Metal-Free Atom Transfer Radical Polymerization
Nicolas J Treat
1
,
Hazel Sprafke
1
,
John W Kramer
2
,
Paul G. Clark
2
,
Bryan E Barton
2
,
J Read De Alaniz
3
,
Brett P. Fors
4
,
C. J. Hawker
1, 3
2
The Dow Chemical Company, Midland, Michigan 48674, United States
|
Publication type: Journal Article
Publication date: 2014-10-31
scimago Q1
wos Q1
SJR: 5.554
CiteScore: 22.5
Impact factor: 15.6
ISSN: 00027863, 15205126
PubMed ID:
25360628
General Chemistry
Catalysis
Biochemistry
Colloid and Surface Chemistry
Abstract
Overcoming the challenge of metal contamination in traditional ATRP systems, a metal-free ATRP process, mediated by light and catalyzed by an organic-based photoredox catalyst, is reported. Polymerization of vinyl monomers are efficiently activated and deactivated with light leading to excellent control over the molecular weight, polydispersity, and chain ends of the resulting polymers. Significantly, block copolymer formation was facile and could be combined with other controlled radical processes leading to structural and synthetic versatility. We believe that these new organic-based photoredox catalysts will enable new applications for controlled radical polymerizations and also be of further value in both small molecule and polymer chemistry.
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Total citations:
866
Citations from 2024:
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GOST
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Treat N. J. et al. Metal-Free Atom Transfer Radical Polymerization // Journal of the American Chemical Society. 2014. Vol. 136. No. 45. pp. 16096-16101.
GOST all authors (up to 50)
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Treat N. J., Sprafke H., Kramer J. W., Clark P. G., Barton B. E., Read De Alaniz J., Fors B. P., Hawker C. J. Metal-Free Atom Transfer Radical Polymerization // Journal of the American Chemical Society. 2014. Vol. 136. No. 45. pp. 16096-16101.
Cite this
RIS
Copy
TY - JOUR
DO - 10.1021/ja510389m
UR - https://doi.org/10.1021/ja510389m
TI - Metal-Free Atom Transfer Radical Polymerization
T2 - Journal of the American Chemical Society
AU - Treat, Nicolas J
AU - Sprafke, Hazel
AU - Kramer, John W
AU - Clark, Paul G.
AU - Barton, Bryan E
AU - Read De Alaniz, J
AU - Fors, Brett P.
AU - Hawker, C. J.
PY - 2014
DA - 2014/10/31
PB - American Chemical Society (ACS)
SP - 16096-16101
IS - 45
VL - 136
PMID - 25360628
SN - 0002-7863
SN - 1520-5126
ER -
Cite this
BibTex (up to 50 authors)
Copy
@article{2014_Treat,
author = {Nicolas J Treat and Hazel Sprafke and John W Kramer and Paul G. Clark and Bryan E Barton and J Read De Alaniz and Brett P. Fors and C. J. Hawker},
title = {Metal-Free Atom Transfer Radical Polymerization},
journal = {Journal of the American Chemical Society},
year = {2014},
volume = {136},
publisher = {American Chemical Society (ACS)},
month = {oct},
url = {https://doi.org/10.1021/ja510389m},
number = {45},
pages = {16096--16101},
doi = {10.1021/ja510389m}
}
Cite this
MLA
Copy
Treat, Nicolas J., et al. “Metal-Free Atom Transfer Radical Polymerization.” Journal of the American Chemical Society, vol. 136, no. 45, Oct. 2014, pp. 16096-16101. https://doi.org/10.1021/ja510389m.