Journal of the American Chemical Society, volume 137, issue 1, pages 42-45
Copper- and cobalt-catalyzed direct coupling of sp(3) α-carbon of alcohols with alkenes and hydroperoxides.
Publication type: Journal Article
Publication date: 2014-12-31
Q1
Q1
SJR: 5.489
CiteScore: 24.4
Impact factor: 14.4
ISSN: 00027863, 15205126
General Chemistry
Catalysis
Biochemistry
Colloid and Surface Chemistry
Abstract
A zerovalent copper- and cobalt-catalyzed direct coupling of the sp(3) α-carbon of alcohols with alkenes and hydroperoxides was developed in which the hydroperoxides acted as radical initiator and then coupling partner. 1,3-Enynes and vinylarenes underwent alkylation-peroxidation to give β-peroxy alcohols and β-hydroxyketones correspondingly with excellent functional group tolerance. The resulting β-peroxy alcohols could be further transformed into β-hydroxyynones and propargylic 1,3-diols.
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Cheng J. K., Xie P. Copper- and cobalt-catalyzed direct coupling of sp(3) α-carbon of alcohols with alkenes and hydroperoxides. // Journal of the American Chemical Society. 2014. Vol. 137. No. 1. pp. 42-45.
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Cheng J. K., Xie P. Copper- and cobalt-catalyzed direct coupling of sp(3) α-carbon of alcohols with alkenes and hydroperoxides. // Journal of the American Chemical Society. 2014. Vol. 137. No. 1. pp. 42-45.
Cite this
RIS
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TY - JOUR
DO - 10.1021/ja510635k
UR - https://doi.org/10.1021/ja510635k
TI - Copper- and cobalt-catalyzed direct coupling of sp(3) α-carbon of alcohols with alkenes and hydroperoxides.
T2 - Journal of the American Chemical Society
AU - Cheng, Jun Kee
AU - Xie, Peizhong
PY - 2014
DA - 2014/12/31
PB - American Chemical Society (ACS)
SP - 42-45
IS - 1
VL - 137
SN - 0002-7863
SN - 1520-5126
ER -
Cite this
BibTex (up to 50 authors)
Copy
@article{2014_Cheng,
author = {Jun Kee Cheng and Peizhong Xie},
title = {Copper- and cobalt-catalyzed direct coupling of sp(3) α-carbon of alcohols with alkenes and hydroperoxides.},
journal = {Journal of the American Chemical Society},
year = {2014},
volume = {137},
publisher = {American Chemical Society (ACS)},
month = {dec},
url = {https://doi.org/10.1021/ja510635k},
number = {1},
pages = {42--45},
doi = {10.1021/ja510635k}
}
Cite this
MLA
Copy
Cheng, Jun Kee, et al. “Copper- and cobalt-catalyzed direct coupling of sp(3) α-carbon of alcohols with alkenes and hydroperoxides..” Journal of the American Chemical Society, vol. 137, no. 1, Dec. 2014, pp. 42-45. https://doi.org/10.1021/ja510635k.