - 1520-5126
ER -
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BibTex (up to 50 authors)
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@article{2014_Chu,
author = {Terry Chu and Ilia Korobkov and G. I. Nikonov},
title = {Oxidative Addition of σ Bonds to an Al(I) Center},
journal = {Journal of the American Chemical Society},
year = {2014},
volume = {136},
publisher = {American Chemical Society (ACS)},
month = {jun},
url = {https://doi.org/10.1021/ja5038337},
number = {25},
pages = {9195--9202},
doi = {10.1021/ja5038337}
}
Cite this
MLA
Copy
Chu, Terry, et al. “Oxidative Addition of σ Bonds to an Al(I) Center.” Journal of the American Chemical Society, vol. 136, no. 25, Jun. 2014, pp. 9195-9202. https://doi.org/10.1021/ja5038337.