Structure-Assisted Functional Anchor Implantation in Robust Metal–Organic Frameworks with Ultralarge Pores
Publication type: Journal Article
Publication date: 2015-01-21
scimago Q1
wos Q1
SJR: 5.554
CiteScore: 22.5
Impact factor: 15.6
ISSN: 00027863, 15205126
PubMed ID:
25581395
General Chemistry
Catalysis
Biochemistry
Colloid and Surface Chemistry
Abstract
A facile functionalization assisted by the structural attributes of PCN-333 has been studied while maintaining the integrity of the parent MOF including ultralarge pores, chemical robustness, and crystallinity. Herein we thoroughly analyzed ligand exchange phenomena in PCN-333 and demonstrate that the extent of exchange can be tailored by varying the exchange conditions as potential applications may require. Through this method a variety of functional groups are incorporated into PCN-333. To further show the capabilities of this system introduction of a BODIPY fluorophore as a secondary functionality was performed to the functionalized framework via a click reaction. We anticipate the PCN-333 with functional anchor can serve as a stable platform for further chemistry to be explored in future applications.
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79
Total citations:
79
Citations from 2024:
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(20.25%)
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GOST
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Park J., Feng D., Zhou H. Structure-Assisted Functional Anchor Implantation in Robust Metal–Organic Frameworks with Ultralarge Pores // Journal of the American Chemical Society. 2015. Vol. 137. No. 4. pp. 1663-1672.
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Park J., Feng D., Zhou H. Structure-Assisted Functional Anchor Implantation in Robust Metal–Organic Frameworks with Ultralarge Pores // Journal of the American Chemical Society. 2015. Vol. 137. No. 4. pp. 1663-1672.
Cite this
RIS
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TY - JOUR
DO - 10.1021/ja5123528
UR - https://doi.org/10.1021/ja5123528
TI - Structure-Assisted Functional Anchor Implantation in Robust Metal–Organic Frameworks with Ultralarge Pores
T2 - Journal of the American Chemical Society
AU - Park, J
AU - Feng, Dawei
AU - Zhou, Hong-Cai
PY - 2015
DA - 2015/01/21
PB - American Chemical Society (ACS)
SP - 1663-1672
IS - 4
VL - 137
PMID - 25581395
SN - 0002-7863
SN - 1520-5126
ER -
Cite this
BibTex (up to 50 authors)
Copy
@article{2015_Park,
author = {J Park and Dawei Feng and Hong-Cai Zhou},
title = {Structure-Assisted Functional Anchor Implantation in Robust Metal–Organic Frameworks with Ultralarge Pores},
journal = {Journal of the American Chemical Society},
year = {2015},
volume = {137},
publisher = {American Chemical Society (ACS)},
month = {jan},
url = {https://doi.org/10.1021/ja5123528},
number = {4},
pages = {1663--1672},
doi = {10.1021/ja5123528}
}
Cite this
MLA
Copy
Park, J., et al. “Structure-Assisted Functional Anchor Implantation in Robust Metal–Organic Frameworks with Ultralarge Pores.” Journal of the American Chemical Society, vol. 137, no. 4, Jan. 2015, pp. 1663-1672. https://doi.org/10.1021/ja5123528.