volume 137 issue 1 pages 42-45

Copper- and cobalt-catalyzed direct coupling of sp(3) α-carbon of alcohols with alkenes and hydroperoxides.

Publication typeJournal Article
Publication date2014-12-31
scimago Q1
wos Q1
SJR5.554
CiteScore22.5
Impact factor15.6
ISSN00027863, 15205126
PubMed ID:  25541811
General Chemistry
Catalysis
Biochemistry
Colloid and Surface Chemistry
Abstract
A zerovalent copper- and cobalt-catalyzed direct coupling of the sp(3) α-carbon of alcohols with alkenes and hydroperoxides was developed in which the hydroperoxides acted as radical initiator and then coupling partner. 1,3-Enynes and vinylarenes underwent alkylation-peroxidation to give β-peroxy alcohols and β-hydroxyketones correspondingly with excellent functional group tolerance. The resulting β-peroxy alcohols could be further transformed into β-hydroxyynones and propargylic 1,3-diols.
Found 
Found 

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GOST Copy
Cheng J. K., Xie P. Copper- and cobalt-catalyzed direct coupling of sp(3) α-carbon of alcohols with alkenes and hydroperoxides. // Journal of the American Chemical Society. 2014. Vol. 137. No. 1. pp. 42-45.
GOST all authors (up to 50) Copy
Cheng J. K., Xie P. Copper- and cobalt-catalyzed direct coupling of sp(3) α-carbon of alcohols with alkenes and hydroperoxides. // Journal of the American Chemical Society. 2014. Vol. 137. No. 1. pp. 42-45.
RIS |
Cite this
RIS Copy
TY - JOUR
DO - 10.1021/ja510635k
UR - https://doi.org/10.1021/ja510635k
TI - Copper- and cobalt-catalyzed direct coupling of sp(3) α-carbon of alcohols with alkenes and hydroperoxides.
T2 - Journal of the American Chemical Society
AU - Cheng, Jun Kee
AU - Xie, Peizhong
PY - 2014
DA - 2014/12/31
PB - American Chemical Society (ACS)
SP - 42-45
IS - 1
VL - 137
PMID - 25541811
SN - 0002-7863
SN - 1520-5126
ER -
BibTex |
Cite this
BibTex (up to 50 authors) Copy
@article{2014_Cheng,
author = {Jun Kee Cheng and Peizhong Xie},
title = {Copper- and cobalt-catalyzed direct coupling of sp(3) α-carbon of alcohols with alkenes and hydroperoxides.},
journal = {Journal of the American Chemical Society},
year = {2014},
volume = {137},
publisher = {American Chemical Society (ACS)},
month = {dec},
url = {https://doi.org/10.1021/ja510635k},
number = {1},
pages = {42--45},
doi = {10.1021/ja510635k}
}
MLA
Cite this
MLA Copy
Cheng, Jun Kee, et al. “Copper- and cobalt-catalyzed direct coupling of sp(3) α-carbon of alcohols with alkenes and hydroperoxides..” Journal of the American Chemical Society, vol. 137, no. 1, Dec. 2014, pp. 42-45. https://doi.org/10.1021/ja510635k.