Journal of the American Chemical Society, volume 137, issue 3, pages 1028-1031
Tandem Amine and Ruthenium-Catalyzed Hydrogenation of CO2 to Methanol
Publication type: Journal Article
Publication date: 2015-01-16
Quartile SCImago
Q1
Quartile WOS
Q1
Impact factor: 15
ISSN: 00027863, 15205126
General Chemistry
Catalysis
Biochemistry
Colloid and Surface Chemistry
Abstract
This Communication describes the hydrogenation of carbon dioxide to methanol via tandem catalysis with dimethylamine and a homogeneous ruthenium complex. Unlike previous examples with homogeneous catalysts, this CO2-to-CH3OH process proceeds under basic reaction conditions. The dimethylamine is proposed to play a dual role in this system. It reacts directly with CO2 to produce dimethylammonium dimethylcarbamate, and it also intercepts the intermediate formic acid to generate dimethylformamide. With the appropriate selection of catalyst and reaction conditions, >95% conversion of CO2 was achieved to form a mixture of CH3OH and dimethylformamide.
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Rezayee N. M., Huff C. A., Sanford M. Tandem Amine and Ruthenium-Catalyzed Hydrogenation of CO2 to Methanol // Journal of the American Chemical Society. 2015. Vol. 137. No. 3. pp. 1028-1031.
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Rezayee N. M., Huff C. A., Sanford M. Tandem Amine and Ruthenium-Catalyzed Hydrogenation of CO2 to Methanol // Journal of the American Chemical Society. 2015. Vol. 137. No. 3. pp. 1028-1031.
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TY - JOUR
DO - 10.1021/ja511329m
UR - https://doi.org/10.1021/ja511329m
TI - Tandem Amine and Ruthenium-Catalyzed Hydrogenation of CO2 to Methanol
T2 - Journal of the American Chemical Society
AU - Rezayee, Nomaan M
AU - Huff, Chelsea A
AU - Sanford, Melanie
PY - 2015
DA - 2015/01/16
PB - American Chemical Society (ACS)
SP - 1028-1031
IS - 3
VL - 137
SN - 0002-7863
SN - 1520-5126
ER -
Cite this
BibTex
Copy
@article{2015_Rezayee,
author = {Nomaan M Rezayee and Chelsea A Huff and Melanie Sanford},
title = {Tandem Amine and Ruthenium-Catalyzed Hydrogenation of CO2 to Methanol},
journal = {Journal of the American Chemical Society},
year = {2015},
volume = {137},
publisher = {American Chemical Society (ACS)},
month = {jan},
url = {https://doi.org/10.1021/ja511329m},
number = {3},
pages = {1028--1031},
doi = {10.1021/ja511329m}
}
Cite this
MLA
Copy
Rezayee, Nomaan M., et al. “Tandem Amine and Ruthenium-Catalyzed Hydrogenation of CO2 to Methanol.” Journal of the American Chemical Society, vol. 137, no. 3, Jan. 2015, pp. 1028-1031. https://doi.org/10.1021/ja511329m.